Multi-terminal multi-junction photovoltaic cells

Patent metadata

Field	Value
Publication number	US-9184319-B2
Application number	US-201213350134-A
Country	US
Kind code	B2
Filing date	Jan 13, 2012
Priority date	Jan 14, 2011
Publication date	Nov 10, 2015
Grant date	Nov 10, 2015

Abstract

Methods and apparatuses are provided in connection with a transparent electrode on organic photovoltaic cells. A layer of dissolvable material is formed on a substrate. A solution having conductive nanowires suspended therein is deposited on the layer of dissolvable material. The solution is evaporated to form a nanowire mesh. The nanowire mesh is heated to sinter junctions between nanowires in the nanowire mesh. The nanowire mesh is affixed on a layer of one or more organic photovoltaic cells. The layer of dissolvable material is dissolved to deposit the nanowire mesh on the layer of one or more organic photovoltaic cells.

First claim

What is claimed is:

1. A method of forming transparent electrodes on organic photovoltaic cells, the method comprising:
forming a layer of dissolvable material on a substrate;
depositing conductive nanowires suspended in a solution on the layer of dissolvable material;
evaporating the solution to form a nanowire mesh;
heating the nanowire mesh to join junctions where nanowires cross in the nanowire mesh;
affixing the nanowire mesh on a layer of one or more organic photovoltaic cells; and
dissolving the layer of dissolvable material, the nanowire mesh forming a transparent electrode on the layer of one or more organic photovoltaic cells.

2. The method of claim 1 , further comprising depositing another layer of one or more organic photovoltaic cells over the nanowire mesh to form a stack of the respective layers of one or more photovoltaic cells with the nanowire mesh in between.

3. The method of claim 1 , wherein the conductive nanowires are silver.

4. The method of claim 1 , wherein the conductive nanowires of the solution are suspended in methanol.

5. The method of claim 1 , wherein the one or more organic photovoltaic cells of the layer are coupled in series.

6. The method of claim 1 , further including affixing to the nanowire mesh another layer of one or more organic photovoltaic cells, wherein the layers of one or more organic photovoltaic cells are respectively configured to absorb light of different spectral frequencies.

7. The method of claim 1 , further including affixing to the nanowire mesh a plurality of layers of one or more organic photovoltaic cells wherein the layers of one or more organic photovoltaic cells have respectively different photocurrent densities whereby each different photocurrent density is different than the photocurrent densities of each of the other plurality of photovoltaic layers.

8. The method of claim 1 , further comprising: compressing the nanowire mesh between the substrate and a plate to reduce roughness of the nanowire mesh.

9. The method of claim 2 , wherein depositing the other layer includes:
depositing a transparent insulating layer on the nanowire mesh;
depositing a second nanowire mesh on the transparent insulating layer; and
depositing the second organic photovoltaic cell on the second nanowire mesh.

10. The method of claim 1 , further comprising plating the nanowire mesh in a silver electrolyte solution.

11. The method of claim 1 , further comprising flattening the nanowire mesh.

12. The method of claim 11 , wherein flattening includes applying uniaxial pressure via a clean glass substrate and hydraulic press to the nanowire mesh.

13. The method of claim 1 , wherein the solution is configured and arranged to, in response to evaporation of solvent in the solution, form the mesh of nanowires on a sacrificial material.

14. The method of claim 1 , wherein the solution is configured and arranged to, in response to evaporation of solvent in the solution, form the mesh of nanowires on a sacrificial material, and wherein the sacrificial material is provided on the mesh of nanowires and wherein the substrate is affixed to the sacrificial material.

15. The method of claim 1 , further comprising using a solution of silver nanowires to form a mesh of nanowires on a sacrificial material, and wherein the sacrificial material is dissolvable to produce a mesh of silver nanowires on the layer of one or more organic photovoltaic cells.

16. The method of claim 1 , further comprising using a solution of silver nanowires to form a mesh of nanowires, and wherein the sacrificial material is dissolvable to produce a mesh of silver nanowires on the layer of one or more organic photovoltaic cells, and wherein the mesh of silver nanowires are semitransparent, having a transmissivity greater than 75%.

17. The method of claim 1 , further comprising using a solution of silver nanowires to form a mesh of silver nanowires, wherein the mesh of silver nanowires are flattened so that the nanowires protrude from the mesh no more than a thickness of the layer of one or more organic photovoltaic cells.

Assignees

• Lee Jung-Yong
• Peumans Peter
• Univ Leland Stanford Junior

Inventors

• Lee Jung-Yong
• Peumans Peter

Classifications

• Y10T428/31678

  Of metal · CPC title

• Y02E10/549

  Organic PV cells · CPC title

• H10F77/247

  comprising indium tin oxide [ITO] · CPC title

• H10F77/244 Primary

  made of transparent conductive layers, e.g. transparent conductive oxide [TCO] layers · CPC title

• H01L51/424

  Electricity · mapped topic