Optical monitoring of battery health

Patent metadata

Field	Value
Publication number	US-10439255-B2
Application number	US-201314414984-A
Country	US
Kind code	B2
Filing date	Aug 9, 2013
Priority date	Aug 10, 2012
Publication date	Oct 8, 2019
Grant date	Oct 8, 2019

Abstract

Light is transmitted through or from a separator of a battery cell or scattered within a battery cell and received by one or more light detectors. The light that is normally transmitted through the separator is scattered, absorbed, wavelength-shifted or otherwise distorted by an impending fault in the vicinity of or within the separator. The change in light due to the impending fault is measured by a detector and a signal from the detector is processed to identify the impending fault so that a warning can be generated indicative of the impending fault.

First claim

What is claimed is:

1. A battery structure for monitoring development of impending faults of a battery cell comprising:
a battery cell separator formed of a light transmitting material that has light transmission characteristics that are a function of a state of at least one impending fault of the battery cell including said separator;
a first optical fiber positioned in optical communication with the battery cell separator to transmit light into said separator and being integrated into said separator;
a second optical fiber positioned in optical communication with the battery cell separator to receive light transmitted through said separator and being integrated into said separator;
a light source coupled to said first optical fiber; and
a light detector coupled to said second optical fiber;
wherein an impending fault state of a first portion of said battery cell associated with said second optical fiber is determined based on the light transmitted through said separator.

2. The battery structure for monitoring the development of impending faults of the battery cell of claim 1 wherein the cell separator is formed as a gelled polymer membrane.

3. The battery structure for monitoring the development of impending faults of the battery cell of claim 1 wherein the cell separator is formed as a porous polyolefin drawn to produce a highly porous membrane.

4. The battery structure for monitoring the development of impending faults of the battery cell of claim 3 wherein an associated electrolyte is selected so that a refractive index of the associated electrolyte is within a range corresponding to a range of a refractive index of the highly porous membrane.

5. The battery structure for monitoring the development of impending faults of the battery cell of claim 4 wherein the associated electrolyte is an ionic liquid.

6. The battery structure for monitoring the development of impending faults of the battery cell of claim 1 further comprising:
a third optical fiber positioned in optical communication with the battery cell separator to receive light transmitted through said separator and being integrated into said separator; and
a light detector coupled to said third optical fiber;
wherein an impending fault state of a second portion of said battery cell associated with said third optical fiber is determined based on the light transmitted through said separator.

7. The battery structure for monitoring the development of impending faults of the battery cell of claim 1 further comprising an outer layer on at least one side of said separator imparting waveguide characteristics to said separator.

8. The battery structure for monitoring the development of impending faults of the battery cell of claim 7 wherein the at least one side of the separator includes spaced apart regions of reduced porosity.

9. The battery structure for monitoring the development of impending faults of the battery cell of claim 8 wherein spacing between the regions of reduced porosity are of the same order of magnitude or smaller than fault structures to be detected.

10. The battery structure for monitoring the development of impending faults of the battery cell of claim 7 further comprising an outer layer on first and second sides of said separator imparting waveguide characteristics to said separator.

11. The battery structure for monitoring the development of impending faults of the battery cell of claim 7 wherein said outer layer comprises a material having a refractive index lower than a refractive index of a core of said separator.

12. A method for monitoring a fault state of a battery cell comprising:
forming a battery cell separator from a light transmitting material having light transmission characteristics that are a function of at least one impending fault of the battery cell including said separator;
providing a first optical fiber for transmitting light into said separator;
providing a second optical fiber for receiving light transmitted through said separator;
coupling a light source to said first optical fiber;
coupling a light detector to said second optical fiber; and
determining an impending fault state of a first portion of said battery cell associated with said second optical fiber from an output of said light detector.

13. The method for monitoring the fault state of a battery as claimed in claim 12 further comprising:
providing a third optical fiber for receiving light transmitted through said separator;
coupling a light detector to said third optical fiber; and
determining an impending fault state of a second portion of said battery cell associated with said third optical fiber from an output of said light detector coupled to said third optical fiber.

14. The method for monitoring the fault state of a battery as claimed in claim 12 further comprising forming an outer layer on at least one side of said separator to impart waveguide characteristics to said separator.

15. The method for monitoring the fault state of a battery as claimed in claim 14 further comprising forming an outer layer on first and second sides of said separator to impart waveguide characteristics to said separator.

16. The method for monitoring the fault state of a battery as claimed in claim 14 further comprising forming said outer layer of a material to have a refractive index lower than a refractive index of a core of said separator.

17. A battery structure for monitoring development of impending faults of a battery cell comprising:
a battery cell separator formed of a light transmitting material that has light scattering characteristics that are a function of the state of at least one impending fault of the battery cell including said separator;
a first optical fiber positioned in optical communication with the battery cell separator to transmit light into said separator and being integrated into said separator;
a second optical fiber positioned in optical communication with the battery cell separator to receive light scattered within said separator and being integrated into said separator;
a light source coupled to said first optical fiber; and
a light detector coupled to said second optical fiber;
wherein an impending fault state of a first portion of said battery cell associated with said second optical fiber is determined based on the light scattered within said separator.

18. The battery structure for monitoring the development of impending faults of the battery cell of claim 17 wherein said light transmitting material also has light transmission characteristics that are a function of the state of the at least one impending fault of the battery cell including said separator and further comprising:
a third optical fiber positioned in optical communication with the battery cell separator to receive light transmitted through said separator and being integrated into said separator; and
a light detector coupled to said third optical fiber;
wherein an impending fault state of a second portion of said battery cell associated with said third optical fiber is determined based on the light transmitted through the separator.

19. The battery structure for monitoring the development of impending faults of the battery cell of claim 17 wherein the second optical fiber receives light scattered at a sharp angle relative to an original light propagation direction within said separator.

20. The battery structure for monitoring the development of impending faults of the battery cell of claim 17 wherein the cell separator is form

Assignees

• Battelle Memorial Institute

Inventors

• Dvorsky James E
• Risser Steven M
• Saunders James H
• Morrow Alexander C
• Nippa David W

Classifications

• H01M10/48 Primary

  Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte (constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569) · CPC title

• H01M50/457

  comprising three or more layers · CPC title

• H01M50/417

  Polyolefins · CPC title

• H01M50/491

  Porosity · CPC title

• G01R1/07

  Non contact-making probes · CPC title