Photoactive layer production process

Patent metadata

Field	Value
Publication number	US-10374181-B2
Application number	US-201414899309-A
Country	US
Kind code	B2
Filing date	Jun 17, 2014
Priority date	Jun 18, 2013
Publication date	Aug 6, 2019
Grant date	Aug 6, 2019

Abstract

The invention relates to processes for producing semi-transparent photoactive layers, and devices comprising the same. The invention provides a process for producing a semi-transparent photoactive layer comprising: a) disposing on a substrate a composition, which composition comprises a photoactive material or one or more precursors of a photoactive material, to form a resulting layer; and b) dewetting the resulting layer to form a dewet layer of the photoactive material, wherein the dewet layer of the photoactive material is semi-transparent. The invention also provides a semi-transparent photoactive layer comprising a substrate and, disposed on the substrate, a dewet layer of a photoactive material, wherein the dewet layer of a photoactive material comprises a plurality of absorbing regions which comprise the photoactive material and a plurality of transparent regions which do not substantially comprise the photoactive material. Devices and processes for producing devices comprising the semi-transparent layer are also disclosed, as are building components and automotive components comprising the semi-transparent layer.

First claim

The invention claimed is:

1. A process for producing a semi-transparent photoactive layer comprising:
a) disposing on a planar compact layer substrate having a substantially uniform thickness a composition comprising a photoactive material or one or more precursors of the photoactive material, to form a resulting layer; and
b) dewetting the resulting layer to form a semi-transparent photoactive layer comprising a plurality of absorbing regions that comprise the photoactive material and a plurality of transparent regions that do not comprise the photoactive material,
wherein the photoactive material comprises a perovskite.

2. A process according to claim 1 wherein (b) comprises dewetting the resulting layer until
a dewet layer of the photoactive material is formed that comprises a plurality of unconnected absorbing regions of the photoactive material, wherein the average radius of the absorbing regions is from 0.4 μm to 100 μm and the average distance between the centres of two adjacent absorbing regions is from 1 μm to 300 μm; or
a dewet layer of the photoactive material is formed that comprises a plurality of unconnected transparent regions that do not comprise the photoactive material, wherein the average diameter of the transparent regions is from 0.4 μm to 300 μm.

3. A process according to claim 1 wherein the perovskite is a mixed-anion perovskite comprising two or more different anions selected from halide anions and chalcogenide anions.

4. A process according to claim 1 wherein (b) comprises heating the resulting layer at a temperature of from 50° C. to 250° C. for a period of time in the range of 5 minutes to 120 minutes.

5. A process according to claim 1 wherein (b) comprises dewetting the resulting layer until;
a dewet layer of the photoactive material having a coverage of the photoactive material in the range of 20% to 90% is formed; or
a dewet layer of the photoactive material having an average transmission in the range of 10% to 90% for light for a wavelength in the range of 370 nm to 740 nm is formed; or
a dewet layer of the photoactive material having a coverage of the photoactive material in the range of 20% to 90% is formed; or
a dewet layer of the photoactive material having an average transmission of from10% to 90% for light with a wavelength of from 370 nm to 740 nm is formed.

6. A process according to claim 1 that further comprises:
c) blocking transparent regions of the photoactive layer with an electronic blocking material suitable for reducing the flow of current through transparent regions from a region on a first side of the photoactive layer to a region on a second side of photoactive layer.

7. A process according to claim 6 wherein the electronic blocking material comprises a self assembled monolayer or multilayer of a molecule, wherein the molecule binds selectively to the substrate, and wherein the electronic blocking material comprises a carboxylated cyclodextrin, a succinyl cyclodextrin, cyanoacrylic end functionalised penta(3-hexylthiophene), iodotetrafluorobenzene carboxylic acid, 4-guanidinobutyric acid, a C 10-30 -alkylphosphonic acid, (dicyanomethylene)-2-methyl-6-(4-dimethylaminostyryl)-4H-pyran, polyethylene glycol or octadecylphosphonic acid.

8. A process according to claim 7 wherein (c) comprises blocking the transparent regions of the photoactive layer with an electronic blocking material by treating the photoactive layer with a composition comprising a solvent and the electronic blocking material.

9. A process according to claim 6 wherein the electronic blocking material comprises an insulating polymer comprising polystyrene, poly(ethylene glycol) diacrylate, polyethylene, polypropylene, polyethylene terephthalate, polyvinyl acetate or polyvinyl chloride.

10. A process according to claim 9 wherein the electronic blocking material further comprises a dye, a pigment or a material that re-emits or scatters light.

11. A process according to claim 9 further comprising the step of cross-linking the insulating polymer by heating, irradiating the substrate, or by treating the polymer with a radical initiator.

12. A process according to claim 1 , further comprising the step of:
c) disposing on the photoactive layer a composition comprising an insulating component that wets transparent regions of the photoactive layer and that is suitable for reducing the flow of current through transparent regions from a region on a first side of the photoactive layer to a region on a second side of photoactive layer, and wherein the composition comprises a solvent, a p-type semiconductor and (dicyanomethylene)-2-methyl-6-(4-dimethylaminostyryl)-4H-pyran.

13. A process according to claim 1 that further comprises a step (z), performed before step (a), wherein (z) comprises treating the substrate with an insulator material suitable for reducing the flow of current through transparent regions in the dewet layer of the photoactive material and suitable for allowing the flow of current through absorbing regions in the dewet layer of the photoactive material,
wherein the flow of current is from a region on a first side of the photoactive layer to a region on a second side of photoactive layer,
wherein the insulator material comprises a material selected from yttrium (III) oxide, magnesium oxide and an insulating polymer, and
wherein (z) comprises disposing on the substrate a thin layer of the insulating material with a thickness of from 0.3 nm to 3 nm.

14. A process according to claim 1 that further comprises disposing in the transparent regions in the photoactive layer a dye, a pigment or a material that re-emits or scatters light.

15. A process according to claim 1 wherein (b) comprises dewetting the resulting layer by disrupting and forming holes in the resulting layer to form a photoactive layer comprising a plurality of absorbing regions that comprise the photoactive material and a plurality of transparent regions that do not comprise the photoactive material.

Assignees

• Isis Innovation
• Univ Oxford Innovation Ltd

Inventors

• Snaith Henry
• Burlakov Victor
• Ball James
• Eperon Giles
• Goriely Alain

Classifications

• H01L51/441

  Electricity · mapped topic

• Y02P70/521

  Cross-Sectional Technologies · mapped topic

• H01L51/0032

  Electricity · mapped topic

• H01L51/424 Primary

  Electricity · mapped topic

• H01L51/4226

  Electricity · mapped topic