Glass article provided with photocatalyst film, process for producing glass article, and coating liquid

Patent metadata

Field	Value
Publication number	US-10478803-B2
Application number	US-201615289642-A
Country	US
Kind code	B2
Filing date	Oct 10, 2016
Priority date	Feb 3, 2012
Publication date	Nov 19, 2019
Grant date	Nov 19, 2019

Abstract

The present invention provides a glass article including a photocatalyst film 1 containing silicon oxide particles 6 and titanium oxide particles 5, and a glass sheet 2. Assuming that the photocatalyst film 1 has a film thickness T, 80% or more of the titanium oxide particles are localized in a region between a surface of the glass sheet 2 and a position spaced from the surface by 0.6 T toward a surface of the photocatalyst film 1 in a thickness direction of the photocatalyst film 1. The glass article has an increased transmittance provided by enhancing the reflection-reducing function of the photocatalyst film 1 while maintaining the film strength and photocatalytic function of the photocatalyst film 1.

First claim

The invention claimed is:

1. A coating liquid for producing a photocatalyst film, comprising:
silicon oxide particles;
titanium oxide particles;
ethylene glycol; and
a binder source as a source of a binder material whose main component is silicon oxide,
wherein the ratio among the mass of the silicon oxide particles, the mass of the titanium oxide particles, and the mass of the binder material in terms of SiO 2 is 72 to 79:13 to 18:8 to 12,
the silicon oxide particles have an average particle diameter of 50 nm to 150 nm, the titanium oxide particles have an average particle diameter of 5 nm to 20 nm, and the average particle diameter of the silicon oxide particles is five times or more of the average particle diameter of the titanium oxide particles,
the binder source is silicon alkoxide, and
a concentration of the ethylene glycol in the coating liquid is 5 to 15% in terms of mass.

2. The coating liquid according to claim 1 , wherein the concentration of the ethylene glycol in the coating liquid is 8 to 12% in terms of mass.

3. A method for producing a glass article, the method comprising applying the coating liquid of claim 1 to a glass sheet to form a coating film on the glass sheet, drying the glass sheet to which the coating liquid is applied, and obtaining a glass article comprising the glass sheet and a photocatalyst Film formed on a surface of the glass sheet by sintering the coating film.

4. The method for producing a glass article according to claim 3 , wherein the coating liquid includes a surfactant.

Assignees

• Nippon Sheet Glass Co Ltd

Inventors

• Yabuta Takeshi
• Kondo Fumiyoshi
• Kawazu Mitsuhiro

Classifications

• C03C17/23 Primary

  Oxides (C03C17/02 takes precedence) · CPC title

• C03C17/007

  containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase · CPC title

• B01J37/0219

  the coating containing organic compounds · CPC title

• C03C2217/478

  Silica · CPC title

• B01J21/08 Primary

  Silica · CPC title