Method for producing paper, and pitch removal agent

Patent metadata

Field	Value
Publication number	US-10370794-B2
Application number	US-201515123528-A
Country	US
Kind code	B2
Filing date	Mar 11, 2015
Priority date	Mar 11, 2014
Publication date	Aug 6, 2019
Grant date	Aug 6, 2019

Abstract

Provided is a method for producing paper and a pitch removal agent that can remove pitch efficiently.
A pitch removal agent having an average polymerization degree of 300 to 2500, a saponification index of 70 to 88 mol % and satisfying, when the absorbance at a wavelength of 490 nm is designated as y (Abs) and the saponification index as x (mol %), the Numerical Formula (A) below is added to a pulp slurry during production of paper using waste paper in the step of deinking the waste paper by floatation and/or a step earlier:

y =−0.0297 x+b   (A)
(wherein, 70≤x≤88 and 2.80≤b≤3.03).

First claim

The invention claimed is:

1. A method for producing paper using waste paper, comprising:
polymerizing a compound in a presence of at least one chain-transfer agent containing an aldehyde, thereby obtaining polyvinyl acetate;
saponifying the polyvinyl acetate, thereby obtaining a polyvinyl alcohol; and
adding, to a pulp slurry in a step of deinking the waste paper by floatation and/or a step earlier, the polyvinyl alcohol having an average polymerization degree of 300 to 2500, a saponification index of 70 to 88 mol %, and an absorbance at a wavelength of 280 nm in an ultraviolet absorption spectrum of its 0.1 mass % aqueous solution of 0.2-1.0 Abs and satisfying, when an iodine absorbance at a wavelength of 490 nm is designated as y (Abs) and the saponification index as x (mol %), the following Numerical Formula (A):
[Numerical Formula 1]
y=− 0.0297 x+b   (A)

(wherein, 70≤x≤88 and 2.80≤b≤3.03).

2. The method according to claim 1 , wherein the iodine absorbance is measured at 25° C.

3. The method according to claim 1 , wherein the absorbance at the wavelength of 280 nm in the ultraviolet absorption spectrum of its 0.1 mass % aqueous solution of 0.2-1.0 Abs indicates double bonds adjacent to terminal carbonyl groups contained in a structure of the polyvinyl alcohol.

4. The method according to claim 1 , wherein the absorbance at the wavelength of 280 nm in the ultraviolet absorption spectrum of its 0.1 mass % aqueous solution is 0.3-0.5 Abs.

5. The method according to claim 1 , wherein the aldehyde is one selected from the group consisting of acetaldehyde, benzaldehyde, propionaldehyde, and n-butyraldehyde.

Assignees

• Kurita Water Ind Ltd
• Nippon Synthetic Chem Ind Co Ltd
• Mitsubishi Chem Corp

Inventors

• Taguchi Chigusa
• Tomita Munetoshi
• Takeda Hiroki

Classifications

• D21B1/32

  of waste paper · CPC title

• D21C5/025 Primary

  De-inking · CPC title

• D21C9/086 Primary

  with organic compounds or compositions comprising organic compounds · CPC title

• D21H11/14

  Secondary fibres (working-up waste paper D21C5/02) · CPC title

• D21C5/027

  Chemicals therefor · CPC title