Catalyst for the epoxidation of oelfins

Patent metadata

Field	Value
Publication number	US-9339798-B2
Application number	US-201514788861-A
Country	US
Kind code	B2
Filing date	Jul 1, 2015
Priority date	Oct 14, 2011
Publication date	May 17, 2016
Grant date	May 17, 2016

Abstract

The carrier of the present invention includes at least 85 wt percent alpha alumina, at least 0.06 wt percent SiO 2 and no more than 0.04 wt percent Na 2 O. The carrier has a water absorption no greater than 0.35 g/g and a ratio of water absorption (g/g) to surface area (m 2 /g) no greater than 0.50 g/m 2 . Another aspect of the invention is a catalyst for the epoxidation of olefins which comprises the above described carrier and silver dispersed thereon, where the carrier has a monomodal, bimodal or multimodal pore distribution and where the quantity of silver is between 5 and 50 wt/%, relative to the weight of the catalyst. A reactor system for the epoxidation of olefins is also disclosed.

First claim

What is claimed is:

1. A catalyst for the epoxidation of olefins comprising a carrier and silver dispersed thereon, said carrier comprising at least 85 wt percent alpha alumina, at least 0.06 wt percent SiO 2 and no more than 0.04 wt percent Na 2 O, said carrier comprising a water absorption no greater than 0.35 gram of water/gram of carrier and a ratio of water absorption (gram of water/gram of carrier) to surface area (m 2 of carrier/gram of carrier) no greater than 0.50 gram of water/m 2 of carrier.

2. The catalyst of claim 1 wherein the carrier has a monomodal, bimodal or multimodal pore distribution.

3. The catalyst of claim 1 wherein the quantity of said silver is between 5 and 50 wt %, relative to the weight of the catalyst.

4. The catalyst of claim 3 wherein said catalyst further comprises a rhenium promoter, a first co-promoter and a second co-promoter, wherein the first co-promoter is selected from sulfur, phosphorus, boron, and mixtures thereof; and the second co-promoter is selected from tungsten, molybdenum, chromium, and mixtures thereof.

5. The catalyst of claim 4 wherein the rhenium promoter is present in a quantity in the range of from 0.1 to 50 mmole/kg, relative to the weight of the catalyst.

6. The catalyst of claim 5 wherein the first co-promoter is sulfur and the second co-promoter is tungsten, and wherein the first co-promoter is present in a quantity in the range of from 0.2 to 50 mmole/kg, relative to the weight of the catalyst and the second co-promoter is present in a quantity in the range of from 0.1 to 40 mmole/kg, relative to the weight of the catalyst.

7. The catalyst of claim 6 wherein the molar ratio of the first co-promoter to the second co-promoter is no greater than 1.

8. The catalyst of claim 7 wherein the catalyst further comprises a further element selected from the group consisting of nitrogen, fluorine, alkali metals, alkaline earth metals, titanium, hafnium, zirconium, vanadium, thallium, thorium, tantalum, niobium, gallium, germanium, and mixtures thereof.

9. The catalyst of claim 8 wherein said catalyst further comprises cesium, lithium and potassium.

10. The catalyst of claim 9 wherein said cesium is present in a quantity in the range of from 0.2 to 50 mmole/kg, relative to the weight of the catalyst; said lithium is present in a quantity in the range of from 0.2 to 50 mmole/kg, relative to the weight of the catalyst; and said potassium is present in a quantity in the range of from 0.2 to 50 mmole/kg, relative to the weight of the catalyst.

11. The catalyst of claim 1 wherein the quantity of said silver relative to the volume of a packed bed of catalyst is between 50 and 500 kg/m3.

Assignees

• Saint Gobain Ceramics

Inventors

• Richard Michael A
• Lockemeyer John R

Classifications

• B01J23/50

  Silver · CPC title

• B01J27/055

  with alkali metals, copper, gold or silver · CPC title

• C07D301/10 Primary

  with catalysts containing silver or gold · CPC title

• B01J21/04

  Alumina · CPC title

• C07D301/04

  with air or molecular oxygen · CPC title