Apparatus for in-situ production of low dissolved hydrogen sulfide, degassed, sulfur from Claus sulfur recovery

Patent metadata

Field	Value
Publication number	US-9757677-B2
Application number	US-201414303913-A
Country	US
Kind code	B2
Filing date	Jun 13, 2014
Priority date	Jun 21, 2013
Publication date	Sep 12, 2017
Grant date	Sep 12, 2017

Abstract

A vertically oriented sulfur condenser may employ a plurality of condenser tubes arranged longitudinally within an exterior casing, a liquid sulfur reservoir at a longitudinal end of the sulfur condenser, and a condenser tube wall of at least one of the plurality of condenser tubes that protrudes into and below a liquid sulfur reservoir. A catalyst may be located within the liquid sulfur reservoir. A liquid sulfur outlet may be located at the liquid sulfur surface. A Claus process gas inlet may be proximate a first end of the plurality of condenser tubes. A first tube sheet may connect to and seal an end of the plurality of condenser tubes proximate a first end of the plurality of condenser tubes. A second tube sheet may connect to and seals with the plurality of condenser tubes and the exterior casing proximate a second end of the plurality of condenser tubes.

First claim

The invention claimed is:

1. A sulfur condenser comprising:
an exterior casing;
a plurality of condenser tubes arranged longitudinally within the casing;
a liquid sulfur reservoir at a longitudinal end of the sulfur condenser, the liquid sulfur reservoir having a liquid sulfur surface;
a condenser tube wall of at least one of the plurality of condenser tubes that protrudes into and below the liquid sulfur surface; and
a catalyst located within the liquid sulfur reservoir.

2. The sulfur condenser of claim 1 , further comprising:
a Claus process gas inlet proximate one end of the plurality of condenser tubes.

3. The sulfur condenser of claim 1 , wherein each of the plurality of condenser tubes further comprises:
a first exterior portion that is surrounded by liquid; and
a second exterior portion that is surrounded by a Claus process gas.

4. The sulfur condenser of claim 1 , further comprising:
a Claus process gas outlet located between the liquid sulfur reservoir and the first exterior portion that is surrounded by liquid.

5. The sulfur condenser of claim 1 , wherein the condenser tube wall that protrudes into and below the sulfur level is a tube end.

6. The sulfur condenser of claim 1 , further comprising:
a sulfur condenser longitudinal central axis that is situated vertically.

7. The sulfur condenser of claim 1 , further comprising:
a liquid sulfur outlet located at the liquid sulfur surface.

8. The sulfur condenser of claim 1 , wherein liquid sulfur of the liquid sulfur reservoir and the catalyst reside in an end of the condenser tube wall.

9. The sulfur condenser of claim 1 , further comprising:
a Claus process gas inlet proximate a first end of the plurality of condenser tubes;
a first tube sheet that connects to and seals with the plurality of condenser tubes and the exterior casing proximate a first end of the plurality of condenser tubes; and
a second tube sheet that connects to and seals with the plurality of condenser tubes and the exterior casing proximate a second end of the plurality of condenser tubes.

10. A sulfur condenser comprising:
a liquid sulfur reservoir within the sulfur condenser, the liquid sulfur reservoir having a liquid sulfur surface;
a plurality of condenser tubes arranged longitudinally within an exterior casing, a first end of the plurality of condenser tubes residing proximate a first end of the exterior casing and a second end of the condenser tubes residing within the liquid sulfur reservoir proximate a second end of the exterior casing; and
a catalyst located within the liquid sulfur reservoir, wherein liquid sulfur and the catalyst of the liquid sulfur reservoir reside partially in ends of the plurality of condenser tubes.

11. The sulfur condenser of claim 10 , further comprising:
a Claus process gas inlet proximate a first end of the plurality of condenser tubes;
a first tube sheet that connects to and seals with the plurality of condenser tubes and the exterior casing proximate a first end of the plurality of condenser tubes; and
a second tube sheet that connects to and seals with the plurality of condenser tubes and the exterior casing proximate a second end of the plurality of condenser tubes.

12. The sulfur condenser of claim 10 , wherein each of the plurality of condenser tubes further comprises:
a first exterior portion that is surrounded by liquid; and
a second exterior portion that is surrounded by a Claus process gas.

13. The sulfur condenser of claim 10 , further comprising:
a Claus process gas outlet located between the liquid sulfur reservoir and the first exterior portion that is surrounded by liquid.

14. The sulfur condenser of claim 10 , wherein the second exterior portion resides between the first exterior portion and the liquid sulfur reservoir.

15. The sulfur condenser of claim 10 , wherein the second end of the condenser tubes residing within the liquid sulfur reservoir is an exit location of the Claus process gas from the plurality of condenser tubes.

16. The sulfur condenser of claim 10 , further comprising:
a sulfur condenser longitudinal central axis that is situated vertically.

17. The sulfur condenser of claim 10 , further comprising:
a liquid sulfur outlet located at the liquid sulfur surface.

Assignees

• Phillips 66 Co

Inventors

• Keller Alfred E

Classifications

• B01D5/0012

  Vertical tubes · CPC title

• B01D5/00

  Condensation of vapours; Recovering volatile solvents by condensation (B01D8/00 takes precedence; condensers F28B) · CPC title

• C01B17/0456

  the hydrogen sulfide-containing gas being a Claus process tail gas · CPC title

• B01J8/02

  with stationary particles, e.g. in fixed beds · CPC title

• B01D53/002 Primary

  by condensation · CPC title