Formed body and method for producing the same, α-olefin dimerization catalyst, and method for producing α-olefin dimer

Patent metadata

Field	Value
Publication number	US-10500570-B2
Application number	US-201415103216-A
Country	US
Kind code	B2
Filing date	Dec 10, 2014
Priority date	Dec 17, 2013
Publication date	Dec 10, 2019
Grant date	Dec 10, 2019

Abstract

Provided is a formed body containing at least one carbonate compound (A1) selected from Na 2 CO 3 or K 2 CO 3 , the formed body having a volume of pores with a pore diameter of from 0.05 μm to 10 μm of from 0.10 mL/g to 0.30 mL/g and a crushing strength of from 1.8 kgf to 10.0 kgf.

First claim

The invention claimed is:

1. An α-olefin dimerization catalyst comprising a formed body and an alkali metal (D) supported on the formed body,
wherein the formed body comprises at least one carbonate compound (A1) selected from Na 2 CO 3 or K 2 CO 3 in a content of 70% by mass or more, the formed body having a volume of pores with a pore diameter of from 0.05 μm to 10 μm of from 0.10 mL/g to 0.30 mL/g and a crushing strength of from 1.8 kgf to 10.0 kgf.

2. A method for producing an α-olefin dimer, the method comprising performing an α-olefin dimerization reaction in the presence of the α-olefin dimerization catalyst according to claim 1 .

3. A method for producing the α-olefin dimerization catalyst according to claim 1 , the method comprising:
forming a mixture of 100 parts by mass of a total amount of (A) and (B), the mixture comprising from 10 parts by mass to 100 parts by mass of at least one hydrogen carbonate compound (A) represented by AHCO 3 , wherein A is Na or K, and 0 parts by mass to 90 parts by mass of at least one compound (B) represented by B n X, wherein B is Na or K, X is CO 3 , SO 4 , SiO 3 , F, Cl, or Br, and n is an integer of 1 or 2 determined by the valence of X, wherein a total amount of (A), and NaCO 3 and KCO 3 among (B) is 70 parts by mass or more; and
thermally treating the resultant formed mixture at a temperature of from 100° C. to 500° C. to thermally decompose 97% by mass or more of the hydrogen carbonate compound (A) to form the formed body, and
supporting the alkali metal (D) on the formed body.

4. The method according to claim 3 , wherein the mixture is free of water.

5. The method according to claim 3 , wherein the forming of the mixture is performed by tablet compression.

6. The method according to claim 3 , wherein the mixture has a median diameter (d50), at a volume statistic, of from 5 μm to 600 μm.

7. The method according to claim 3 , wherein a content ratio of particles with a particle diameter of 40 μm or less is from 3% by mass to 30% by mass in the mixture.

8. The α-olefin dimerization catalyst according to claim 1 , further comprising at least one compound (B1) represented by Na n Y or K n Y, wherein Y is SO 4 , SiO 3 , F, Cl or Br, and n is an integer of 1 or 2 determined by the valence of Y.

9. The α-olefin dimerization catalyst according to claim 1 , wherein the formed body is produced by a process comprising:
forming a mixture of 100 parts by mass of a total amount of (A) and (B), the mixture comprising from 10 parts by mass to 100 parts by mass of at least one hydrogen carbonate compound (A) represented by AHCO 3 , wherein A is Na or K, and 0 parts by mass to 90 parts by mass of at least one compound (B) represented by B n X, wherein B is Na or K, X is CO 3 , SO 4 , SiO 3 , F, Cl, or Br, and n is an integer of 1 or 2 determined by the valence of X, wherein a total amount of (A) and NaCO 3 and/or KCO 3 among (B) is 70 parts by mass or more; and
thermally treating the resultant formed mixture at a temperature of from 100° C. to 500° C. to thermally decompose 97% by mass or more of the hydrogen carbonate compound (A).

10. The α-olefin dimerization catalyst according to claim 1 , wherein the volume of pores is from 0.14 mL/g to 0.28 mL/g, and the crushing strength is from 2.2 kgf to 8.5 kgf.

11. The α-olefin dimerization catalyst according to claim 1 , wherein the carbonate compound (A1) is K 2 CO 3 .

12. The α-olefin dimerization catalyst according to claim 1 , further comprising graphite (C).

Assignees

• Mitsui Chemicals Inc

Inventors

• Ichikawa Shinichiro
• Takahashi Naoya
• Murakami Masami

Classifications

• C07C2/14

  with inorganic acids; with salts or anhydrides of acids · CPC title

• B01J27/232 Primary

  Carbonates · CPC title

• C07C2/24

  with metals · CPC title

• C07C2523/04

  Alkali metals · CPC title

• B01J37/023

  using molten compounds · CPC title