Aqueous surfactant compositions

Patent metadata

Field	Value
Publication number	US-10370618-B2
Application number	US-201515505623-A
Country	US
Kind code	B2
Filing date	Aug 7, 2015
Priority date	Aug 27, 2014
Publication date	Aug 6, 2019
Grant date	Aug 6, 2019

Abstract

Aqueous surfactant compositions containing
one or more alpha-sulfo fatty acid disalts (A) of the general formula (I),

R 1 CH(SO 3 M 1 )COOM 2   (I),

in which the radical R 1 is a linear or branched alkyl or alkenyl radical with 6 to 18 carbon atoms and the radicals M 1 and M 2 , independently of one another, are selected from the group H, Li, Na, K, Ca/2, Mg/2, ammonium and alkanolamines,
one or more N-acylglutamic acid compounds (B) of the general formula (II),

M 3 OOC—CH 2 —CH 2 —CH(NH—CO—R 2 )—COOM 4   (II)
in which the radical R 2 is a linear or branched alkyl or alkenyl radical with 7 to 19 carbon atoms and the radicals M 3 and M 4 , independently of one another, are selected from the group H, Li, Na, K, Ca/2, Mg/2, ammonium and alkanolamines, and water, with specific limiting conditions, are disclosed. The compositions are transparent, storage-stable, exhibit good foaming ability, and are suitable for cosmetic products, detergents, and cleaners.

First claim

The invention claimed is:

1. An aqueous surfactant composition comprising
one or more alpha-sulfo fatty acid disalt (A) of general formula (I),
R 1 CH(SO 3 M 1 )COOM 2   (I)

in which the radical R 1 is a linear or branched alkyl or alkenyl radical with 6 to 18 carbon atoms and the radicals M 1 and M 2 , independently of one another, are selected from the group H, Li, Na, K, Ca/2, Mg/2, ammonium, and alkanolamine,
one or more N-acylglutamic acid compound (B) of general formula (II),
M 3 OOC—CH 2 —CH 2 —CH(NH—CO—R 2 )—COOM 4   (II)

in which the radical R 2 is a linear or branched alkyl or alkenyl radical with 7 to 19 carbon atoms and the radicals M 3 and M 4 , independently of one another, are selected from the group H, Li, Na, K, Ca/2, Mg/2, ammonium, and alkanolamines, and
water,
where the following provisos apply:
a content of the compounds (A) and (B) in the aqueous surfactant composition is, based on the total aqueous surfactant composition, at least 5% by weight;
if the aqueous surfactant composition comprises one or more ester sulfonate (E) of general formula (V),
R 5 CH(SO 3 M 7 )COOR 6   (V)

in which the radical R 5 is a linear or branched alkyl or alkenyl radical with 6 to 18 carbon atoms and the radical R 6 is a linear or branched alkyl or alkenyl radical with 1 to 20 carbon atoms, where the radical R 7 is an alkenyl radical or is branched only above 3 carbon atoms, and the radical M 7 is selected from the group Li, Na, K, Ca/2, Mg/2, ammonium, and alkanolamines, the compounds (A), based on the totality of the compounds (A) and (E), must be present to 50% by weight or more;
the weight ratio of the compounds (B):(A) in the aqueous surfactant composition is in the range from 2:1 to 6:1;
the pH of the aqueous surfactant composition is 8 or less;
the average transmission of the aqueous surfactant composition at 23° C.—measured using a TurbiScan MA 2000—is at least 80%.

2. The composition according to claim 1 , wherein the radical R 2 in the formula (II) is a saturated alkyl radical with 11 to 13 carbon atoms.

3. The composition according to claim 1 , wherein the radical R 1 in the formula (I) is a saturated, linear radical with 10 to 16 carbon atoms, wherein for compound (A), the fraction of the compound (A) in which the radical R 1 is a decyl or a dodecyl radical, based on the total amount of the compounds (A), is 90% by weight or more.

4. The composition according to claim 1 , wherein the radicals M 1 and M 2 are Na.

5. The composition according to claim 1 , wherein the radicals M 3 and M 4 are Na.

6. The composition according to claim 1 , wherein the composition comprises additionally one or more compound (C) of general formula (III)
R 4 COOM 5   (III)

in which the radical R 4 is a linear or branched alkyl or alkenyl radical with 7 to 19 carbon atoms and the radicals M 5 is selected from the group H, Li, Na, K, Ca/2, Mg/2, ammonium, and alkanolamine.

7. The composition according to claim 1 , wherein the composition comprises additionally one or more inorganic salt of sulfuric acid (D) of the general formula (IV)
(M 6 ) 2 SO 4   (IV)

wherein M 6 is selected from the group Li, Na, K, Ca/2, Mg/2, ammonium, and alkanolamine.

8. The composition according to claim 1 , wherein the content of the compounds (A) and (B) in the composition, based on the total composition, is in the range from 8 to 12% by weight.

9. The composition according to claim 1 , wherein the weight ratio of the compounds (B):(A) in the composition is in the range from 3:1 to 4.5:1.

10. The composition according to claim 1 , wherein the pH of the composition is in the range from 4.0 to 7.0.

11. The composition according to claim 1 , wherein the pH of the composition is in the range from 4.5 to 5.5.

12. A cosmetic product comprising a composition of claim 1 .

13. The cosmetic product of claim 12 in the form of hair shampoos, shower gels, soaps, syndets, washing pastes, washing lotions, scrub preparations, foam baths, oil baths, shower baths, shaving foams, shaving lotions, shaving creams, and dental care products.

14. A detergent or cleaner comprising a composition of claim 1 .

15. The detergent or cleaner of claim 14 in the form of a hard surface cleaner, a bath cleaner, a toilet cleaner, or a fragrance gel.

Assignees

• Basf Se

Inventors

• Behler Ansgar
• Brunn Claudia
• Stanislowski Detlev

Classifications

• C11D3/0094

  High foaming compositions · CPC title

• C11D1/37

  Mixtures of compounds all of which are anionic · CPC title

• C11D1/28

  Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides · CPC title

• C11D1/10 Primary

  Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof · CPC title

• A61Q19/10

  Washing or bathing preparations · CPC title