Compositions comprising C5 and C6 oligosaccarides

Patent metadata

Field	Value
Publication number	US-10487369-B2
Application number	US-201715701778-A
Country	US
Kind code	B2
Filing date	Sep 12, 2017
Priority date	Dec 30, 2011
Publication date	Nov 26, 2019
Grant date	Nov 26, 2019

Abstract

Compositions comprising C5 and C6 saccharides of varying degrees of polymerization and low levels of undesirable impurities, such as compounds containing sulfur, nitrogen, or metals, are disclosed.

First claim

What is claimed is:

1. A composition comprising:
a water-soluble C6 oligosaccharide hydrolysate; and
a water-soluble C6 monosaccharide hydrolysate;
wherein said water-soluble C6 monosaccharide hydrolysate is present at a level of about 5% by weight to about 20% by weight, based on the total weight of said water-soluble C6 oligosaccharide hydrolysate and said water-soluble C6 monosaccharide hydrolysate in said composition;
wherein said water-soluble C6 oligosaccharide hydrolysate comprises: about 10% by weight to about 25% by weight, based on the total weight of said water-soluble C6 oligosaccharide hydrolysate and said water-soluble C6 monosaccharide hydrolysate in said composition, of C6 pentasaccharides;
wherein said water-soluble C6 oligosaccharide hydrolysate is processed from lignocellulosic biomass using supercritical, subcritical, or near critical fluid extraction, or a combination thereof; and
wherein said composition further comprises:
(a) less than about 10 ppm by weight, based on the total weight of the composition, of aluminum;
(b) less than about 3000 ppm by weight, based on the total weight of the composition, of calcium;
(c) less than about 350 ppm by weight, based on the total weight of the composition, of iron; and/or
(d) less than about 1000 ppm by weight, based on the total weight of the composition, of sulfur.

2. The composition of claim 1 , wherein said water-soluble C6 oligosaccharide hydrolysate comprises a C6 oligosaccharide having a degree of polymerization of about 2 to about 15.

3. The composition of claim 1 , wherein said water-soluble C6 monosaccharide hydrolysate is glucose, galactose, mannose, fructose, or a mixture thereof.

4. The composition of claim 1 , further comprising less than about 10 ppm by weight, based on the total weight of the composition, of aluminum.

5. The composition of claim 1 , further comprising less than about 3000 ppm by weight, based on the total weight of the composition, of calcium.

6. The composition of claim 1 , further comprising less than about 350 ppm by weight, based on the total weight of the composition, of iron.

7. The composition of claim 1 , further comprising less than about 1000 ppm by weight, based on the total weight of the composition, of sulfur.

8. The composition of claim 1 , wherein aluminum, calcium, iron and sulfur, if present, comprise, based on the total weight of said composition, less than about 10 ppm by weight of aluminum; less than about 3000 ppm by weight of calcium; less than about 350 ppm by weight of iron; and less than about 1000 ppm by weight of sulfur.

9. The composition of claim 1 , wherein said water-soluble C6 oligosaccharide hydrolysate further comprises:
about 10% by weight to about 25% by weight, based on the total weight of said water-soluble C6 oligosaccharide hydrolysate and said water-soluble C6 monosaccharide hydrolysate in said composition, of C6 disaccharides;
about 10% by weight to about 25% by weight, based on the total weight of said water-soluble C6 oligosaccharide hydrolysate and said water-soluble C6 monosaccharide hydrolysate in said composition, of C6 trisaccharides;
about 10% by weight to about 25% by weight, based on the total weight of said water-soluble C6 oligosaccharide hydrolysate and said water-soluble C6 monosaccharide hydrolysate in said composition, of C6 tetrasaccharides; and
about 10% by weight to about 50% by weight, based on the total weight of said water-soluble C6 oligosaccharide hydrolysate and said water-soluble C6 monosaccharide hydrolysate in said composition, of water-soluble C6 saccharides having a degree of polymerization of at least about 6.

10. The composition of claim 9 , wherein said C6 monosaccharides are present at a level of about 7.5% by weight to about 20% by weight, based on the total weight of said water-soluble C6 oligosaccharide hydrolysate and said water-soluble C6 monosaccharide hydrolysate in said composition.

11. The composition of claim 1 , further comprising: about 10% by weight to about 25% by weight, based on the total weight of water-soluble C6 saccharides present in said composition, of C6 disaccharides.

12. The composition of claim 1 , further comprising: about 10% by weight to about 25% by weight, based on the total weight of water-soluble C6 saccharides present in said composition, of C6 trisaccharides.

13. The composition of claim 1 , further comprising: about 10% by weight to about 25% by weight, based on the total weight of water-soluble C6 saccharides present in said composition, of C6 tetrasaccharides.

14. The composition of claim 1 , wherein said C6 pentasaccharides are present at a level of about 10% by weight to about 20% by weight, based on the total weight of water-soluble C6 saccharides present in said composition.

15. The composition of claim 1 , further comprising: about 10% by weight to about 50% by weight, based on the total weight of water-soluble C6 saccharides present in said composition, of water-soluble C6 saccharides having a degree of polymerization of at least about 6.

16. The composition of claim 1 , wherein said C6 monosaccharides are present at a level of about 7.5% by weight to about 20% by weight, based on the total weight of water-soluble C6 saccharides present in said composition.

17. The composition of claim 1 , wherein said water-soluble C6 oligosaccharide hydrolysate is present at a level of about 80% by weight to about 95% by weight, based on the total weight of water-soluble C6 saccharides present in said composition; and wherein said water-soluble C6 oligosaccharides have a degree of polymerization of about 2 to about 15.

18. The composition of claim 17 , wherein said water-soluble C6 oligosaccharide hydrolysate is present at a level of about 80% by weight to about 92.5% by weight, based on the total weight of water-soluble C6 saccharides present in said composition.

19. The composition of claim 1 , wherein said water-soluble C6 oligosaccharide hydrolysate further comprises:
about 10% by weight to about 25% by weight, based on the total weight of said water-soluble C6 oligosaccharide hydrolysate and said water-soluble C6 monosaccharide hydrolysate in said composition, of C6 trisaccharides; and
about 10% by weight to about 50% by weight, based on the total weight of said water-soluble C6 oligosaccharide hydrolysate and said water-soluble C6 monosaccharide hydrolysate in said composition, of water-soluble C6 saccharides having a degree of polymerization of at least about 6.

20. The composition of claim 1 , wherein said water-soluble C6 oligosaccharide hydrolysate is processed from lignocellulosic biomass using supercritical, or near critical fluid extraction, or a combination thereof.

Assignees

• Renmatix Inc

Inventors

• Floyd Daniel Clay
• Kadam Kiran
• Kilambi Srinivas

Classifications

• C07H3/06

  Oligosaccharides, i.e. having three to five saccharide radicals attached to each other by glycosidic linkages · CPC title

• C13K13/002

  Xylose · CPC title

• C13K13/007

  Separation of sugars provided for in subclass C13K (C13K3/00 takes precedence) · CPC title

• C13K13/00

  Sugars not otherwise provided for in this class · CPC title

• C07H3/02 Primary

  Monosaccharides · CPC title