Systems and methods for using cold liquid to remove solidifiable gas components from process gas streams

Patent metadata

Field	Value
Publication number	US-10408534-B2
Application number	US-201113575907-A
Country	US
Kind code	B2
Filing date	Jan 5, 2011
Priority date	Feb 3, 2010
Publication date	Sep 10, 2019
Grant date	Sep 10, 2019

Abstract

Systems and methods are described for re-moving solidifiable gas from a process gas stream by direct contact with a cold liquid. The process gas stream includes at least gas that is frozen by the cold liquid while one or more other gases of the process gas stream remain in a gaseous state. The process gas stream may include water, and will have a different composition than the cold liquid. The contacting of the cold liquid with the process gas stream may be at a pressure that is less than 200 psia, and optionally less than 100 psia, 50 psia, or even 30 psia, and the solidified gas may be removed from the contacting assembly as a slurry with cold liquid.

First claim

We claim:

1. A method for removing a solidifiable gas component from a process gas stream, the method comprising:
(a) contacting in a countercurrent manner in two or more equilibrium stages in a contacting assembly a process gas stream containing a solidifiable gas component with a cold liquid to form a liquid-solid slurry containing the cold liquid and solids formed by solidifying at least a portion of the solidifiable gas component in the process gas stream, wherein the contacting in each stage occurs at a contacting temperature for that stage and a contacting pressure for that stage;
wherein:
the cold liquid is a liquid at the contacting temperature and contacting pressure for each stage and wherein the cold liquid is a liquid at a temperature of 20° C. and a pressure of 1 atmosphere;
the contacting further forms a treated gas stream containing a portion of the process gas stream that was not solidified by the contacting with the cold liquid;
the cold liquid is at a temperature at which the solidifiable gas component within the process gas stream will transition to a solid phase;
the cold liquid has a different composition than the solidifiable gas component; and
the process gas stream includes at least one gas component that remains in a gas phase at the contacting temperature and the contacting pressure; and
wherein the contacting in at least one of the two or more equilibrium stages occurs at a contacting temperature of less than −100° C. and a contacting pressure of less than 100 psia; and
wherein the contacting in at least one other of the two or more equilibrium stages occurs at a contacting temperature of less than −80° C. and a contacting pressure of less than 100 psia; and

(b) removing at least a portion of the solids from the slurry,
wherein the removing step is performed mechanically and removal occurs between at least one set of adjacent equilibrium stages.

2. The method of claim 1 , wherein the solidifiable gas component is selected from the group consisting of carbon dioxide, hydrogen sulfide, sulfur dioxide, or carbonyl sulfide.

3. The method of claim 1 , wherein the solidifiable gas component is carbon dioxide.

4. The method of claim 1 , wherein the process gas stream contains a plurality of solidifiable gas components.

5. The method of claim 1 , wherein the process gas stream includes water at a concentration equal to a water saturation at a temperature above the freezing point of water.

6. The method of claim 5 , wherein the method includes removing at least a portion of the water from the process gas stream prior to the contacting.

7. The method of claim 1 , wherein the process gas stream includes an exhaust stream from a combustion process.

8. The method of claim 1 , wherein the cold liquid has a temperature that is below the temperature at which solid carbon dioxide will precipitate from the process gas stream.

9. The method claim 1 , wherein the cold liquid has a solidifiable gas component solubility of less than 10 mol % at the contacting pressure and the contacting temperature.

10. The method of claim 1 , wherein the cold liquid has a different composition than the process gas stream.

11. The method of claim 1 , wherein the cold liquid has a freezing point of less than −100° C.

12. The method of claim 1 , wherein the cold liquid comprises at least one isoalkane, isoalkene, or alcohol that forms a majority component of the cold liquid.

13. The method of claim 1 , wherein the cold liquid comprises a mixture of two or more components.

14. The method of claim 12 , wherein the cold liquid comprises an isohexane, an isohexene, or combination thereof.

15. The method of claim 1 , wherein the cold liquid comprises an ethanol, a methanol, or combinations thereof.

16. The method of claim 1 , wherein the contacting pressure in at least one equilibrium stage is less than 50 psia.

17. The method of claim 1 , wherein the contacting comprises spraying the process gas stream with the cold liquid.

18. The method claim 1 , wherein the contacting includes bubbling the process gas stream through the cold liquid.

19. The method of claim 1 , wherein the method includes repeating the contacting with the cold liquid at a different contacting temperature.

20. The method of claim 1 , wherein the cold liquid is a first cold liquid, and further wherein the method includes repeating the contacting with a second cold liquid having a different composition than the first cold liquid.

21. The method of claim 1 , wherein the method includes repeating the contacting with a second cold liquid at a different contacting temperature.

22. The method of claim 1 , wherein the removing includes heating the slurry to a temperature at which at least a portion of the solids are no longer in a solid phase.

23. The method of claim 1 , wherein prior to the removing, the method includes pressurizing the slurry to a pressure that is greater than the contacting pressure.

24. The method of claim 23 , wherein the pressurization is achieved by heating the solid in a sealed container.

25. The method of claim 1 , wherein prior to the removing, the method includes increasing the concentration of the solids in the slurry by removing a portion of the cold liquid from the slurry.

26. The method of claim 22 , wherein the solids that are no longer in a solid phase are transformed solids, and further wherein the method includes separating at least a portion of the transformed solids to form an outlet stream.

27. The method of claim 26 , wherein the outlet stream is pumped into a subsurface formation for disposal.

28. The method of claim 1 , wherein the removing produces a resultant liquid stream from which the solids were removed, and further wherein the methods includes recycling the resultant liquid to form at least a portion of the cold liquid.

29. The method of claim 28 , wherein the method includes cooling the resultant liquid stream by heat exchange with at least a portion of the treated gas stream.

30. The method of claim 1 , wherein the removing step is performed using a filter.

31. The method of claim 1 , wherein the treated gas stream is utilized by a cooling assembly to cool a refrigerant used to cool a liquid stream to form the cold liquid.

32. The method of claim 1 , the removing step is performed using a centrifugal separator or a static centrifugal separator.

Assignees

• Kaminsky Robert D
• Minta Moses
• Exxonmobil Upstream Res Co

Inventors

• Kaminsky Robert D
• Minta Moses

Classifications

• B01D2257/504

  Carbon dioxide · CPC title

• B01D2257/304

  Hydrogen sulfide · CPC title

• B01D2257/302

  Sulfur oxides · CPC title

• B01D53/002

  by condensation · CPC title

• B01D2258/0283

  Flue gases · CPC title