Porous bodies with enhanced crush strength

Patent metadata

Field	Value
Publication number	US-10449520-B2
Application number	US-201715834375-A
Country	US
Kind code	B2
Filing date	Dec 7, 2017
Priority date	May 15, 2017
Publication date	Oct 22, 2019
Grant date	Oct 22, 2019

Abstract

A porous body with enhanced fluid transport properties and crush strength is provided. The porous body includes the porous body includes at least 80 percent alpha alumina and having a pore volume from 0.3 mL/g to 1.2 mL/g, a surface area from 0.3 m2/g to 3.0 m2/g, and a pore architecture that provides at least one of a tortuosity of 7 or less, a constriction of 4 or less and a permeability of 30 mdarcys or greater, wherein the porous body is a cylinder comprising at least two spaced apart holes that extend through an entire length of the cylinder. The porous body has a flat plate crush strength improved by more than 10% over a porous body cylinder having a same outer diameter and length, but having only a single hole.

First claim

What is claimed is:

1. A porous body comprising:
at least 80 percent alpha alumina and having a pore volume from 0.3 mL/g to 1.2 mL/g, a surface area from 0.3 m 2 /g to 3.0 m 2 /g, and a pore architecture that provides at least one of a tortuosity of 7 or less, a constriction of 4 or less and a permeability of 30 mdarcys or greater, wherein said porous body is a cylinder comprising at least two spaced apart holes that extend through an entire length of the cylinder.

2. The porous body of claim 1 , wherein said cylinder comprises three spaced apart holes that extend through said entire length of said cylinder.

3. The porous body of claim 1 , wherein said cylinder comprises five spaced apart holes that extend through said entire length of said cylinder.

4. The porous body of claim 1 , wherein said cylinder comprises seven spaced apart holes that extend through said entire length of said cylinder.

5. The porous body of claim 1 , wherein said cylinder has an outer diameter of from about 4 to about 10 millimeters, said length of said cylinders is about the same as said outer diameter, and said cylinder comprises three to twenty spaced apart holes that extend through said entire length of said cylinder.

6. The porous body of claim 1 , wherein each hole has an inner diameter from about 0.2 millimeters to about 30 millimeters.

7. The porous body of claim 6 , wherein each cylinder has an outer diameter from about 1 millimeter to about 100 millimeters and said length of said cylinders is from about 1 millimeter to about 100 millimeters.

8. The porous body of claim 1 , wherein said porous body has an average flat plate crush strength of at least 60 N.

9. The porous body of claim 1 , wherein said porous body has an average flat plate crush strength improved more than 10% over a porous body cylinder with a single hole and the same outer diameter and length.

10. The porous body of claim 1 , wherein said pore architecture provides said tortuosity and said constriction.

11. A silver-based epoxidation catalyst comprising:
a porous body comprises at least 80 percent alpha alumina and having a pore volume from 0.3 mL/g to 1.2 mL/g, a surface area from 0.3 m 2 /g to 3.0 m 2 /g, and a pore architecture that provides at least one of a tortuosity of 7 or less, a constriction of 4 or less and a permeability of 30 mdarcys or greater, wherein said porous body is a cylinder comprising at least two spaced apart holes that extend through an entire length of the cylinder;
a catalytic amount of silver disposed on and/or in said porous body; and
a promoting amount of one or more promoters disposed on said porous body.

12. The silver-based ethylene epoxidation catalyst of claim 11 , wherein said one or more promoters comprise Group 1 alkali metal promoters, one or more transition metals, one or more Group 2 alkaline earth metals or any combination thereof.

13. The silver-based ethylene epoxidation catalyst of claim 12 , wherein said one or more transition metals are selected from the group consisting of Groups 4-10 of the Periodic Table of the Elements.

14. The silver-based ethylene epoxidation catalyst of claim 13 , wherein said one or more transition metals are selected from the group consisting of molybdenum, rhenium, tungsten, chromium, titanium, hafnium, zirconium, vanadium, thorium, tantalum, and niobium.

15. The silver-based ethylene epoxidation catalyst of claim 12 , wherein said one or more transition metals comprise rhenium, molybdenum, tungsten, or any combination thereof.

16. The silver-based ethylene epoxidation catalyst of claim 12 , wherein said Group 1 alkali metal promoters are selected from the group consisting of cesium, lithium, sodium, potassium, and rubidium.

17. The silver-based ethylene epoxidation catalyst of claim 16 , wherein said Group 1 alkali metal promoters comprise lithium and cesium.

18. The silver-based ethylene epoxidation catalyst of claim 11 , wherein said one or more promoters comprises a promoting combination of rhenium, cesium and lithium.

19. The silver-based ethylene epoxidation catalyst of claim 11 , wherein said catalytic amount of silver is from 10 to 50% by weight.

20. The silver-based ethylene epoxidation catalyst of claim 11 , wherein at least 90 percent of said pore volume is attributed to a pore size of 20 microns or less.

21. The silver-based ethylene epoxidation catalyst of claim 11 , wherein at least 85 percent of said pore volume is attributed to pores having a size from 1 micron to 6 microns.

22. The silver-based ethylene epoxidation catalyst of claim 11 , wherein less than 15 percent of said pore volume is attributed to pores having a size of less than 1 micron.

23. The silver-based ethylene epoxidation catalyst of claim 11 , wherein at least 80 percent of said pore volume is attributed to pores having a size from 1 micron to 10 microns.

24. The silver-based ethylene epoxidation catalyst of claim 11 , wherein said porous body has a silica content, as measured as SiO 2 , of less than 0.2 weight percent, and a sodium content, as measured as Na 2 O, of less than 0.2 weight percent.

25. The silver-based ethylene epoxidation catalyst of claim 11 , wherein said porous body has a water washing acid leachable sodium content of 40 ppm or less.

26. The silver-based ethylene epoxidation catalyst of claim 11 , wherein said porous body has alumina crystallites having a platelet morphology in a content of less than 20 percent by volume.

27. The silver-based ethylene epoxidation catalyst of claim 11 , wherein said pore architecture provides said tortuosity and said constriction.

28. A catalyst composition comprising:
porous body comprises at least 80 percent alpha alumina and having a pore volume from 0.3 mL/g to 1.2 mL/g, a surface area from 0.3 m 2 /g to 3.0 m 2 /g, and a pore architecture that provides at least one of a tortuosity of 7 or less, a constriction of 4 or less and a permeability of 30 mdarcys or greater, wherein said porous body is a cylinder comprising at least two spaced apart holes that extend through an entire length of the cylinder; and
a catalytic amount of at least one catalytically active material disposed on and/or in said porous body.

Assignees

• Scient Design Co

Inventors

• Suchanek Wojciech L
• Di Mare Michael
• Adam Jean
• Ellis Jr Paul E

Classifications

• B01D71/025

  Aluminium oxide · CPC title

• B01J23/50

  Silver · CPC title

• B01J23/8986

  with manganese, technetium or rhenium · CPC title

• B01D63/066

  with a porous block having membrane coated passages · CPC title

• B01J21/12

  Silica and alumina · CPC title