Lithographic printing plate precursor, method of preparing lithographic printing plate, and lithographic printing method

Patent metadata

Field	Value
Publication number	US-10427443-B2
Application number	US-201916382196-A
Country	US
Kind code	B2
Filing date	Apr 12, 2019
Priority date	Sep 29, 2017
Publication date	Oct 1, 2019
Grant date	Oct 1, 2019

Abstract

Provided are a lithographic printing plate precursor including an aluminum support, and an image recording layer on the aluminum support, in which the aluminum support includes an anodized film on a surface of the image recording layer side, the anodized film has micropores extending in a depth direction from the surface of the anodized film on the image recording layer side, an average pore diameter of the micropores in the surface of the anodized film is greater than 0 μm and 0.03 μm or less, an average maximum diameter of the micropores inside the anodized film is in a range of 0.04 μm to 0.30 μm, an average value A nm of thicknesses of surface opening portions and an average value B nm of thicknesses of internal maximum diameter portions satisfy a relationship of 2.5≤B/A≤28.0, and the image recording layer contains an acid color former; a method of preparing a lithographic printing plate using the lithographic printing plate precursor; and a lithographic printing method.

First claim

What is claimed is:

1. A lithographic printing plate precursor comprising:
an aluminum support; and
an image recording layer on the aluminum support,
wherein the aluminum support includes an anodized film on a surface of the image recording layer side,
the anodized film has micropores extending in a depth direction from the surface of the anodized film on the image recording layer side,
an average pore diameter of the micropores in the surface of the anodized film is greater than 0 μm and 0.03 μm or less,
an average maximum diameter of the micropores inside the anodized film is in a range of 0.04 μm to 0.30 μm,
an average value A nm of thicknesses of surface opening portions starting from the surface of the anodized film and having a pore diameter inside the anodized film of greater than 0 μm and 0.03 μm or less and an average value B nm of thicknesses of internal maximum diameter portions in which pore diameters of the micropores inside the anodized film are in a range of 0.04 μm to 0.30 μm satisfy a relationship of 2.5≤B/A≤28.0,
the average value B of thicknesses of the internal maximum diameter portions is in a range of 500 nm to 2800 nm, and
the image recording layer contains an acid color former.

2. The lithographic printing plate precursor according to claim 1 ,
wherein the average value A of the thicknesses of the surface opening portions is in a range of 10 nm to 200 nm.

3. A lithographic printing plate precursor comprising:
an aluminum support; and
an image recording layer on the aluminum support,
wherein the aluminum support includes an anodized film on a surface of the image recording layer side,
the anodized film has micropores extending in a depth direction from the surface of the anodized film on the image recording layer side,
the micropores include at least large-diameter pores whose maximum diameter inside the anodized film is in a range of 0.01 um to 0.30 um,
an average pore diameter of the micropores in the surface of the anodized film is 90% or less of the maximum diameter of the micropores inside the anodized film,
a thickness of the anodized film is in a range of 550 nm to 2850 nm, and
the image recording layer contains an acid color former.

4. The lithographic printing plate precursor according to claim 3 ,
wherein the micropores are micropores which further include small-diameter pores communicating with a bottom of the large-diameter pores, extending in the depth direction from a communication position, and having an average pore diameter of 0.01 μm or less and in which the pore diameters of the small-diameter pores in the communication position are smaller than the pore diameters of the large-diameter pores in the communication position.

5. The lithographic printing plate precursor according to claim 3 ,
wherein an average value of depths of the large-diameter pores to the bottom from the surface of the anodized film is in a range of 5 nm to 400 nm.

6. The lithographic printing plate precursor according to claim 3 ,
wherein the acid color former is a leuco dye.

7. The lithographic printing plate precursor according to claim 3 ,
wherein the image recording layer further contains an acid generator.

8. The lithographic printing plate precursor according to claim 7 ,
wherein the acid generator contains an organic borate compound.

9. The lithographic printing plate precursor according to claim 3 ,
wherein a value of a brightness L* in an L*a*b* color system of the surface of the anodized film on the image recording layer side is in a range of 70 to 100.

10. The lithographic printing plate precursor according to claim 3 ,
wherein a value of a brightness L* in an L*a*b* color system of the surface of the anodized film on the image recording layer side is in a range of 72 to 90.

11. The lithographic printing plate precursor according to claim 3 ,
wherein a steepness a45 representing an area ratio of a portion having an inclining degree of 45° or greater obtained by extracting a component with a wavelength of 0.2 μm to 2 in the surface of the anodized film on the image recording layer side in a frequency distribution based on fast Fourier transformation of three-dimensional data obtained by performing measurement using an atomic force microscope is 30% or less.

12. The lithographic printing plate precursor according to claim 3 ,
wherein an amount of the image recording layer is in a range of 0.5 g/m 2 to 2.5 g/m 2 .

13. The lithographic printing plate precursor according to claim 3 ,
wherein a thickness X μm of the anodized film and a total amount Y g/m 2 of all layers formed on the aluminum support satisfy a relationship of Expression 1
Y≥− 1.19 X+ 2.6  Expression 1.

14. The lithographic printing plate precursor according to claim 3 ,
wherein the image recording layer contains thermoplastic polymer particles, and
the thermoplastic polymer particles are formed of a copolymer of a styrene-(meth)acrylonitrile-poly(ethylene glycol)monoalkyl ether (meth)acrylate compound.

15. The lithographic printing plate precursor according to claim 3 ,
wherein an overcoat layer containing a water-soluble polymer is provided on the image recording layer.

16. The lithographic printing plate precursor according to claim 15 ,
wherein the overcoat layer contains hydroxyalkyl cellulose.

17. The lithographic printing plate precursor according to claim 3 , which is a lithographic printing plate precursor for on-press development.

18. A method of preparing a lithographic printing plate, comprising:
a step of imagewise-exposing the lithographic printing plate precursor according to claim 3 ; and
a step of supplying at least any of printing ink or dampening water and removing an image recording layer in a non-image area on a printing press.

19. A lithographic printing method comprising:
a step of imagewise-exposing the lithographic printing plate precursor according to claim 3 ;
a step of supplying at least any of printing ink or dampening water and removing a non-image area of an image recording layer on a printing press to prepare a lithographic printing plate; and
a step of performing printing using the obtained lithographic printing plate.

Assignees

• Fujifilm Corp

Inventors

• Kudo Kotaro

Classifications

• B41N1/083 Primary

  made of aluminium or aluminium alloys or having such surface layers (B41N1/086 takes precedence) · CPC title

• B41M1/06

  Lithographic printing · CPC title

• B41C2210/24

  characterised by a macromolecular compound or binder obtained by reactions involving carbon-to-carbon unsaturated bonds, e.g. acrylics, vinyl polymers · CPC title

• B41C2210/08

  Developable by water or the fountain solution · CPC title

• B41C2210/04

  Negative working, i.e. the non-exposed (non-imaged) areas are removed · CPC title