Copper-based alloys, processes for producing the same, and products formed therefrom

Patent metadata

Field	Value
Publication number	US-10507520-B2
Application number	US-201715398509-A
Country	US
Kind code	B2
Filing date	Jan 4, 2017
Priority date	Apr 6, 2011
Publication date	Dec 17, 2019
Grant date	Dec 17, 2019

Abstract

Processes are provided that include providing a copper-manganese alloy containing copper and manganese and having an amount of manganese that is at least 32 weight percent and not more than 40 weight percent of a combined total amount of the copper and manganese in the copper-manganese alloy, and casting the copper-manganese alloy by multidirectional solidification to produce a product in the form of a casting. The copper-manganese alloy has a composition sufficiently near the congruent melting point of the Cu—Mn alloy system to sufficiently avoid dendritic growth during the multidirectional solidification of the copper-manganese alloy to avoid the formation of microporosity attributable to dendritic growth. The product has a cast microstructure having a cellular and/or planar solidification structure free of dendritic growth and having multidirectional columnar grains.

First claim

The invention claimed is:

1. A process comprising:
combining copper and ferromanganese to form a copper-manganese alloy, the ferromanganese containing about 75 to 80 weight percent manganese with the balance carbon, iron, and incidental impurities, the copper-manganese alloy containing copper and manganese and having an amount of manganese that is at least 32 weight percent and not more than 40 weight percent of a combined total amount of the copper and manganese in the copper-manganese alloy; and
casting the copper-manganese alloy by multidirectional solidification at an uncontrolled solidification rate to produce a product in the form of a casting, the copper-manganese alloy having a composition sufficiently near the congruent melting point of the Cu—Mn alloy system to sufficiently avoid dendritic growth during the multidirectional solidification of the copper-manganese alloy to avoid the formation of microporosity attributable to dendritic growth, the product having a cast microstructure having a cellular and/or planar solidification structure and having multidirectional columnar grains.

2. The process according to claim 1 , wherein the copper-manganese alloy contains at least 32 weight percent and not more than 36 weight percent manganese.

3. The process according to claim 1 , wherein the copper-manganese alloy further contains one or more of iron, nickel, aluminum, silicon, tin, and lead.

4. The process according to claim 1 , wherein the copper-manganese alloy does not contain lead.

5. The process according to claim 1 , wherein the product is free of microporosity.

6. The process according to claim 1 , wherein the product is a plumbing valve or fitting.

7. A process comprising:
combining copper and ferromanganese as a source of manganese to form a copper-manganese alloy, the ferromanganese containing about 75 to 80 weight percent manganese with the balance carbon, iron, and incidental impurities, the copper-manganese alloy containing copper and manganese and having an amount of manganese that is at least 32 weight percent and not more than 40 weight percent of a combined total amount of the copper and manganese in the copper-manganese alloy; and
casting the copper-manganese alloy by multidirectional solidification to produce a product in the form of a casting, the copper-manganese alloy having a composition sufficiently near the congruent melting point of the Cu—Mn alloy system to sufficiently avoid dendritic growth during the multidirectional solidification of the copper-manganese alloy to avoid the formation of microporosity attributable to dendritic growth, the product having a cast microstructure having a cellular and/or planar solidification structure and having multidirectional columnar grains.

8. The process according to claim 7 , wherein the ferromanganese is solid ferromanganese, the copper has not been deoxidized, and the combining step comprises generating heat by oxidation of the carbon in the ferromanganese to melt and dissolve the ferromanganese.

9. The process according to claim 1 , wherein the copper-manganese alloy contains iron.

10. The process according to claim 7 , wherein the copper-manganese alloy contains at least 32 weight percent and not more than 36 weight percent manganese.

11. The process according to claim 7 , wherein the copper-manganese alloy further contains one or more of nickel, aluminum, silicon, tin, and lead.

12. The process according to claim 7 , wherein the copper-manganese alloy does not contain lead.

13. The process according to claim 7 , wherein the product is a plumbing valve or fitting.

14. The process according to claim 7 , wherein the product is free of microporosity.

15. The process according to claim 1 , wherein the casting step is performed in a steel mold.

16. The process according to claim 15 , wherein the casting step includes melting the copper-manganese alloy to form a melt and pouring the melt into the steel mold, wherein the temperature of the melt decreases toward an ambient temperature established by the steel mold.

17. The process according to claim 1 , wherein the casting step includes melting the copper-manganese alloy to form a melt and pouring the melt into a mold, wherein the temperature of the melt decreases toward an ambient temperature established by the mold.

18. The process according to claim 1 , wherein heat is generated by oxidation of carbon in the ferromanganese to melt and dissolve the ferromanganese.

19. A process comprising:
combining copper that has not been deoxidized and solid ferromanganese containing carbon to form a copper-manganese alloy containing copper and manganese and having an amount of manganese that is at least 32 weight percent and not more than 40 weight percent of a combined total amount of the copper and manganese in the copper-manganese alloy, wherein heat is generated by oxidation of the carbon in the ferromanganese to melt and dissolve the ferromanganese;
melting the copper-manganese alloy to form a melt;
pouring the melt into a multidirectional solidification mold to cast a product via multidirectional solidification in the form of a casting, wherein the temperature of the melt decreases toward an ambient temperature established by the mold, the copper-manganese alloy having a composition sufficiently near the congruent melting point of the Cu—Mn alloy system to sufficiently avoid dendritic growth during the multidirectional solidification of the copper-manganese alloy to avoid the formation of microporosity attributable to dendritic growth, the product having a cast microstructure having a cellular and/or planar solidification structure and having multidirectional columnar grains.

Assignees

• Purdue Research Foundation

Inventors

• Trumble Kevin Paul

Classifications

• C22C9/05

  with manganese as the next major constituent · CPC title

• B22D21/005

  with high melting point, e.g. Be 1280 degrees C, Ti 1725 degrees C · CPC title

• B22D27/045 Primary

  Directionally solidified castings · CPC title

• C22C1/02

  by melting {(C22C1/1036 takes precedence)} · CPC title

• C22C1/03

  using master alloys · CPC title