Semiconductor device structures including silicon-containing dielectric materials
US-10121966-B2 · Nov 6, 2018 · US
US10468595B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10468595-B2 |
| Application number | US-201816164510-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 18, 2018 |
| Priority date | Jul 1, 2013 |
| Publication date | Nov 5, 2019 |
| Grant date | Nov 5, 2019 |
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A method of forming a silicon-containing dielectric material. The method includes forming a plasma comprising nitrogen radicals, absorbing the nitrogen radicals onto a substrate, and exposing the substrate to a silicon-containing precursor in a non-plasma environment to form monolayers of a silicon-containing dielectric material on the substrate. Additional methods are also described, as are semiconductor device structures including the silicon-containing dielectric material and methods of forming the semiconductor device structures.
Opening claim text (preview).
What is claimed is: 1. A semiconductor device comprising: stacks separated from one another by a distance of from 180 Å to 200 Å; and at least one conformal silicon-containing dielectric material adjacent to each of the stacks. 2. The semiconductor device of claim 1 , wherein the at least one conformal silicon-containing dielectric material comprises at least one of a silicon oxide material, a silicon nitride material, a silicon carbon nitride material, or a silicon carbon oxide material. 3. The semiconductor device of claim 1 , wherein the at least one conformal silicon-containing dielectric material comprises at least one of a silicon oxide material or a silicon nitride material. 4. The semiconductor device of claim 3 , wherein the at least one conformal silicon-containing dielectric material further comprises carbon. 5. The semiconductor device of claim 1 , wherein the at least one conformal silicon-containing dielectric material comprises from 30% to 70% silicon, from 4% to 25% carbon, and from 5% to 66% oxygen. 6. The semiconductor device of claim 1 , wherein the at least one conformal silicon-containing dielectric material comprises from 30% to 70% silicon, from 4% to 25% carbon, and from 5% to 66% nitrogen. 7. The semiconductor device of claim 1 , wherein the stacks comprise at least one of a chalcogenide material or a carbon material. 8. The semiconductor device of claim 1 , wherein the at least one conformal silicon-containing dielectric material comprises a thickness of from 10 Å to 1000 Å. 9. A semiconductor device comprising: stacks comprising a carbon material, the stacks separated from one another by a distance of from 50 Å to 220 Å; and at least one conformal silicon-containing dielectric material in contact with the stacks. 10. The semiconductor device of claim 9 , wherein the at least one conformal silicon-containing dielectric material comprises silicon oxide or silicon dioxide. 11. The semiconductor device of claim 10 , wherein the at least one conformal silicon-containing dielectric material further comprises carbon. 12. The semiconductor device of claim 9 , wherein the stacks further comprise a chalcogenide material. 13. The semiconductor device of claim 9 , wherein the at least one conformal silicon-containing dielectric material comprises a first conformal silicon-containing dielectric material in contact with the stacks and a second conformal silicon-containing dielectric material in contact with the first conformal silicon-containing dielectric material. 14. The semiconductor device of claim 13 , further comprising a third conformal silicon-containing dielectric material in contact with the second conformal silicon-containing dielectric material. 15. The semiconductor device of claim 14 , wherein: the first conformal silicon-containing dielectric material comprises a silicon carbon nitride material; the second conformal silicon-containing dielectric material comprises one of a silicon oxide material, a silicon nitride material, or a silicon carbon oxide material; and the third conformal silicon-containing dielectric material comprises one of the silicon oxide material, the silicon nitride material, or the silicon carbon oxide material, the second conformal silicon-containing dielectric material and the third conformal silicon-containing dielectric material comprising different materials. 16. The semiconductor device of claim 14 , wherein the first conformal silicon-containing dielectric material comprises a silicon carbon nitride material, the second conformal silicon-containing dielectric material comprises a silicon nitride material, and the third conformal silicon-containing dielectric material comprises a silicon carbon oxide material. 17. The semiconductor device of claim 9 , wherein the at least one conformal silicon-containing dielectric material decreases the distance between the stacks. 18. A semiconductor device comprising: stacks separated from one another by a distance of from 50 Å to 220 Å; and at least one conformal silicon-containing dielectric material contacting the stacks, the at least one conformal silicon-containing dielectric material comprising from 30% to 70% silicon, from 4% to 25% carbon, and from 5% to 66% oxygen. 19. The semiconductor device of claim 18 , wherein the at least one conformal silicon-containing dielectric material directly contacts the stacks.
the material being a silicon nitride not containing oxygen, e.g. SixNy or SixByNz · CPC title
the material being a silicon oxide, e.g. SiO2 · CPC title
the material containing Si, O and at least one of H, N, C, F or other non-metal elements, e.g. SiOC, SiOC:H or SiONC · CPC title
being a silicon carbide or silicon carbonitride and not containing oxygen, e.g. SiC or SiC:H · CPC title
by exposure to a plasma · CPC title
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