Syrup purification by capacitive deionization

Patent metadata

Field	Value
Publication number	US-10463064-B2
Application number	US-201414771315-A
Country	US
Kind code	B2
Filing date	Mar 5, 2014
Priority date	Mar 6, 2013
Publication date	Nov 5, 2019
Grant date	Nov 5, 2019

Abstract

The invention relates to a process for purifying syrups. The process comprises removing charged components from the syrup by passing said syrup through a capacitive deionization cell. The present invention further relates to the use of capacitive deionization to recover charged components from syrups. In particular the syrups are mannose, fructose and sorbitol containing syrups.

First claim

What is claimed is:

1. A process to remove charged components from a syrup comprising:
passing the syrup through a capacitive deionization cell, wherein the specific surface area of the capacitive deionization cell is in the range of 600 to 1100 m 2 /g and the flow rate of syrup through the capacitive deionization cell is from 50 to 100 l/h, and
performing a regeneration step comprising releasing charged components from the capacitive deionization cell into a portion of the syrup by inverting the electrode charge of the capacitive deionization cell to form a syrup enriched in charged components, and
draining the syrup enriched in charged components from the capacitive deionization cell.

2. The process of claim 1 wherein the syrup is a carbohydrate containing syrup and/or a polyol containing syrup.

3. The process of claim 2 , wherein the carbohydrate content or the polyol content of the syrup is from 10 weight/weight % (w/w %) to 90 w/w %.

4. The process of claim 1 , wherein the charged component is one or more of a carbohydrate isomerisation catalyst, a carbohydrate epimerization catalyst, and a carbohydrate hydrogenation catalyst.

5. The process according to claim 1 , further comprising recovering the charged component.

6. The process according to claim 1 , further comprising recycling the charged components by reusing the syrup enriched in charged components in a process for catalytic reaction of a sweetener.

7. The process of claim 1 , wherein the electrical resistivity of the capacitive deionization cell is around 40 mΩ/cm.

8. The process of claim 2 , wherein the carbohydrate content or the polyol content of the syrup is from 20 weight/weight % (w/w %) to 95 w/w %.

9. The process of claim 2 , wherein the carbohydrate content or the polyol content of the syrup is from 25 weight/weight % (w/w %) to 95 w/w %.

10. The process of claim 2 , wherein the carbohydrate content or the polyol content of the syrup is from 70 weight/weight % (w/w %) to 95 w/w %.

11. The process of claim 2 , wherein the carbohydrate content or the polyol content of the syrup is from 75 weight/weight % (w/w %) to 95 w/w %.

12. The process of claim 2 , wherein the carbohydrate content or the polyol content of the syrup is from 80 weight/weight % (w/w %) to 95 w/w %.

13. The process of claim 1 , wherein the conductivity of the syrup at the outlet of the capacitive deionization cell is 10 μS/cm or less.

14. The process of claim 1 , wherein the voltage applied to the capacitive deionization cell is in the range of 0.7 to 1.4 V.

15. A process to remove and recycle charged components from a syrup comprising:
passing a syrup through a capacitive deionization cell to remove charged components to form a purified syrup;
performing a regeneration step comprising releasing charged components from the capacitive deionization cell into a portion of the syrup by inverting the electrode charge of the capacitive deionization cell to form a syrup enriched in charged components;
draining the syrup enriched in charged components from the capacitive deionization cell; and
recycling the charged components by reusing the syrup enriched in charged components in a process for catalytic reaction of a sweetener.

16. The process of claim 15 , wherein the charged component is one or more of a carbohydrate isomerisation catalyst, a carbohydrate epimerization catalyst, and a carbohydrate hydrogenation catalyst.

17. The process of claim 15 , wherein the capacitive deionization cell comprises carbon and the electrical resistivity of the capacitive deionization cell is about 40 mΩ/cm.

18. The process of claim 15 , wherein the specific surface area of the capacitive deionization cell is in the range of 600 to 1100 m 2 /g.

19. The process of claim 15 wherein the syrup is a carbohydrate containing syrup and/or a polyol containing syrup.

20. The process of claim 15 , wherein the catalytic reaction of a sweetener is an isomerization, an epimerisation, or a hydrogenation reaction.

Assignees

• Cargill Inc

Inventors

• Ketsman Joost
• Nataloni Luigi
• Vercauteren Ronny Leontina Marcel

Classifications

• A23L29/37

  Sugar alcohols · CPC title

• A23L7/00

  Cereal-derived products; Malt products; Preparation or treatment thereof (preparation of malt for brewing C12C) · CPC title

• B01D61/44

  Ion-selective electrodialysis · CPC title

• C13B20/18

  by electrical means · CPC title

• A23L5/00 Primary

  Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor · CPC title