Co2 Z-type ferrite composite material for use in ultra-high frequency antennas

Patent metadata

Field	Value
Publication number	US-10468169-B2
Application number	US-201515329072-A
Country	US
Kind code	B2
Filing date	Jul 31, 2015
Priority date	Jul 31, 2014
Publication date	Nov 5, 2019
Grant date	Nov 5, 2019

Abstract

A ferrite composition is provided containing Ba, Co, and Ir and having a Z-type hexaferrite phase and a Y-type hexaferrite phase. The ferrite composition has the formula Ba 3 Co (2+x) Ir x Fe (24-2x) O 41 where x=0.05-0.20. The composition has equal or substantially equal values of permeability and permittivity while retaining low magnetic and dielectric loss factors. The composition is suitable for ultrahigh frequency applications such as high frequency and microwave antennas.

First claim

What is claimed is:

1. A ferrite composition comprising Ba, Co, Fe, and Ir, wherein said ferrite composition comprises a composite of grains of a Z-type hexaferrite phase and grains of a Y-type hexaferrite phase; wherein the Z-type hexaferrite phase has the formula
Ba 3 CO (2+x) Ir x Fe (24-2x) O 41
where x=0.05-0.20.

2. The ferrite composition of claim 1 , wherein x=0.12-0.15.

3. The ferrite composition of claim 1 , wherein the Z-type hexaferrite phase ranges from 65 vol. % to 97.5 vol %, and the Y-type hexaferrite phase ranges from 2.5 vol. % to 35 vol. %.

4. The ferrite composition of claim 1 , wherein the Z-type hexaferrite phase ranges from 65 vol. % to 97.5 vol %, and the Y-type hexaferrite phase comprises a balance.

5. The ferrite composition of claim 1 , further comprising Bi 2 O 3 ranging from 0.2 to 5.0 wt. %.

6. The ferrite composition of claim 5 , wherein the Bi 2 O 3 is present at grain boundaries of the Z-type hexaferrite phase and the Y-type hexaferrite phase.

7. The ferrite composition of claim 1 , wherein the ferrite composition has a real permittivity ranging from about 7 to about 8.

8. The ferrite composition of claim 1 , wherein the ferrite composition has a real permeability ranging from about 7 to about 8.

9. The ferrite composition of claim 1 , wherein a real permittivity of the ferrite composition is equal to a real permeability of the ferrite composition within 10%.

10. The ferrite composition of claim 1 , wherein the ferrite composition has a characteristic impedance matching an impedance of free space within 3%.

11. The ferrite composition of claim 1 , wherein the ferrite composition has a dielectric loss tangent tan δ ∈ ranging from 0.05 to 0.07 over a frequency range of 0.65 to 0.85 GHz.

12. The ferrite composition of claim 1 , wherein the ferrite composition has a magnetic loss tangent tan δ μ ranging from 0.07 to 0.29 over a frequency range of 0.65 to 0.85 GHz.

13. The ferrite composition of claim 1 , wherein the ferrite composition has a dielectric loss factor tan δ ∈ /∈′=0.008±20% at a frequency of 0.8 GHz.

14. The ferrite composition of claim 1 , wherein the ferrite composition has a magnetic loss factor tan δ μ /μ′=0.037±10% at a frequency of 0.8 GHz.

15. A part comprising the ferrite composition of claim 1 , wherein the part is an antenna, microwave antenna, filter, inductor, circulator, or phase shifter.

16. A method of making a ferrite composition comprising:
(a) providing hexaferrite phase precursor compounds comprising Fe, Ba, Co, and Ir,
(b) calcining the hexaferrite phase precursor compounds in air to form a material comprising a composite of grains of a Z-type hexaferrite phase and grains of a Y-type hexaferrite phase;
wherein the Z-type hexaferrite phase has the formula
Ba 3 Co (2+x) Ir x Fe (24-2x) O 41
where x=0.05-0.20.

17. The method of claim 16 , wherein the hexaferrite phase precursor compounds comprise oxides of Fe, Ba, Co, and Ir.

18. The method of claim 16 , wherein the hexaferrite phase precursor compounds comprise 0.2 to 2 wt. % IrO 2 , 20-25 wt. % BaCO 3 , 5-7 wt. % Co 3 O 4 , and 68-74 wt. % Fe 2 O 3 .

19. The method of claim 16 , wherein in step (b), the precursor compounds are calcined at 1000 to 1200° C. for 2 to 10 hours, and further comprising
(c) crushing the material formed in step (b) to form a powder mixture and forming the powder mixture into a compact; and
(d) sintering the powder mixture at 1250 to 1280° C. for 2 to 10 hours in an oxygen atmosphere.

20. The method of claim 16 , further comprising adding Bi 2 O 3 after step (b), the Bi 2 O 3 ranging from 0.2 to 5.0 wt. %.

21. The method of claim 19 , further comprising adding a binder to the powder mixture, wherein the binder is selected from the group consisting of a polyvinyl alcohol, methyl cellulose, polyethylene glycol, and poly(alkylene carbonate).

22. The method of claim 21 , wherein the powder mixture comprises 8% to 12% by weight of the polyvinyl alcohol.

Assignees

• Rogers Corp

Inventors

• Chen Yajie
• Harris Vincent

Classifications

• H01F1/348

  Hexaferrites with decreased hardness or anisotropy, i.e. with increased permeability in the microwave (GHz) range, e.g. having a hexagonal crystallographic structure · CPC title

• C04B2235/6585

  at an oxygen percentage above that of air · CPC title

• C04B2235/81

  Materials characterised by the absence of phases other than the main phase, i.e. single phase materials · CPC title

• C01G49/0036

  containing one alkaline earth metal, magnesium or lead · CPC title

• C01G49/0018 Primary

  Mixed oxides or hydroxides, (C01G49/0009 takes precedence) · CPC title