Natural gas liquid fractionation plant waste heat conversion to simultaneous power, cooling and potable water using modified goswami cycle and new modified multi-effect-distillation system

Patent metadata

Field	Value
Publication number	US-10480355-B2
Application number	US-201715842292-A
Country	US
Kind code	B2
Filing date	Dec 14, 2017
Priority date	Aug 8, 2017
Publication date	Nov 19, 2019
Grant date	Nov 19, 2019

Abstract

Certain aspects of natural gas liquid fractionation plant waste heat conversion to simultaneous power, cooling and potable water using modified Goswami Cycle and new modified MED system can be implemented as a system. In an example implementation, the system includes a waste heat recovery heat exchanger network coupled to multiple heat sources of a Natural Gas Liquid (NGL) fractionation plant, the heat exchanger network configured to transfer at least a portion of heat generated at the multiple heat sources to a first buffer fluid and a second buffer fluid flowed through the first heat exchanger network. The system includes a first sub-system configured to generate power and sub-ambient cooling capacity, the first sub-system thermally coupled to the waste heat recovery heat exchanger. The system includes a second sub-system configured to generate potable water from brackish water, the second sub-system thermally coupled to the waste heat recovery heat exchanger.

First claim

The invention claimed is:

1. A system comprising:
a waste heat recovery heat exchanger network comprising heat exchangers coupled to a a Natural Gas Liquid (NGL) fractionation plant, the NGL fractionation plant comprising a propane dehydration section comprising a propane dehydrator column and a de-propanizer section comprising a de-propanizer distillation column, wherein the heat exchangers comprise:
a first heat exchanger thermally coupled to the propane dehydration section to heat a first buffer stream using heat carried by a propane de-hydration outlet stream from the propane de-hydration section; and
a second heat exchanger thermally coupled to the de-propanizer section to heat a second buffer stream using heat carried by a de-propanizer overhead outlet stream, wherein the first buffer stream is a first type of buffer fluid, and wherein the second buffer stream is a second type of buffer fluid different than the first type; and

a first sub-system comprising a power turbine and heat exchangers, the first sub-system coupled to the waste heat recovery heat exchanger network and configured to generate power and sub-ambient cooling capacity using heat provided by the first buffer stream.

2. The system of claim 1 , further comprising a flow control system connected to the heat exchanger network and the first sub-system and comprising pumps, pipe, and valves to flow fluids between the NGL fractionation plant, the heat exchanger network, and the first sub-system, wherein the fluids comprise buffer fluid and NGL fractionation plant streams.

3. The system of claim 1 , comprising:
a first collection-header conduit to receive the first buffer stream discharged from the first heat exchanger, wherein the first collection-header conduit to route the first type of buffer fluid to the first sub-system; and
a second collection-header conduit to receive the second buffer stream discharged from the second heat exchanger.

4. The system of claim 1 , wherein the NGL fractionation plant comprises a butane de-hydrator section comprising a butane dehydrator column and a de-butanizer section comprising a de-butanizer distillation column, and wherein the heat exchangers comprise:
a third heat exchanger thermally coupled to the butane de-hydrator section to heat a third buffer stream using heat carried by a butane de-hydrator outlet stream; and
a fourth heat exchanger thermally coupled to the de-butanizer section to heat a fourth buffer stream using heat carried by a de-butanizer overhead outlet stream.

5. The system of claim 4 , wherein the NGL fractionation plant comprises a de-pentanizer section comprising a de-pentanizer distillation column, an Amine-Di-Iso-Propanol (ADIP) regeneration section comprising an ADIP regenerator distillation column, a natural gas (NG) de-colorizing section comprising NG decolorizer distillation-column, a propane vapor recovery section comprising a compressor and a condenser heat exchanger, and a propane product refrigeration section comprising a propane refrigeration compressor, wherein the heat exchangers comprise:
a seventh heat exchanger thermally coupled to the de-pentanizer section to heat a seventh buffer stream using heat carried by a de-pentanizer overhead outlet stream from the de-pentanizer section; and
an eighth heat exchanger thermally coupled to the ADIP regeneration section to heat a eighth buffer stream using heat carried by an ADIP regeneration section overhead outlet stream.

6. The system of claim 5 , wherein the heat exchangers comprise:
a ninth heat exchanger thermally coupled to the ADIP regeneration section, the ninth heat exchanger configured to heat a ninth buffer stream using heat carried by an ADIP regeneration section bottoms outlet stream;
a tenth heat exchanger thermally coupled to the natural gas de-colorizing section, the tenth heat exchanger configured to heat a tenth buffer stream using heat carried by a natural gas de-colorizing section pre-flash drum overhead outlet stream;
an eleventh heat exchanger thermally coupled to the natural gas de-colorizing section, the eleventh heat exchanger configured to heat an eleventh buffer stream using heat carried by a natural gas de-colorizer overhead outlet stream;
a twelfth heat exchanger thermally coupled to the propane vapor recovery section, the twelfth heat exchanger configured to heat a twelfth buffer stream using heat carried by a propane vapor recovery compressor outlet stream; and
a thirteenth heat exchanger thermally coupled to the propane product refrigeration section, the thirteenth heat exchanger configured to heat a thirteenth buffer stream using heat carried by a propane refrigeration compressor outlet stream from the propane product refrigeration section.

7. The system of claim 4 , wherein the heat exchangers comprise:
a fifth heat exchanger thermally coupled to the de-butanizer section, the fifth heat exchanger configured to heat a fifth buffer stream using heat carried by a de-butanizer overhead outlet stream from the de-butanizer section; and
a sixth heat exchanger thermally coupled to the de-butanizer section, the sixth heat exchanger configured to heat a sixth buffer stream using heat carried by a de-butanizer bottoms outlet stream from the de-butanizer section.

8. The system of claim 4 , wherein the NGL fractionation plant comprises:
a propane product sub-cooling section comprising a main compressor and a propane condenser heat-exchanger;
a butane product refrigeration section comprising a butane refrigeration compressor and a butane refrigeration condenser heat-exhanger;
an ethane production section comprising an ethane dryer column; and
a Reid Vapor Pressure (RVP) control section comprising a RVP distillation column.

9. The system of claim 8 , wherein the heat exchangers comprise:
a fourteenth heat exchanger thermally coupled to the propane product sub-cooling, the fourteenth heat exchanger configured to heat a fourteenth buffer stream using heat carried by a propane main compressor outlet stream from the propane product sub-cooling section;
a fifteenth heat exchanger thermally coupled to the butane product refrigeration section, the fifteenth heat exchanger configured to heat a fifteenth buffer stream using heat carried by a butane refrigeration compressor outlet stream from the butane product refrigeration section;
a sixteenth heat exchanger thermally coupled to the ethane production section, the sixteenth heat exchanger configured to heat a sixteenth buffer stream using heat carried by an ethane dryer outlet stream; and
a seventeenth heat exchanger thermally coupled to the RVP control section, the seventeenth heat exchanger configured to heat a seventeenth buffer stream using heat carried by a RVP control column overhead outlet stream.

10. The system of claim 4 , wherein the third buffer stream comprises the first type, and wherein the fourth buffer stream comprises the second type.

11. The system of claim 1 , wherein the first sub-system comprises a Goswami cycle system comprising the power turbine and the heat exchangers.

12. The system of claim 1 , comprising a second sub-system coupled to the waste heat recovery heat exchanger network, the second sub-system comprising train distillation effects to generate potable water from brackish water by removing saline water from the brackish water.

13. The system of claim 12 , wherein the second sub-system is configured to generate the potable water from brackish water using heat provided by the second buffer stream.

14. The system of claim 12 , wherein the second sub-system comprises a multi-effect-distillation (MED) system comprising the train distillation

Assignees

• Saudi Arabian Oil Co

Inventors

• Noureldin Mahmoud Bahy Mahmoud
• Kamel Akram Hamed Mohamed

Classifications

• F01K25/10

  the vapours being cold, e.g. ammonia, carbon dioxide, ether · CPC title

• B01D3/146

  Multiple effect distillation · CPC title

• B01D1/0082

  Regulation; Control · CPC title

• B01D3/065

  Multiple-effect flash distillation (more than two traps) · CPC title

• C10G7/00

  Distillation of hydrocarbon oils · CPC title