Electrochemical cell that generates hydrogen

Patent metadata

Field	Value
Publication number	US-10392716-B2
Application number	US-201715708666-A
Country	US
Kind code	B2
Filing date	Sep 19, 2017
Priority date	Sep 19, 2016
Publication date	Aug 27, 2019
Grant date	Aug 27, 2019

Abstract

An electrochemical cell that generates hydrogen has an anode including an electrochemically oxidizable substance and an electrode designed for hydrogen generation as a cathode and an aqueous alkaline electrolyte. The anode and the cathode are designed such that the hydrogen generation begins at the cathode as soon the anode and the cathode are electrically connected to one another. At least one resistance foil is adhesively bonded to at least one outer side of the housing which, when it is connected as a load resistance between the anode and the cathode, reduces the current flow between the anode and the cathode and therefore also the gas generation rate.

First claim

What is claimed is:

1. An electrochemical cell that generates hydrogen comprising:
an anode comprising an electrochemically oxidizable substance;
an electrode designed for hydrogen generation as a cathode;
an aqueous alkaline electrolyte, wherein the anode and the cathode are designed such that the hydrogen generation begins at the cathode as soon as the anode and the cathode are electrically connected to one another; a housing that encloses an interior in which the anode and the cathode, separated from one another by a separator, are arranged, wherein the housing has at least one aperture through which hydrogen generated at the electrode designed for hydrogen generation can escape from the interior; and
at least one resistance foil adhesively bonded to at least one outer side of the housing which, when connected as a load resistance between the anode and the cathode, reduces current flow between the anode and the cathode and therefore the gas generation rate.

2. The cell according to claim 1 , wherein the resistance foil has a resistance per unit area of 1 mΩ/□ to 100 kΩ/□.

3. The cell according to claim 1 , having at least one of:
the resistance foil comprises at least one metal layer,
the resistance foil comprises at least one resistance layer,
the resistance foil comprises at least one adhesive layer,
the resistance foil has a layer sequence: metal layer/adhesive layer,
the resistance foil has a layer sequence: adhesive layer/metal layer/adhesive layer,
the resistance foil has a layer sequence: metal layer/resistance layer/metal layer,
the resistance foil has a layer sequence: adhesive layer/metal layer/resistance layer/ metal layer, and
the resistance foil has a layer sequence: adhesive layer/metal layer/resistance layer/ metal layer/adhesive layer.

4. The cell according to claim 3 , having at least one of:
the metal layer consists of copper, aluminum, nickel, cobalt, noble metals such as gold, silver, and platinum, or an alloy of one of these metals,
the resistance layer is based on a polymer having defined conductivity, a resistance alloy, or a carbon-based material, and
the adhesive layer is formed from an acrylic adhesive or an epoxy adhesive.

5. The cell according to claim 1 , having at least one of:
the cell is a button cell and comprises a cylindrical housing, an outer side of which comprises a flat upper side, a flat lower side, and a circumferential lateral surface,
the housing consists of a cell cup, a cell cover, and a seal, wherein the cell cover is inserted into the cell cup and the seal separates the cell cup and the cell cover from one another, and
the at least one aperture is introduced into the bottom of the cell cup or the cell cover.

6. The cell according to claim 5 , having at least one of:
the cell is a button cell and comprises at least one resistance foil adhesively bonded to the flat upper side of its housing,
the cell is a button cell and comprises at least one resistance foil adhesively bonded to the flat lower side of its housing, and
the cell is a button cell and comprises at least one resistance foil adhesively bonded to the circumferential lateral surface of its housing of the button cell.

7. The cell according to claim 6 , having at least one of:
the at least one aperture in the bottom of the cell cup is closed by the resistance foil on the flat lower side of the housing,
the resistance foil covers the at least one aperture and a region enclosing the at least one aperture,
the resistance foil has at least one intended tear point that tears upon the first startup of the cell due to a pressure forming in the interior as a result of the beginning hydrogen or oxygen generation, and
the resistance foil has at least one passage in the form of a hole or a slot in the region enclosing the aperture.

8. The cell according to claim 7 , having at least one of:
the at least one intended tear point is implemented as a punctiform or linear attenuation of the resistance foil,
the attenuation is induced by perforation along an attenuation line,
the attenuation is continuous and free of holes along an attenuation line,
the intended tear point is implemented as a linear attenuation of the resistance foil having curved or circular geometry, and
the intended tear point is implemented as a linear attenuation of the resistance foil along one or more straight lines.

9. The cell according to claim 7 , having at least one of:
the at least one passage comprises multiple holes and/or slots along a line, and
the line is implemented along one or more straight lines having curved or circular geometry.

Assignees

• Varta Microbattery Gmbh

Inventors

• Kreidler Bernd
• Schweinstetter Bernd
• Voigt Uwe

Classifications

• C25B1/04

  by electrolysis of water · CPC title

• C25B15/04 Primary

  Regulation of the inter-electrode distance · CPC title

• C25B15/02 Primary

  Process control or regulation · CPC title

• C25B1/10

  Chemistry & Metallurgy · mapped topic

• C25B9/08

  Chemistry & Metallurgy · mapped topic