Kalina cycle based conversion of gas processing plant waste heat into power

Patent metadata

Field	Value
Publication number	US-9745871-B2
Application number	US-201514978085-A
Country	US
Kind code	B2
Filing date	Dec 22, 2015
Priority date	Aug 24, 2015
Publication date	Aug 29, 2017
Grant date	Aug 29, 2017

Abstract

A system includes a waste heat recovery heat exchanger configured to heat a heating fluid stream by exchange with a heat source in a crude oil associated gas processing plant; and a Kalina cycle energy conversion system including a first group of heat exchangers to heat a first portion of a working fluid by exchange with the heated heating fluid stream and a second group of heat exchangers to heat a second portion of the working fluid. The second group of heat exchangers includes a first heat exchanger to heat the second portion of the working fluid by exchange with a liquid stream of the working fluid; and a second heat exchanger to heat the second portion of the working fluid by exchange with the heated heating fluid stream. The energy conversion system includes a separator to receive the heated first and second portions of the working fluid and to output a vapor stream of the working fluid and the liquid stream of the working fluid; a first turbine and a generator to generate power by expansion of the vapor stream; and a second turbine to generate power from the liquid stream.

First claim

What is claimed is:

1. A system comprising:
a waste heat recovery heat exchanger configured to heat a heating fluid stream by exchange with a heat source in a crude oil associated gas processing plant;
a Kalina cycle energy conversion system including:
a first group of energy conversion heat exchangers configured to heat a first portion of a working fluid by exchange with the heated heating fluid stream, the working fluid comprising ammonia and water;
a second group of energy conversion heat exchangers configured to heat a second portion of the working fluid, the second group of energy conversion heat exchangers including:
a first heat exchanger configured to heat the second portion of the working fluid by exchange with a liquid stream of the working fluid; and
a second heat exchanger configured to receive the second portion of the working fluid from the first heat exchanger and to heat the second portion of the working fluid by exchange with the heated heating fluid stream;

a separator configured to receive the heated first and second portions of the working fluid and to output a vapor stream of the working fluid and the liquid stream of the working fluid;
a first turbine and a generator, wherein the turbine and generator are configured to generate power by expansion of the vapor stream of the working fluid; and
a second turbine configured to generate power from the liquid stream of the working fluid.

2. The system of claim 1 , wherein each of the energy conversion heat exchangers has a thermal duty of between 800 MM Btu/h and 1200 MM Btu/h.

3. The system of claim 1 , wherein the first turbine and generator are configured to generate between at least 60 MW of power.

4. The system of claim 1 , wherein the energy conversion system comprises a pump configured to pump the working fluid to a pressure of between 24 Bar and 26 Bar.

5. The system of claim 4 , wherein the first group of energy conversion heat exchangers is configured to heat the first portion of the working fluid to a temperature of between 170° F. and 180° F.

6. The system of claim 1 , wherein the energy conversion system comprises a pump configured to pump the working fluid to a pressure of between 20 Bar and 22 Bar.

7. The system of claim 6 , wherein the heated first and second portions of the working fluid have a pressure of between 19 Bar and 21 Bar upon entry into the separator.

8. The system of claim 6 , wherein the first group of energy conversion heat exchangers is configured to heat the first portion of the working fluid to a temperature of between 185° F. and 195° F.

9. The system of claim 1 , wherein the second group of energy conversion heat exchangers is configured to heat the second portion of the working fluid to a temperature of between 155° F. and 165° F.

10. The system of claim 1 , wherein the second turbine is configured to generate at least 1 MW of power.

11. The system of claim 1 , wherein the Kalina cycle energy conversion system comprises a cooler configured to cool the vapor stream of the working fluid and the liquid stream of the working fluid after power generation, wherein the cooler has a thermal duty of between 2500 MM Btu/h and 3200 MM Btu/h.

12. The system of claim 1 , comprising an accumulation tank, wherein the heating fluid stream flows from the accumulation tank, through the waste heat recovery heat exchanger, through the Kalina cycle energy conversion system, and back to the accumulation tank.

13. The system of claim 1 , wherein the waste heat recovery heat exchanger is configured to heat the heating fluid stream by exchange with a vapor stream from a slug catcher in an inlet area of the gas processing plant.

14. The system of claim 1 , wherein the waste heat recovery heat exchanger is configured to heat the heating fluid stream by exchange with an output stream from a DGA stripper in the gas processing plant.

15. The system of claim 1 , wherein the waste heat recovery heat exchanger is configured to heat the heating fluid stream by exchange with one or more of a sweet gas stream and a sales gas stream in the gas processing plant.

16. The system of claim 1 , wherein the waste heat recovery heat exchanger is configured to heat the heating fluid stream by exchange with a propane header in a propane refrigeration unit of the gas processing plant in the gas processing plant.

17. A method comprising:
heating a heating fluid stream via a waste heat recovery heat exchanger by exchange with a heat source in a crude oil associated gas processing plant;
generating power in a Kalina cycle energy conversion system, comprising:
heating a first portion of a working fluid via a first group of energy conversion heat exchangers by exchange with the heated heating fluid stream, the working fluid comprising ammonia and water;
heating a second portion of a working fluid via a second group of energy conversion heat exchangers, including:
heating the second portion of the working fluid via a first heat exchanger by exchange with a liquid stream of the working fluid; and
heating the second portion of the working fluid via a second heat exchanger by exchange with the heated heating fluid stream;

separating, in a separator, the heated first and second portions of the working fluid into a vapor stream of the working fluid and the liquid stream of the working fluid;
generating power, by a first turbine and generator, by expansion of the vapor stream of the working fluid; and
generating power from the liquid stream of the working fluid by a second turbine.

18. The method of claim 17 , wherein generating power by the first turbine and generator includes generating at least 60 MW.

19. The method of claim 17 , comprising pumping the working fluid to a pressure of between 24 Bar and 26 Bar.

20. The method of claim 19 , wherein heating the first portion of the working fluid comprises heating the first portion of the working fluid to a temperature of between 170 ° F. and 180° F.

21. The method of claim 17 , comprising pumping the working fluid to a pressure of between 20 Bar and 22 Bar.

22. The method of claim 21 , wherein heating the first portion of the working fluid comprises heating the first portion of the working fluid to a temperature of between 185° F. and 195° F.

23. The method of claim 17 , wherein heating the second portion of the working fluid comprises heating the second portion of the working fluid to a temperature of between 155° F. and 165° F.

24. The method of claim 17 , wherein generating power by the second turbine comprises generating at least 1 MW of power.

25. The method of claim 17 , comprising cooling the vapor stream of the working fluid and the liquid stream of the working fluid after power generation, wherein the cooler has a thermal duty of between 2500 MM Btu/h and 3200 MM Btu/h.

26. The method of claim 17 , comprising flowing the heating fluid stream from an accumulation tank, through the waste heat recovery exchanger, through the Kalina cycle energy conversion system, and back to the accumulation tank.

27. The method of claim 17 , comprising heating the heating fluid stream by exchange with a vapor stream from a slug catcher in an inlet area of the gas processing plant.

28. The method of claim 17 , comprising heating the heating fluid stream by exchange with an output stream from a DGA stripper in the gas processing plant.

29.

Assignees

• Saudi Arabian Oil Co

Inventors

• Noureldin Mahmoud Bahy Mahmoud
• Kamel Akram Hamed Mohamed

Classifications

• F01K25/065 Primary

  with an absorption fluid remaining at least partly in the liquid state, e.g. water for ammonia (F01K5/00 takes precedence) · CPC title

• F01K23/08 Primary

  with working fluid of one cycle heating the fluid in another cycle · CPC title

• F01K25/10

  the vapours being cold, e.g. ammonia, carbon dioxide, ether · CPC title