Staged solvent assisted hydroprocessing and resid hydroconversion

Patent metadata

Field	Value
Publication number	US-9677015-B2
Application number	US-201414308932-A
Country	US
Kind code	B2
Filing date	Jun 19, 2014
Priority date	Jun 20, 2013
Publication date	Jun 13, 2017
Grant date	Jun 13, 2017

Abstract

Systems and methods are provided for processing a heavy oil feed, such as an atmospheric or vacuum resid, using a combination of solvent assisted hydroprocessing and slurry hydroconversion of a heavy oil feed. The systems and methods allow for conversion and desulfurization/denitrogenation of a feed to form fuels and gas oil (or lubricant base oil) boiling range fractions while reducing the portion of the feed that is exposed to the high severity conditions present in slurry hydroconversion.

First claim

What is claimed is:

1. A method for processing a heavy oil feedstock, comprising:
providing a combined feedstock comprising a heavy oil feedstock having a 10% distillation point of at least about 650° F. (343° C.) and a solvent component, wherein the solvent component has an ASTM D86 90% distillation point of less than 300° C.;
exposing the combined feedstock to a catalyst in the presence of hydrogen under first effective hydroprocessing conditions to form a first slurry hydroconversion effluent comprising at least a first plurality of liquid products and a first hydroprocessing bottoms product, the first effective hydroprocessing conditions including a temperature of at least about 680° F. (360° C.) and a liquid hourly space velocity of the fraction of the combined feedstock boiling above 1050° F. (566° C.) of at least about 0.10 hr −1 ;
exposing the first hydroprocessing bottoms product to a catalyst in the presence of hydrogen under second effective slurry hydroconversion conditions to form a second slurry hydroconversion effluent comprising at least a second plurality of liquid products and a second hydroprocessing bottoms product; and
fractionating the first plurality of liquid products and the second plurality of liquid products.

2. The method of claim 1 , wherein the solvent component comprises a recycle component containing at least a portion of the second slurry hydroconversion effluent.

3. The method of claim 2 , wherein the ratio of the recycle component to the heavy oil feed component on a weight basis is from about 0.3 to about 6.0.

4. The method of claim 1 , wherein the first effective hydroprocessing conditions are effective for conversion of from about 50 to about 70% of the 1050° F.+(566° C.+) portion of the heavy oil feed feedstock.

5. The method of claim 1 , wherein the solvent component comprises at least a portion of the first slurry hydroconversion effluent.

6. The method of claim 1 , further comprising fractionating at least a portion of the first plurality of liquid products, the second plurality of liquid products, or a combination thereof, the first plurality of liquid products and the second plurality of liquid products optionally being fractionated in a common fractionator.

7. The method of claim 6 , wherein the common fractionator comprises a divided wall fractionator.

8. The method of claim 1 , further comprising hydrotreating at least a portion of the second plurality of liquid products.

9. The method of claim 1 , further comprising:
combining at least a portion of one or more of the first plurality of liquid products with at least a portion of one or more of the second plurality of liquid products;
hydroprocessing the combined liquid products; and
fractionating the hydroprocessed combined liquid products, optionally wherein hydroprocessing the combined liquid products comprises hydrotreating the combined liquid products.

10. The method of claim 1 , further comprising coking a second feedstock under effective coking conditions, wherein the second feedstock is heated in a common heating zone.

11. The method of claim 1 , wherein a 10% distillation point of the heavy oil feedstock is at least about 900° F. (482° C.).

12. The method of claim 1 , wherein the heavy oil feedstock has a Conradson carbon residue of about 27.5 wt % or less.

13. The method of claim 1 , wherein the heavy oil feedstock has a Conradson carbon residue of at least about 30 wt %.

14. The method of claim 1 , wherein a portion of at least one of the first plurality of liquid products is added to the first slurry hydroconversion effluent as a quench stream.

15. The method of claim 1 , wherein the first effective hydroprocessing conditions further include a hydrogen partial pressure of about 1000 psig (6895 kPa-g) or less.

Assignees

• Gupta Himanshu
• Brown Stephen Harold
• Barrai Federico
• Trivedi Kirtan Kunjbihari
• Exxonmobil Res & Eng Co

Inventors

• Gupta Himanshu
• Brown Stephen Harold
• Barrai Federico
• Trivedi Kirtan Kunjbihari

Classifications

• C10G45/16

  suspended in the oil, e.g. slurries · CPC title

• C10G2300/4081

  Recycling aspects · CPC title

• C10G65/10

  including only cracking steps · CPC title

• C10G65/02 Primary

  plural serial stages only · CPC title

• C10G2300/44

  Solvents · CPC title