Toughened bond layer and method of production

Patent metadata

Field	Value
Publication number	US-10414694-B2
Application number	US-201815946550-A
Country	US
Kind code	B2
Filing date	Apr 5, 2018
Priority date	Feb 17, 2015
Publication date	Sep 17, 2019
Grant date	Sep 17, 2019

Abstract

According to one embodiment of this disclosure, a coating includes a plurality of elongated reinforcing materials. The coating includes a bond coat in which a first portion of a first elongated reinforcing material is embedded. The coating further includes a ceramic coat adjacent the bond coat in which a second portion of the first elongated reinforcing material is embedded.

First claim

The invention claimed is:

1. A method of coating a component comprising the steps of:
depositing a bond coat formed from a metal alloy on an outer surface of the component, wherein the bond coat extends from an inner surface bonded to the outer surface of the component to an outer surface, the inner surface and the outer surface of the bond coat defining a first thickness of the bond coat wherein the bond coat comprises a plurality of elongated reinforcing materials disposed throughout the metal alloy;
removing a layer of the bond coat on a side of the bond coat opposite the component so that a first portion of a first elongated reinforcing material is embedded within the bond coat and a second portion of the elongated reinforcing material protrudes from the outer surface of the bond coat; and
depositing a ceramic coat on the outer surface of the bond coat and the second portion of the elongated reinforcing material, so that the second portion of the first elongated reinforcing material is embedded within the ceramic coat.

2. The method of claim 1 , wherein the first portion of the first elongated reinforcing material protrudes from the outer surface of the bond coat between about 1 micron and about 10 microns.

3. The method of claim 1 , wherein the step of removing the layer of the bond coat is performed using a process selected from the group consisting of: chemical etching or plasma etching, and combinations thereof.

4. The method of claim 1 , and further comprising:
forming an oxide layer between the bond coat and the ceramic coat so that a third portion of the first elongated reinforcing material is embedded in the oxide layer.

5. The method of claim 1 , and further comprising:
heat treating the bond coat.

6. The method of claim 1 , wherein the ceramic coat is deposited on the bond coat using a process selected from the group consisting of: plasma spray, electron beam, high velocity air fuel deposition, high velocity oxygen fuel deposition, electron beam physical vapor deposition, cathodic arc, and combinations thereof.

7. The method of claim 1 , wherein the ceramic coat is a thermal barrier coating or an environmental barrier coating.

8. The method of claim 1 , wherein the elongated reinforcing materials comprise a material selected from the group consisting of: alumina, zirconia, titanium diboride, zirconia diboride, silicon carbide, tungsten, tungsten carbide, boron nitride, silicon nitride, and combinations thereof.

9. The method of claim 1 , wherein the elongated reinforcing materials comprise between about two percent and about twenty percent of the total volume of the component coating.

10. The method of claim 1 , wherein a length to diameter ratio of each of the plurality of elongated reinforcing materials ranges from about 3:1 to 20:1.

11. The method of claim 1 and further comprising:
forming the bond coat by mechanically alloying a mixture of an MCrAlY alloy powder and the elongated reinforcing materials.

12. The method of claim 11 , wherein the step of depositing the bond coat on the outer surface of the component is performed using a process selected from the group consisting of: low pressure plasma spray, electron beam physical vapor deposition, electron beam directed vapor deposition, high velocity air fuel deposition, high velocity oxygen fuel deposition, and combinations thereof.

13. The method of claim 12 , wherein the elongated reinforcing materials are randomly oriented within the bond coat.

14. The method of claim 1 and further comprising:
forming the bond coat by forming a slurry of an MCrAlY alloy powder and the elongated reinforcing materials.

15. The method of claim 14 , wherein the step of depositing the bond coat on the outer surface of the component is performed using a slurry deposition process.

16. The method of claim 15 , wherein the elongated reinforcing materials are randomly oriented within the bond coat.

17. The method of claim 1 and further comprising:
forming the bond coat by forming a colloidal suspension of an MCrAlY powder and the elongated reinforcing materials.

18. The method of claim 17 , wherein the step of depositing the bond coat on the outer surface of the component is performed using electrophoretic deposition.

19. The method of claim 18 , wherein the elongated reinforcing materials are uniformly oriented within the bond coat.

20. A method of coating a component comprising the steps of:
depositing a bond coat formed from a metal alloy on an outer surface of the component, wherein the bond coat extends from an inner surface bonded to the outer surface of the component to an outer surface, the inner surface and the outer surface of the bond coat defining a first thickness of the bond coat wherein the bond coat comprises a plurality of elongated reinforcing materials disposed throughout the metal alloy;
removing a layer of the bond coat on a side of the bond coat opposite the component so that a first portion of a first elongated reinforcing material is embedded within the bond coat and a second portion of the elongated reinforcing material protrudes from the outer surface of the bond coat; and
forming an oxide layer proximate the outer surface of the bond coat so that a third portion of the first elongated reinforcing material is embedded in the oxide layer.

Assignees

• United Technologies Corp

Inventors

• Strock Christopher W
• Martin Thomas J
• Staroselsky Alexander
• Mironets Sergey

Classifications

• C23C28/345

  with at least one oxide layer · CPC title

• F05D2230/90

  Coating; Surface treatment · CPC title

• C23C24/085

  Coating with metallic material, i.e. metals or metal alloys, optionally comprising hard particles, e.g. oxides, carbides or nitrides · CPC title

• C23C14/22

  characterised by the process of coating · CPC title

• C04B35/62222 Primary

  obtaining ceramic coatings (coating of mortars, concrete, artificial or natural stone or ceramics C04B41/45; laminated ceramic products B32B18/00; coating of glass C03C17/00, applying ceramic coatings on silicon for semi-conductor purposes H10W; coating metallic materials C23) · CPC title