Process for the refining of crude oil

Patent metadata

Field	Value
Publication number	US-10407628-B2
Application number	US-201414902204-A
Country	US
Kind code	B2
Filing date	Jul 4, 2014
Priority date	Jul 5, 2013
Publication date	Sep 10, 2019
Grant date	Sep 10, 2019

Abstract

A process for the refining of crude oil with at least one atmospheric distillation unit for separating the various fractions, a sub-atmospheric distillation unit, a conversion unit of the heavy fractions obtained, a unit for enhancing the quality of some of the fractions obtained by actions on the chemical composition of their constituents and a unit for the removal of undesired components, where the sub-atmospheric distillation residue is sent to one of the conversion units, the conversion unit includes at least one hydroconversion reactor in slurry phase, into which hydrogen or a mixture of hydrogen and H 2 S, is fed, in the presence of a suitable dispersed hydrogenation catalyst with dimensions ranging from 1 nanometer to 30 microns.

First claim

The invention claimed is:

1. A process for refining of crude oil, the process comprising:
feeding the crude oil to one or more atmospheric distillation units in order to separate at least a heavy residue(s);
feeding the heavy residue(s) separated in the atmospheric distillation unit(s), to a sub-atmospheric distillation unit, separating at least two liquid streams, which are a vacuum residue and a light separated fraction;
feeding the vacuum residue separated in the sub-atmospheric distillation unit to a conversion unit comprising at least one hydroconversion reactor in slurry phase into which hydrogen or a mixture of hydrogen and H 2 S is fed in the presence of a dispersed hydrogenation catalyst with a dimension ranging from 1 nanometer to 30 microns to obtain a product in vapour phase and a by-product in slurry phrase, wherein the product in vapour phase is treated in a gas-liquid treatment unit and separated in a separation unit thereby obtaining fractions in both vapour phase and liquid phase;
feeding the light separated fraction obtained in the sub-atmospheric distillation unit to a hydrodesulfurization unit of light gasoils (HDS1);
feeding a liquid fraction separated in the conversion unit, having a boiling point higher than 350° C., to a hydrodesulfurization and/or hydrocracking unit of heavy gasoils (HDS/HDC);
feeding a liquid fraction separated in the conversion unit, having a boiling point ranging from 170 to 350° C., to a hydrodesulfurization unit of medium gasoils (HDS2);
feeding a liquid fraction separated in the conversion unit, having a boiling point ranging from the boiling point of the C 5 products to 170° C., to a desulfurization unit of naphtha (HDS3);
feeding a light separated fraction separated in the atmospheric distillation unit(s), having a boiling point ranging from the boiling point of the C 5 products to 170° C., to said desulfurization unit of naphtha (HDS3),
wherein the conversion unit comprises, in addition to one or more hydroconversion reactors in slurry phase, a first separator, to which the slurry residue is sent, followed by a second separator, an atmospheric stripper and a separation unit downstream said stripper, and wherein in addition to the conversion reaction, the following steps occur:
separating the by-product in slurry phase in a first separator forming a bottom product and a head product,
separating the head product in a second separator also fed by a liquid stream having a boiling point higher than 170° C. obtained in the gas-liquid treatment and separation section, forming a liquid and gaseous stream both sent in points at different heights to the atmospheric stripper, and
stripping in the atmospheric stripper using steam said liquid and gaseous stream separated in the second separator; wherein a stream leaving the bottom of the atmospheric stripper is recycled to the conversion unit and/or to the sub-atmospheric distillation unit, and obtaining from the stripper a heavy liquid stream and a light liquid stream which is fed to the separation unit together with the liquid stream having a boiling point lower than 500° C. and obtained in the gas-liquid treatment and separation section so as to separate at least three fractions: a fraction having a boiling point higher than 350° C., the liquid fraction having a boiling point ranging from 170° C. to 350° C. and the liquid fraction having a boiling point ranging from the boiling point of C5 products to 170° C.

2. The process according to claim 1 , wherein a heavy fraction separated in liquid phase obtained in the conversion unit comprising at least one conversion reactor is at least partly recycled to the sub-atmospheric distillation unit.

3. The process according to claim 1 , wherein the light separated fraction obtained in the sub-atmospheric distillation unit and the liquid fraction separated in the conversion unit, having a boiling point ranging from 170 to 350° C., are fed to the same hydrodesulfurization unit of light or medium gasoils (HDS1/HDS2).

4. The process according to claim 1 , wherein a reforming unit (REF) is present downstream of the desulfurization unit of naphtha (HDS3).

5. The process according to claim 1 , wherein three streams are separated in the sub-atmospheric distillation unit, the third steam, having a boiling point ranging from 350 to 540° C., being fed to the hydrodesulfurization and/or hydrocracking unit of heavy gasoils (HDS/HDC).

6. The process according to claim 1 , wherein a heavy fraction obtained downstream of the hydrodesulfurization and/or hydrocracking unit of heavy gasoils (HDS/HDC) is sent to a FCC unit (FCC).

7. The process according to claim 1 , wherein gases, a heavy liquid stream, an intermediate liquid stream, having a boiling point lower than 380° C., and a stream containing acid water, are obtained from the gas-liquid treatment unit and separation section, the heavy stream being sent to the second separator downstream of the hydroconversion reactor(s) and the intermediate liquid stream being sent to the separation unit downstream of the atmospheric stripper.

8. The process according to claim 1 , wherein a nano-dispersed catalyst is based on molybdenum.

9. A process for refining of crude oil, the process comprising:
feeding the crude oil to one or more atmospheric distillation units in order to separate at least a heavy residue(s);
feeding the heavy residue(s) separated in the atmospheric distillation unit(s), to a sub-atmospheric distillation unit, separating at least two liquid streams, which are a vacuum residue and a light separated fraction;
feeding the vacuum residue separated in the sub-atmospheric distillation unit to a conversion unit comprising at least one conversion reactor in slurry phase into which hydrogen or a mixture of hydrogen and H 2 S is fed in the presence of a dispersed hydrogenation catalyst with dimension ranging from 1 nanometer to 30 microns in order to obtain a product in vapour phase and a by-product in slurry phase, wherein said product in vapor phase is treated in a gas-liquid treatment unit and separated in a separation section obtaining fractions in both vapour phase and liquid phase;
feeding a light separated fraction obtained in the sub-atmospheric distillation unit to a hydrodesulfurization unit of light gasoils (HDS1);
feeding a liquid fraction separated in the conversion unit, having a boiling point higher than 350° C., to a hydrodesulfurization and/or hydrocracking unit of heavy gasoils (HDS/HDC);
feeding a liquid fraction separated in the conversion unit, having a boiling point ranging from 170 to 350° C., to a hydrodesulfurization unit of medium gasoils (HDS2);
feeding a liquid fraction separated in the conversion unit, having a boiling point ranging from the boiling point of the C 5 products to 170° C., to a desulfurization unit of naphtha (HDS3);
feeding a liquid stream separated in the atmospheric distillation unit(s), having a boiling point ranging from the boiling point of the C 5 products to 170° C., to said desulfurization unit of naphtha (HDS3),
wherein the conversion unit comprises, in addition to one or more conversion reactors in slurry phase, a first separator, to which the slurry residue is sent, followed by a second separator, an atmospheric stripper and a separation unit downstream said stripper, and wherein in addition to the conversion reaction, the following steps occur:
separating the by-product in slurry phase in a first separator, forming a bottom product and a head product,
separating said head product in a second separator, also fed by a liquid stream having a boiling point higher than 170° C. obtained in the gas-liquid treatment and separation section, forming a liquid and gaseous stream both sent in points at different he

Assignees

• Eni Spa

Inventors

• Bellussi Giuseppe
• Piccolo Vincenzo
• Malandrino Alberto Maria Antonio
• Fabio Valentina
• Rispoli Giacomo Fernando

Classifications

• C10G7/00

  Distillation of hydrocarbon oils · CPC title

• C10G47/26

  suspended in the oil, e.g. slurries · CPC title

• C10G65/12

  including cracking steps and other hydrotreatment steps · CPC title

• C10G65/14

  plural parallel stages only · CPC title

• C10G45/02 Primary

  to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing · CPC title