Graphene-augmented composite materials

Patent metadata

Field	Value
Publication number	US-10400075-B2
Application number	US-201815948674-A
Country	US
Kind code	B2
Filing date	Apr 9, 2018
Priority date	Jan 5, 2015
Publication date	Sep 3, 2019
Grant date	Sep 3, 2019

Abstract

Graphene fibers made from a graphene film formed into an elongated fiber-like shape and composite materials made from the graphene fibers. The elongated fiber-like shape may be the graphene film in a rolled spiral orientation or the graphene film in a twisted formation. The graphene film has benzoxazine groups formed on at least an outer surface of the graphene film and epoxide groups formed on at least one edge of the graphene film. Methods of increasing strength of a composite material include combining a resin matrix with a plurality of the graphene fibers to form a prepreg material and curing the prepreg material to form the composite material.

First claim

The invention claimed is:

1. A graphene fiber comprising a graphene film formed into an elongated fiber-like shape and having benzoxazine groups formed on at least an outer surface of the graphene film and epoxide groups formed on at least one edge of the graphene film.

2. The graphene fiber of claim 1 , wherein the graphene film has a linear density of epoxide groups formed on the at least one edge of about 7,000 to about 700,000 groups per millimeter.

3. The graphene fiber of claim 1 , wherein about 0.1% to about 10% of carbon atoms at the least one edge of the graphene film have epoxide groups bonded thereto.

4. The graphene fiber of claim 1 , wherein the elongated fiber-like shape comprises the graphene film in a rolled spiral orientation.

5. The graphene fiber of claim 4 , wherein the benzoxazine groups are formed in a functionalized area on the outer surface of the graphene film that is within about 10 microns from the at least one edge of the graphene film.

6. The graphene fiber of claim 5 , wherein the benzoxazine groups in the functionalized area on the outer surface of the graphene film have a surface density of about 4.0E10 to about 2.0E12 groups per square millimeter of the functionalized area.

7. The graphene fiber of claim 5 , wherein about 0.1% to about 5.0% of carbon atoms in the functionalized area of the graphene film have benzoxazine groups bonded thereto.

8. The graphene fiber of claim 4 , wherein the graphene fiber has a diameter of about 1 to about 7 microns and a circumference of about 3 to about 22 microns.

9. The graphene fiber of claim 4 , wherein the elongated fiber-like shape has a center hollow area having a diameter of less than 500 nanometers.

10. The graphene fiber of claim 4 , wherein the spiral orientation comprises the graphene film rolled at an angle less than 0.6 degrees and overlapping layers of the graphene film.

11. The graphene fiber of claim 1 , wherein the elongated fiber-like shape comprises the graphene film in a twisted formation.

12. The graphene fiber of claim 11 , wherein the benzoxazine groups on the outer surface of the graphene film have a surface density of about 4.0E10 to about 2.0E12 groups per square millimeter of the outer surface of the graphene film.

13. The graphene fiber of claim 1 , wherein the graphene film further comprises at least one hole formed through the graphene film.

14. The graphene fiber of claim 13 , wherein the at least one hole is substantially circular and has a diameter of 1-2 nanometers.

15. The graphene fiber of claim 13 , wherein the graphene film has a density of holes in the range of about 4E7 to about 4E10 holes per square millimeter, or about one hole per 1,000 to 1 million carbon atoms.

16. The graphene fiber of claim 13 , wherein the at least one hole has a size of about 12-80 carbon atoms.

17. The graphene fiber of claim 13 , wherein the benzoxazine groups on the outer surface of the graphene film have a surface density of about 4.0E10 to about 2.0E12 groups per square millimeter of the outer surface of the graphene film.

18. The graphene fiber of claim 13 , wherein the graphene film has a linear density of epoxide groups formed on all edges of the graphene film of about 7,000 to about 700,000 groups per millimeter.

19. The graphene fiber of claim 13 , wherein about 0.1% to about 10% of carbon atoms at all edges of the graphene film have epoxide groups bonded thereto.

20. The graphene fiber of claim 13 , wherein the elongated fiber-like shape comprises the graphene film in a rolled spiral orientation.

21. The graphene fiber of claim 13 , wherein the elongated fiber-like shape comprises the graphene film in a twisted formation.

22. The graphene fiber of claim 1 , wherein the graphene film is about 50 microns to about 500 microns wide.

23. A composite material comprising the graphene fiber of claim 1 and a matrix material.

24. A method of increasing strength of a composite material, the method comprising:
forming a graphene fiber comprising a graphene film formed into an elongated fiber-like shape and having benzoxazine groups formed on at least an outer surface of the graphene film and epoxide groups formed on at least one edge of the graphene film;
combining a resin matrix material with a plurality of the graphene fibers to form a prepreg material; and
curing the prepreg material to form the composite material.

25. The method of claim 24 , wherein the step of forming the graphene fiber comprises rolling the graphene film in a spiral orientation to form the elongated fiber-like shape of the graphene fiber.

26. The method of claim 25 , wherein the step of forming the graphene fiber further comprises forming the graphene fiber with a diameter of about 1 to about 7 microns, a circumference of about 3 to about 22 microns, and a center hollow area having a diameter of less than 500 nanometers.

27. The method of claim 25 , wherein the step of forming the graphene fiber further comprises maintaining a tension in the graphene film at about 0.001 N per meter of film width.

28. The method of claim 24 , wherein the step of forming the graphene fiber comprises twisting the graphene film to form the elongated fiber-like shape.

29. The method of claim 24 , wherein the step of forming the graphene fiber further comprises forming at least one hole in the graphene film.

30. The method of claim 24 , wherein the step of forming the graphene fiber further comprises forming benzoxazine groups in a functionalized area on the outer surface of the graphene film that is within about 10 microns from the at least one edge of the graphene film.

31. The method of claim 29 , wherein the at least one hole is formed in a substantially circular shape with a diameter of 1-20 nanometers.

32. The method of claim 31 , wherein the graphene film has a density of holes in the range of about 4E7 to about 4E10 holes per square millimeter, or about one hole per 1,000 to 1 million carbon atoms.

33. The method of claim 24 , further comprising combining carbon fiber with the graphene fiber to form the prepreg material.

Assignees

• Boeing Co

Inventors

• Humfeld Keith Daniel

Classifications

• C08J2379/08

  Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors · CPC title

• C08J5/042 Primary

  with carbon fibres · CPC title

• C08J2379/04

  Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors · CPC title

• C08J5/005

  Reinforced macromolecular compounds with nanosized materials, e.g. nanoparticles, nanofibres, nanotubes, nanowires, nanorods or nanolayered materials · CPC title

• C08K9/04

  Ingredients treated with organic substances {(treated with macromolecular compounds C08K9/08)} · CPC title