Process for the incineration of activated coal-supported PGM catalysts

Patent metadata

Field	Value
Publication number	US-10393374-B2
Application number	US-201815899474-A
Country	US
Kind code	B2
Filing date	Feb 20, 2018
Priority date	Feb 17, 2017
Publication date	Aug 27, 2019
Grant date	Aug 27, 2019

Abstract

A process for the incineration of activated coal-supported PGM catalysts, the process comprising a joint incineration of a multilayer arrangement, wherein the multilayer arrangement includes (i) a top layer of particulate activated coal-supported PGM catalyst, (ii) a layer of coarse charcoal located beneath said top layer and, optionally, (iii) a layer of particulate coke located beneath the charcoal layer, and wherein an upward flow of oxidizing gas is homogeneously passed through said multilayer arrangement during the incineration.

First claim

The invention claimed is:

1. A process for the incineration of activated coal-supported PGM catalysts, the process comprising a joint incineration of a multilayer arrangement,
wherein the multilayer arrangement comprises (i) a top layer of particulate activated coal-supported PGM catalyst, (ii) a layer of coarse charcoal located beneath said top layer and, optionally, (iii) a layer of particulate coke located beneath the charcoal layer, and
wherein an upward flow of oxidizing gas is homogeneously passed through said multilayer arrangement during the incineration.

2. The process of claim 1 , wherein the particulate activated coal-supported PGM catalyst comprises one or more activated coal-supported PGM catalysts.

3. The process of claim 1 , wherein the particulate activated coal-supported PGM catalyst comprises particles of 2 mm to 2 cm measured in the longest dimension.

4. The process of claim 1 , wherein the thickness of the top layer prior to the incineration lies in the range of 30 to 100 cm.

5. The process of claim 1 , wherein a total PGM content of the particulate activated coal-supported PGM catalyst lies in the range of 0.1 to 5 wt.-%.

6. The process of claim 1 , wherein the particulate activated coal-supported PGM catalyst comprises 0 to 3 wt.-% of aluminum oxide and/or silicon dioxide.

7. The process of claim 1 , wherein the particulate activated coal-supported PGM catalyst comprises an exhausted catalyst.

8. The process of claim 1 , wherein the particulate activated coal-supported PGM catalyst comprises a minimally combustible activated coal-supported PGM catalyst.

9. The process of claim 1 , wherein the coarse charcoal of the layer beneath the top layer comprises pieces of 2 to 8 cm measured in the longest dimension.

10. The process of claim 1 , wherein the thickness of the layer of coarse charcoal prior to the incineration lies in the range of 5 to 20 cm.

11. The process of claim 1 , wherein the particulate coke comprises pieces of 0.5 to 2.5 cm measured in the longest dimension.

12. The process of claim 1 , wherein a thickness of the layer of particulate coke prior to the incineration lies in the range of 5 to 20 cm.

13. The process of claim 1 , wherein a flow rate of the oxidizing gas at a pressure of about 1.1 bar lies in the range of 500 to 1000 liters per hour and per kg of particulate activated coal-supported PGM catalyst.

14. The process of claim 1 , wherein the oxidizing gas is air or oxygen-enriched air with an oxygen content of up to 50 vol.-%.

15. The process of claim 1 , wherein the incineration is performed at an incineration temperature in the range of 600 to 850° C.

Assignees

• Heraeus Deutschland Gmbh & Co Kg
• Heraeus Precious Metals North America LLC
• Heraeus Deutschland & Gmbh & Co Kg

Inventors

• Peters Brian
• Hobbs Chris
• England Todd
• Taylor Jimmy
• Winkler Holger
• Bauer-Siebenlist Bernhard

Classifications

• C22B11/026

  from spent catalysts · CPC title

• C22B7/001 Primary

  Dry processes · CPC title

• B01J23/40

  of the platinum group metals · CPC title

• F23G2900/70

  Incinerating particular products or waste · CPC title

• F23G2207/30

  Oxidant supply · CPC title