Method for the cryogenic fractionation of air and air fractionation plant

Patent metadata

Field	Value
Publication number	US-10041729-B2
Application number	US-201514828568-A
Country	US
Kind code	B2
Filing date	Aug 18, 2015
Priority date	Sep 2, 2014
Publication date	Aug 7, 2018
Grant date	Aug 7, 2018

Abstract

A method for the cryogenic fractionation of air, in which a liquid volume present in a vaporization chamber in a distillation column system of an air fractionation plant is fed by means of a cryogenic liquid and in which a proportion of the liquid volume is continuously transferred into the gas phase by vaporization, wherein, in addition to oxygen, the cryogenic liquid contains components, including xenon, which are higher-boiling than oxygen. The content of xenon in the cryogenic liquid is determined and used as a measure of any enrichment of the components which are higher-boiling than oxygen in the cryogenic liquid. A corresponding air fractionation plant is also described.

First claim

The invention claimed is:

1. A method for cryogenic fractionation of air, said method comprising:
fractionating air in a distillation column system of an air fractionation plant to obtain a cryogenic liquid containing oxygen;
feeding said cryogenic liquid containing oxygen into a liquid volume present in a vaporization chamber in said distillation column system of said air fractionation plant, and
continuously transferring a proportion of the liquid volume into the gas phase by vaporization, wherein, in addition to oxygen, said cryogenic liquid contains xenon and at least one further component having a boiling point higher than the boiling point of oxygen, and
determining the content of xenon in the liquid volume and using the determined content of xenon as a measure of the content in the liquid volume of said at least one further component having a boiling point higher than the boiling point of oxygen in the liquid volume.

2. The method according to claim 1 , further comprising withdrawing at least one stream withdrawn in liquid form from the liquid volume wherein the flow rate of said at least one stream is selected based on the determination of the content of xenon.

3. The method according to claim 1 , wherein said distillation column system comprises a high-pressure column and a low-pressure column.

4. The method according to claim 3 , in which said vaporization chamber is a vaporization chamber of a main condenser which provides a heat-exchanging connection between the high-pressure column and the low-pressure column.

5. The method according to claim 3 , wherein said distillation column system further comprises a crude argon column and said vaporization chamber is a vaporization chamber of a top condenser of the crude argon column.

6. The method according to claim 3 , wherein said distillation column system further comprises a pure argon column and said vaporization chamber is a vaporization chamber of a top condenser of the pure argon column.

7. The method according to claim 3 , in which the cryogenic liquid is formed from a fluid which is drawn off in liquid form from the high-pressure column and then transferred into the vaporization chamber.

8. The method according to claim 1 , wherein said distillation column system comprises a krypton/xenon enrichment column, and said vaporization chamber is the bottom of the krypton/xenon enrichment column.

9. The method according to claim 8 , wherein said at least one further component having a boiling point higher than the boiling point of oxygen whose content in the liquid volume is measured based on the content of xenon is at least one hydrocarbon and the measured content of said at least one hydrocarbon is used as a measure of a purity of the air fractionated in the air fractionation plant.

10. The method according to claim 8 , wherein said at least one further component having a boiling point higher than the boiling point of oxygen whose content in the liquid volume is measured based on the content of xenon is carbon dioxide and/or nitrous oxide and the measured content of carbon dioxide and/or nitrous oxide is used for ascertaining the functionality of at least one air purification device of the air fractionation plant.

11. The method according to claim 1 , in which a proportion of the liquid volume corresponding to 0.1 to 1 percent by volume of the air used to obtain the cryogenic liquid is continuously or intermittently drawn off from the vaporization chamber.

12. The method according to claim 11 , in which the proportion of the liquid volume which is continuously or periodically drawn off from the vaporization chamber is adjusted on the basis of the content of xenon.

13. The method according to claim 1 , in which the content of xenon is determined by means of gas chromatography.

14. The method according to claim 13 , in which the content of xenon is determined by using a conductivity detector.

15. The method according to claim 4 , wherein said cryogenic liquid is formed from a fluid withdrawn in liquid form from the high-pressure column and then transferred into said vaporization chamber.

16. The method according to claim 1 , wherein said at least further component having a boiling point higher than the boiling point of oxygen in the liquid volume is nitrous oxide, carbon dioxide or at least one hydrocarbon.

17. The method according to claim 1 , further comprising withdrawing at least one stream withdrawn in liquid form from the liquid volume and adjusting the amount of said at least one stream withdrawn on the basis of the determination of the content of xenon.

18. The method according to claim 4 , wherein said main condenser is arranged outside of the high-pressure column and the low-pressure column.

19. A method for cryogenic fractionation of air, said method comprising:
fractionating air in a distillation column system of an air fractionation plant to obtain a cryogenic liquid containing oxygen;
feeding said cryogenic liquid containing oxygen into a liquid volume present in a vaporization chamber in said distillation column system of said air fractionation plant, and
continuously transferring a proportion of the liquid volume into the gas phase by vaporization, wherein, in addition to oxygen, said cryogenic liquid contains xenon and at least one further component having a boiling point higher than the boiling point of oxygen, and
determining the content of xenon in the liquid volume and using the determined content of xenon to determine the amount of enrichment in the liquid volume of at least one further component having a boiling point higher than the boiling point of oxygen in the liquid volume, in comparison to the amount of said at least one further component in the air fed to said distillation column system.

Assignees

• Linde Ag

Inventors

• Meilinger Matthias

Classifications

• F25J3/04412 Primary

  in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column · CPC title

• F25J3/04654

  Producing crude argon in a crude argon column · CPC title

• F25J3/0486

  of vaporisers for oxygen enriched liquids, e.g. purging of liquids · CPC title

• F25J2280/02

  Control in general, load changes, different modes ("runs"), measurements · CPC title

• G01N33/0036

  specially adapted to detect a particular component (physical analysis of gaseous biological material G01N33/497) · CPC title