Conductive material formulation and use thereof

Patent metadata

Field	Value
Publication number	US-10504658-B2
Application number	US-201815879875-A
Country	US
Kind code	B2
Filing date	Jan 25, 2018
Priority date	May 20, 2013
Publication date	Dec 10, 2019
Grant date	Dec 10, 2019

Abstract

The invention pertains to a conductive material formulation comprising:
(a) a conductive polymer material; and
(b) an insulation material,
wherein the conductive polymer material is derived from a conductive polymer and a polyanion and has a weight average molecular weight ranging from 3,000 to 30,000; and
wherein the (b) insulation material is present in an amount of 0.01 part to 200 parts by weight based on 100 parts by weight of the (a) conductive polymer material. The conductive material formulation according to the invention is useful for the preparation of solid capacitors.

First claim

What is claimed is:

1. A conductive material formulation, comprising a plurality of separate components including:
(a) a first solution comprising a conductive polymer material, and
(b) a second solution comprising an insulation material,

wherein the conductive polymer material is derived from a conductive polymer and polyanion,
wherein the conductive polymer comprises a polymerization unit derived from a monomer of formula (I):

wherein
A is C 1 to C 4 alkylene substituted with (R) p ,
X is O or S,
R is H, unsubstituted or substituted C 1 to C 20 alkyl or alkoxy, or unsubstituted or substituted C 6 to C 20 aryl, and
p is 0, 1 or 2, and
the conductive polymer has a weight average molecular weight in the range of 3,000 to 30,000, wherein the (b) insulation material is a non-conjugated polymer selected from the group consisting of polyethylene, polypropylene, carboxymethyl cellulose, polyethylene glycol, polyacrylamide and polytetrafluoroethene (Telfon); and wherein the (b) insulation material has a content of about 0.01 to about 50 parts by weight, based on 100 parts by weight of the (a) conductive polymer material.

2. The conductive material formulation according to claim 1 , wherein the conductive polymer material further comprises a polymerization unit derived from a monomer of formula (II):

wherein,
B1 is O, S or N,
B2 is N or C,
each of R1, R2 and R3 is independently H, unsubstituted or substituted C 1 to C 20 alkyl or alkoxy, or unsubstituted or substituted C 6 to C 20 aryl, and
each of q and w is independently 0 or 1.

3. The conductive material formulation according to claim 1 , wherein the monomer of formula (I) is selected from a group consisting of:

and a combination thereof,
wherein each of R4 and R5 is independently H, unsubstituted or substituted C 1 to C 15 alkyl or alkoxy, or unsubstituted or substituted C 6 to C 15 aryl.

4. The conductive material formulation according to claim 2 , wherein the monomer of formula (II) is selected from a group consisting of:

and a combination thereof,
wherein each of R1, R2 and R3 is independently H or C 1 to C 3 alkyl or alkoxy.

5. The conductive material formulation according to claim 1 , wherein the conductive polymer material has a size in the range of about 10 to about 1000 nanometers.

6. The conductive material formulation according to claim 1 , wherein the insulation material has a resistivity of 10 3 to 10 12 Ω·m.

7. A solid capacitor, comprising:
an anode;
a dielectric layer, formed on the anode;
a cathode; and
a solid electrolyte, located between the dielectric layer and the cathode, wherein the solid electrolyte comprises the conductive material formulation according to claim 1 .

8. A solid capacitor, comprising:
an anode;
a dielectric layer, formed on the anode;
a cathode; and
a solid electrolyte, located between the dielectric layer and the cathode,

wherein the solid electrolyte comprises the conductive material formulation according to claim 2 .

9. A solid capacitor, comprising:
an anode;
a dielectric layer, formed on the anode;
a cathode; and
a solid electrolyte, located between the dielectric layer and the cathode,

wherein the solid electrolyte comprises the conductive material formulation according to claim 3 .

10. A solid capacitor, comprising:
an anode;
a dielectric layer, formed on the anode;
a cathode; and
a solid electrolyte, located between the dielectric layer and the cathode,

wherein the solid electrolyte comprises the conductive material formulation according to claim 4 .

11. A solid capacitor, comprising:
an anode;
a dielectric layer, formed on the anode;
a cathode; and
a solid electrolyte, located between the dielectric layer and the cathode,

wherein the solid electrolyte comprises the conductive material formulation according to claim 5 .

12. A solid capacitor, comprising:
an anode;
a dielectric layer, formed on the anode;
a cathode; and
a solid electrolyte, located between the dielectric layer and the cathode,

wherein the solid electrolyte comprises the conductive material formulation according to claim 6 .

13. A solid capacitor produced by a process comprising (a) forming a capacitor body by forming a dielectric layer on an anode; (b) forming a solid electrolyte comprising the conductive material formulation according to claim 1 on the dielectric layer by immersing the capacitor body into the first solution comprising the conductive polymer material and immersing the capacitor body into the second solution comprising the insulation material respectively in either order, wherein the respective first and second solutions are heated to dry after the respective immersing steps; and (c) forming a cathode on the dielectric layer.

Assignees

• Eternal Mat Co Ltd

Inventors

• Chen Shinn-Horng

Classifications

• Y10T428/2982

  Particulate matter [e.g., sphere, flake, etc.] · CPC title

• H01G9/025

  Solid electrolytes (H01G11/54 takes precedence) · CPC title

• H01B1/14 Primary

  Conductive material dispersed in non-conductive inorganic material · CPC title

• H01G9/028 Primary

  Organic semiconducting electrolytes, e.g. TCNQ · CPC title

• H01G9/15

  Solid electrolytic capacitors (H01G11/00 takes precedence) · CPC title