Method for producing nickel powder

Patent metadata

Field	Value
Publication number	US-10518332-B2
Application number	US-201716303313-A
Country	US
Kind code	B2
Filing date	May 30, 2017
Priority date	May 30, 2016
Publication date	Dec 31, 2019
Grant date	Dec 31, 2019

Abstract

A nickel sulfate amine complex liquid and nickel powder having a particle diameter of 0.1 μm to 300 μm are supplied to a reaction container, hydrogen gas is continuously supplied while the inside of the reaction container is maintained at 150° C. to 250° C., and the pressure is set to 2.5 MPa to 3.5 MPa, whereby nickel ions in the nickel sulfate amine complex liquid are reduced to nickel and deposited on the surfaces of the nickel powder supplied to the reaction container, a reacted slurry including the nickel sulfate amine complex liquid and the nickel powder is then transferred to a pressurized storage container at the same or slightly lower pressure than the internal pressure of the reaction container, and the pressure of the pressurized storage container to which the reacted slurry is transferred is then reduced, after which the reacted slurry is extracted from the pressurized storage container.

First claim

The invention claimed is:

1. A method for producing nickel powder, the method comprising:
supplying a nickel sulfate ammine complex solution and nickel powder having a particle size of 0.1 μm to 300 μm as seed crystals to a reaction container, continuously supplying hydrogen gas to set a pressure of a gas phase part inside the reaction container to 2.5 MPa to 3.5 MPa while the inside of the reaction container is maintained at a temperature in a range of 150° C. to 250° C. so that nickel ions in the nickel sulfate ammine complex solution are reduced to nickel and the reduced nickel is precipitated on a surface of the nickel powder as seed crystals supplied to the reaction container so as to obtain reduced nickel powder;
subsequently transferring a reacted slurry containing the nickel sulfate ammine complex solution and the reduced nickel powder to a pressurized storage container which is connected to the reaction container and is maintained at the same as an internal pressure of the reaction container or lower than the internal pressure of the reaction container by a range of 0.2 MPa to 1.0 MPa; and
subsequently reducing the pressure of the pressurized storage container to which the reacted slurry is transferred, and then extracting the reacted slurry from the pressurized storage container to recover the reduced nickel powder.

2. The method for producing nickel powder according to claim 1 , wherein the internal pressure of the pressurized storage container is adjusted and maintained by blowing an inert gas to the pressurized storage container to increase the pressure of the pressurized storage container or discharging the inert gas from the pressurized storage container to reduce the pressure of the pressurized storage container.

3. The method for producing nickel powder according to claim 1 , wherein the internal pressure of the pressurized storage container is reduced by cooling the inside of the pressurized storage container to 100° C. or lower.

4. The method for producing nickel powder according to claim 1 , wherein the internal pressure of the pressurized storage container to which the reacted slurry is transferred is reduced to atmospheric pressure, the reacted slurry is then extracted from the pressurized storage container, and the extracted reacted slurry is subjected to solid-liquid separation to recover the nickel powder.

5. The method for producing nickel powder according to claim 2 , wherein the internal pressure of the pressurized storage container is reduced by cooling the inside of the pressurized storage container to 100° C. or lower.

6. The method for producing nickel powder according to claim 2 , wherein the internal pressure of the pressurized storage container to which the reacted slurry is transferred is reduced to atmospheric pressure, the reacted slurry is then extracted from the pressurized storage container, and the extracted reacted slurry is subjected to solid-liquid separation to recover the nickel powder.

Assignees

• Sumitomo Metal Mining Co

Inventors

• Takaishi Kazuyuki
• HEGURI Shin-ichi
• YAMAGUMA Ryo-ma
• Ozaki Yoshitomo
• Doi Yasuo

Classifications

• B22F9/26 Primary

  using gaseous reductors · CPC title

• B22F2301/15

  Nickel or cobalt · CPC title

• B22F2201/013

  Hydrogen · CPC title

• B22F9/24 Primary

  starting from liquid metal compounds, e.g. solutions · CPC title

• B22F2201/10

  Inert gases · CPC title