Method for producing nickel powder

Patent metadata

Field	Value
Publication number	US-2016354844-A1
Application number	US-201515117855-A
Country	US
Kind code	A1
Filing date	Feb 17, 2015
Priority date	Feb 17, 2014
Publication date	Dec 8, 2016
Grant date	—

Abstract

Provided is a method for producing fine nickel powder used as suitable seed crystals for producing nickel powder from a solution containing a nickel ammine sulfate complex. The method for producing nickel powder sequentially includes: a mixing step of adding, to a solution containing a nickel ammine sulfate complex, a dispersant containing a sulfonate and an insoluble solid which is insoluble in the solution to form a mixed slurry; a reduction and precipitation step of charging a reaction vessel with the mixed slurry and then blowing hydrogen gas into the mixed slurry in the reaction vessel to reduce nickel complex ions contained in the mixed slurry to form nickel precipitate on a surface of the insoluble solid; and a separation step of separating the nickel precipitate on the surface of the insoluble solid from the surface of the insoluble solid to form nickel powder.

First claim

1 . A method for producing nickel powder, sequentially comprising:
a mixing step of adding, to a solution containing a nickel ammine sulfate complex, a dispersant containing a sulfonate and an insoluble solid which is insoluble in the solution to form a mixed slurry; a reduction and precipitation step of charging a reaction vessel with the mixed slurry and then blowing hydrogen gas into the mixed slurry while maintaining a pressure of a gas phase part in the reaction vessel at 1.0 to 4.0 MPa, to reduce nickel complex ions contained in the mixed slurry to form nickel precipitate on a surface of the insoluble solid; and a separation step of separating the nickel precipitate on the surface of the insoluble solid from the surface of the insoluble solid to form nickel powder.

2 . The method for producing nickel powder according to claim 1 , wherein the concentration of ammonium sulfate contained in the solution containing a nickel ammine sulfate complex is in the range of 10 to 500 g/L.

3 . The method for producing nickel powder according to claim 2 , wherein, in the reduction step, the mixed slurry when the hydrogen gas is blown has a temperature of 150 to 200° C.

4 . (canceled)

5 . The method for producing nickel powder according to claim 3 , wherein the insoluble solid is one or a combination selected from among nickel, alumina, zirconia, iron, and silica.

6 . The method for producing nickel powder according to claim 5 , wherein, in the mixing step, the dispersant containing a sulfonate is added before the insoluble solid is added.

7 . The method for producing nickel powder according to claim 1 , wherein, in the reduction step, the mixed slurry when the hydrogen gas is blown has a temperature of 150 to 200° C.

8 . The method for producing nickel powder according to claim 7 , wherein the insoluble solid is one or a combination selected from among nickel, alumina, zirconia, iron, and silica.

9 . The method for producing nickel powder according to claim 8 , wherein, in the mixing step, the dispersant containing a sulfonate is added before the insoluble solid is added.

10 . The method for producing nickel powder according to claim 1 , wherein the insoluble solid is one or a combination selected from among nickel, alumina, zirconia, iron, and silica.

11 . The method for producing nickel powder according to claim 10 , wherein, in the mixing step, the dispersant containing a sulfonate is added before the insoluble solid is added.

12 . The method for producing nickel powder according to claim 1 , wherein, in the mixing step, the dispersant containing a sulfonate is added before the insoluble solid is added.

Assignees

• Kochi Univ Nat Univ Corp
• Sumitomo Metal Mining Co

Inventors

• Yanagisawa Kazumichi
• Zhang Junhao
• HEGURI Shin-ichi
• Ozaki Yoshitomo
• Takaishi Kazuyuki
• Ohara Hideki
• Yoneyama Tomoaki
• Ikeda Osamu
• Kudo Yohei

Classifications

• B22F2999/00

  Aspects linked to processes or compositions used in powder metallurgy · CPC title

• B22F2998/10

  Processes characterised by the sequence of their steps · CPC title

• B22F2009/245

  Reduction reaction in an Ionic Liquid [IL] · CPC title

• B22F2301/15

  Nickel or cobalt · CPC title

• B22F9/24 Primary

  starting from liquid metal compounds, e.g. solutions · CPC title