Method for recovering rare earth element

Patent metadata

Field	Value
Publication number	US-9322082-B2
Application number	US-201214234750-A
Country	US
Kind code	B2
Filing date	Jul 27, 2012
Priority date	Jul 29, 2011
Publication date	Apr 26, 2016
Grant date	Apr 26, 2016

Abstract

An object of the present invention is to provide a method for recovering a rare earth element from a workpiece containing at least a rare earth element and an iron group element, which can be put into practical use as a low-cost, simple recycling system. The method of the present invention as a means for resolution is characterized by including at least a step of separating a rare earth element in the form of an oxide from an iron group element by subjecting a workpiece to an oxidation treatment, then turning the treatment environment into an environment where carbon is present, and subjecting the oxidation-treated workpiece to a heat treatment at a temperature of 1150° C. or more.

First claim

The invention claimed is:

1. A method for recovering a rare earth element from a workpiece containing at least a rare earth element and an iron group element, characterized by including at least a step of separating a rare earth element in the form of an oxide from an iron group element by subjecting a workpiece to an oxidation treatment, then turning the treatment environment into an environment where carbon is present, and subjecting the oxidation-treated workpiece to a heat treatment at a temperature of 1150° C. or more,
wherein after the oxidation treatment, the molar concentration of oxygen in the workpiece is at least 2.0 times more than the molar concentration of the rare earth element.

2. The method according to claim 1 , characterized in that in the heat treatment of the oxidation-treated workpiece in the presence of carbon, a carbon crucible is used as a treatment container and a carbon supply source.

3. The method according to claim 1 , characterized in that in the heat treatment of the oxidation-treated workpiece in the presence of carbon, a carbon supply source is added to a non-carbon treatment container.

4. The method according to claim 1 , characterized in that at least part of the workpiece is in granular or powder form having a particle size of 500 μm or less.

5. The method according to claim 1 , characterized in that the workpiece is an R—Fe—B based permanent magnet.

6. The method according to claim 5 , characterized in that the step of separating a rare earth element in the form of an oxide from an iron group element is followed by a step of reducing the boron content of the oxide of the rare earth element by subjecting the oxide of the rare earth element to a heat treatment together with a carbonate of an alkali metal in the presence of carbon.

7. A method for reducing the boron content of a boron-containing oxide of a rare earth element, characterized in that a boron-containing oxide of a rare earth element is subjected to a heat treatment together with a carbonate of an alkali metal in the presence of carbon.

Assignees

• Hoshi Hiroyuki
• Kikugawa Atsushi
• Hitachi Metals Ltd

Inventors

• Hoshi Hiroyuki
• Kikugawa Atsushi

Classifications

• C22B1/02

  Roasting processes (C22B1/16 takes precedence) · CPC title

• C22B7/001

  Dry processes · CPC title

• C22B59/00 Primary

  Obtaining rare earth metals · CPC title

• H01F41/0253

  for manufacturing permanent magnets · CPC title

• C22B1/005

  Preliminary treatment of scrap (C22B1/02 - C22B1/26 take precedence) · CPC title