Graphene-augmented composite materials

Patent metadata

Field	Value
Publication number	US-9518160-B2
Application number	US-201514865820-A
Country	US
Kind code	B2
Filing date	Sep 25, 2015
Priority date	Jan 5, 2015
Publication date	Dec 13, 2016
Grant date	Dec 13, 2016

Abstract

Composite materials are augmented with functionalized graphene having added amine groups, benzoxazine groups, imide groups, or a combination of amine groups and imide groups on a surface of the graphene, epoxide groups formed on at least one edge of the graphene and/or holes formed through the graphene. The functionalized graphene is integrated into a composite material as a supplement to or as a replacement for either the carbon reinforcement material or the resin matrix material to increase strength of the composite materials, and may be in the form of a functionalized graphene nanoplatelet, a flat graphene sheet or film, or a rolled or twisted graphene sheet or film.

First claim

The invention claimed is:

1. A composite material comprising carbon reinforcement fibers and a matrix material, the matrix material comprising 0.1% to 100% by weight functionalized graphene nanoplatelets having benzoxazine groups formed on a surface of the graphene nanoplatelets and epoxide groups formed on at least one edge of the graphene nanoplatelets.

2. The composite material of claim 1 , wherein the graphene nanoplatelets further comprise holes having a size of about 12-80 carbon atoms formed through the graphene nanoplatelets.

3. The composite material of claim 1 , wherein the benzoxazine groups on the surface of the graphene nanoplatelets have a surface density of about 4.0E10 to about 2.0E12 groups per square millimeter.

4. The composite material of claim 1 , wherein about 0.1% to about 5.0% of carbon atoms in the graphene nanoplatelets have benzoxazine groups bonded thereto.

5. The composite material of claim 1 , wherein the graphene nanoplatelets have a linear density of the epoxide groups formed on the at least one edge of about 7,000 to about 700,000 groups per millimeter.

6. The composite material of claim 1 , wherein about 0.1% to about 10% of carbon atoms at the at least one edge of the graphene nanoplatelets have epoxide groups bonded thereto.

7. The composite material of claim 1 , wherein the matrix material comprises an aerospace-grade benzoxazine resin having 0.1% to 5.0% by weight functionalized graphene nanoplatelets, the graphene nanoplatelets are present throughout the benzoxazine resin, and the benzoxazine resin is a macromolecular complex.

8. The composite material of claim 1 , wherein the matrix material comprises an aerospace-grade benzoxazine resin, the graphene nanoplatelets form an interlayer between two layers of the benzoxazine resin, and the interlayer is a macromolecular complex of the benzoxazine resin.

9. The composite material of claim 1 , wherein the matrix material comprises 100% by weight functionalized graphene nanoplatelets, and the matrix material is a macromolecular complex of the graphene nanoplatelets.

10. An aircraft comprising composite structures made from the composite material of claim 1 .

11. A composite material comprising carbon reinforcement fibers and a matrix material, the matrix material comprising an aerospace-grade bismaleimide resin having 0.1% to 5.0% by weight functionalized grapheme nanoplatelets having imide groups formed on a surface of the graphene nanoplatelets, the grapheme nanoplatelets being present throughout the bismaleimide resin, and the bismaleimide resin is a macromolecular complex.

12. The composite material of claim 11 , wherein the graphene nanoplatelets further comprise amine groups formed on the surface of the graphene nanoplatelets.

13. The composite material of claim 12 , wherein the graphene nanoplatelets further comprise holes having a size of about 12-80 carbon atoms formed through the graphene nanoplatelets.

14. The composite material of claim 12 , wherein the imide groups and amine groups on the surface of the graphene nanoplatelets have a surface density of about 4.0E10 to about 2.0E12 groups per square millimeter.

15. The composite material of claim 12 , wherein about 0.1% to about 5.0% of carbon atoms in the graphene nanoplatelets have imide groups or amine groups bonded thereto.

16. The composite material of claim 11 , wherein the matrix material comprises an aerospace-grade bismaleimide resin, the grapheme nanoplatelets form an interlayer between two layers of the bismaleimide resin, and interlayer is a macromolecular complex of the bismaleimide resin.

17. The composite material of claim 11 , wherein the matrix material comprises 100% by weight functionalized graphene nanoplatelets, and the matrix material is a macromolecular complex of the graphene nanoplatelets.

18. An aircraft comprising composite structures made from the composite material of claim 11 .

19. A method of increasing strength of a composite material comprising carbon reinforcement fibers and a resin matrix material, the method comprising:
preparing functionalized graphene nanoplatelets having a chemical functionalization;
mixing the functionalized graphene nanoplatelets into the resin matrix material to form a graphene-resin mixture;
combining the graphene-resin mixture with a plurality of the carbon reinforcement fibers to form a prepreg material; and
curing the prepreg material to form the composite material.

20. The method of claim 19 , wherein the chemical functionalization is selected from the group consisting of (i) amine groups formed on a surface of the graphene nanoplatelets and epoxide groups formed on at least one edge of the graphene nanoplatelets, (ii) benoxazine groups formed on the surface of the graphene nanoplatelets and epoxide groups formed on at least one edge of the graphene nanoplatelets, (iii) imide groups formed on the surface of the grapheme nanoplatelets, and (iv) a combination of amine groups and imide groups formed on the surface of the graphene nanoplatelets.

21. The method of claim 20 , wherein the step of preparing the functionalized graphene nanoplatelets comprises forming holes through the graphene nanoplatelets.

22. The method of claim 20 , wherein about 0.1% to about 5.0% of carbon atoms in the graphene nanoplatelets have one of amine groups, benzoxazine groups, imide groups or a combination of amine groups and imide groups bonded thereto.

23. The method of claim 21 , wherein the functionalized graphene nanoplatelets are mixed into the resin matrix material in an amount of 0.1% to 5.0% by weight of the graphene-resin mixture.

Assignees

• Boeing Co

Inventors

• Humfeld Keith Daniel

Classifications

• C08J2379/04

  Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors · CPC title

• C08J2379/08

  Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors · CPC title

• C08J2363/00

  Characterised by the use of epoxy resins; Derivatives of epoxy resins · CPC title

• C08J5/005

  Reinforced macromolecular compounds with nanosized materials, e.g. nanoparticles, nanofibres, nanotubes, nanowires, nanorods or nanolayered materials · CPC title

• C08J5/042 Primary

  with carbon fibres · CPC title