Gas chromatograph

Patent metadata

Field	Value
Publication number	US-10386343-B2
Application number	US-201715815039-A
Country	US
Kind code	B2
Filing date	Nov 16, 2017
Priority date	Nov 16, 2017
Publication date	Aug 20, 2019
Grant date	Aug 20, 2019

Abstract

When a flow rate of a carrier gas calculated by a column flow rate calculation unit is controlled to be a first flow rate, and when the flow rate of the carrier gas is controlled to be a second flow rate, the flow rates of the carrier gas are detected by a whole flow rate detection unit, and a gas leakage determination unit determines of leakage of the carrier gas on the basis of the rates. Since the flow rate of the carrier gas is changed and the detected value of the whole flow rate detection unit is used at different flow rates, a case can be discriminated where an offset occurs in the detected value of the whole flow rate detection unit and a case where leakage of the carrier gas occurs. Thus, it is satisfactorily determined the presence or absence of the leakage of the carrier gas.

First claim

What is claimed is:

1. A gas chromatograph comprising:
a column into which a sample is introduced from a column inlet;
a sample introduction unit which introduces the sample together with a carrier gas into the column from the column inlet;
a gas supply unit which communicates with the sample introduction unit to supply a carrier gas to the sample introduction unit;
a whole flow rate detection unit which detects a flow rate of the carrier gas supplied from the gas supply unit;
a pressure detection unit which detects a pressure of the carrier gas at the column inlet;
a column flow rate calculation unit which calculates a flow rate of the carrier gas passing through the column, on the basis of the pressure of the carrier gas at the column inlet;
a first flow rate control unit which controls the flow rate of the carrier gas supplied from the gas supply unit so that the flow rate of the carrier gas calculated by the column flow rate calculation unit becomes a first flow rate;
a second flow rate control unit which controls the flow rate of the carrier gas supplied from the gas supply unit so that the flow rate of the carrier gas calculated by the column flow rate calculation unit becomes a second flow rate different from the first flow rate; and
a gas leakage determination unit which determines presence or absence of leakage of the carrier gas, on a basis of the flow rate of the carrier gas detected by the whole flow rate detection unit when the flow rate of the carrier gas is controlled by the first flow rate control unit, the flow rate of the carrier gas detected by the whole flow rate detection unit when the flow rate of the carrier gas is controlled by the second flow rate control unit, the first flow rate, and the second flow rate.

2. The gas chromatograph according to claim 1 , wherein the gas leakage determination unit includes:
a first difference calculation unit which calculates a difference between the flow rate of the carrier gas detected by the whole flow rate detection unit when the flow rate of the carrier gas is controlled by the first flow rate control unit and the first flow rate;
a second difference calculation unit which calculates a difference between the flow rate of the carrier gas detected by the whole flow rate detection unit when the flow rate of the carrier gas is controlled by the second flow rate control unit and the second flow rate; and
a comparison processing unit which compares a difference between the difference calculated by the first difference calculation unit and the difference calculated by the second difference calculation unit with a first threshold value.

3. The gas chromatograph according to claim 1 , further comprising:
a first notification control unit which notifies the leakage, when the gas leakage determination unit determines that there is leakage of the carrier gas.

4. The gas chromatograph according to claim 1 , further comprising:
a detection abnormality determination unit which determines presence or absence of a detection abnormality in the whole flow rate detection unit, by comparing the difference calculated by the first difference calculation unit or the second difference calculation unit with a second threshold value, when the gas leakage determination unit determines that there is no leakage of the carrier gas.

5. The gas chromatograph according to claim 4 , further comprising:
a second notification control unit which notifies detection abnormality, when the detection abnormality determination unit determines that there is a detection abnormality in the whole flow rate detection unit.

6. The gas chromatograph according to claim 2 , further comprising:
a first notification control unit which notifies the leakage, when the gas leakage determination unit determines that there is leakage of the carrier gas.

7. The gas chromatograph according to claim 2 , further comprising:
a detection abnormality determination unit which determines presence or absence of a detection abnormality in the whole flow rate detection unit, by comparing the difference calculated by the first difference calculation unit or the second difference calculation unit with a second threshold value, when the gas leakage determination unit determines that there is no leakage of the carrier gas.

8. The gas chromatograph according to claim 3 , further comprising:
a detection abnormality determination unit which determines presence or absence of a detection abnormality in the whole flow rate detection unit, by comparing the difference calculated by the first difference calculation unit or the second difference calculation unit with a second threshold value, when the gas leakage determination unit determines that there is no leakage of the carrier gas.

Assignees

• Shimadzu Corp

Inventors

• Masuda Shingo

Classifications

• G01F1/36

  the pressure or differential pressure being created by the use of flow constriction · CPC title

• G05D7/06

  characterised by the use of electric means {(G05D7/005 takes precedence)} · CPC title

• G01N30/68

  Flame ionisation detectors · CPC title

• G01N2030/6013

  interfaces to detectors · CPC title

• G01N2030/025

  Gas chromatography · CPC title