Process for simultaneous removal of arsenic and sulphur from hydrocarbon streams

Patent metadata

Field	Value
Publication number	US-10370604-B2
Application number	US-201715717009-A
Country	US
Kind code	B2
Filing date	Sep 27, 2017
Priority date	Sep 29, 2016
Publication date	Aug 6, 2019
Grant date	Aug 6, 2019

Abstract

The present invention describes a process for the simultaneous removal of arsenic and sulphur compounds from hydrocarbon streams of fossil origin, wherein hydrocarbon streams of fossil origin resulting from the retorting process of schist are purified by direct contact with hydrated iron oxide, such as goethite (α-FeOOH) in its raw natural form (limonite ore particles).

First claim

What is claimed is:

1. A process for simultaneous removal of arsenic and sulphur from hydrocarbon streams, comprising the steps of
a) grinding schist rock contaminated with arsenic and sulphur to obtain particles of schist rock;
b) removing the arsenic and sulphur from the particles of schist rock by
b1) mixing the particles of schist rock with particles of hydrated iron oxide (FeOOH) in a schist:FeOOH ratio, by weight, in the range from 100:1 to 1:100 and
b2) pyrolyzing the mixture obtained in step b1) with heating from ambient temperature to a temperature in the range 400-600° C.,

wherein the process takes place in the absence of hydrogen partial pressure and at atmospheric pressure.

2. The process according to claim 1 , wherein the particles of schist rock are ground to a granulometry in the range between 3.5 and 20 Tyler mesh.

3. The process according to claim 1 , wherein the particles of schist rock are mixed with particles of FeOOH in a schist:FeOOH ratio, by weight, in the range from 1:1 to 50:1.

4. The process according to claim 1 , wherein the particles of hydrated iron oxide (FeOOH) are particles of goethite (α-FeOOH) in the natural form of limonite ore.

5. The process according to claim 1 , wherein the pyrolyzing step b2) is carried out with heating from ambient temperature to a temperature of 500° C.

6. The process according to claim 1 , wherein arsenic compounds selected from the group consisting of organic compounds of As(III) and As(V) are removed.

7. The process according to claim 1 , wherein mercaptides are removed.

8. A process for simultaneous removal of arsenic and sulphur from hydrocarbon streams, comprising the steps of
a) extruding paste of limonite ore particles, followed by drying; and
b) removing arsenic and sulphur from a hydrocarbon stream contaminated with arsenic and sulphur by passing the hydrocarbon stream through the bed obtained in a) at a temperature of at least 80° C., varying up to 420° C.,
wherein the process takes place in the absence of hydrogen partial pressure and at atmospheric pressure.

9. The process according to claim 8 , wherein extrusion of particles of natural limonite and drying at 120° C., for 3 hours, are carried out in a N 2 stream.

10. The process according to claim 8 , wherein hydrocarbon streams of fossil origin are treated, selected from the group consisting of: hydrocarbon streams resulting from the industrial retorting process of schist rock; gaseous streams of light hydrocarbons; gaseous or liquid hydrocarbon streams derived from petroleum or from coal.

11. The process according to claim 10 , wherein the hydrocarbon stream of fossil origin is a hydrocarbon stream resulting from the industrial retorting process of schist rock and is selected from shale oil and the distilled derivatives thereof.

12. The process according to claim 10 , wherein the hydrocarbon stream of fossil origin is a gaseous stream of light hydrocarbons and is shale gas resulting from processes of fracturing in subsoils.

13. The process according to claim 8 , wherein arsenic compounds selected from the group consisting of organic compounds of As(III) and As(V) are removed.

14. The process according to claim 8 , wherein mercaptides are removed.

Assignees

• Petroleo Brasileiro S A —Petrobras

Inventors

• Ferraz De Souza Wladmir
• Duarte Marcus Vinicius Eiffle
• Ernst Lilian
• Tavares Da Silva Carmen Lucia

Classifications

• B01J20/0229

  Compounds of Fe · CPC title

• B01D2257/306

  Organic sulfur compounds, e.g. mercaptans · CPC title

• B01D53/64

  Heavy metals or compounds thereof, e.g. mercury · CPC title

• B01J20/3028

  Granulating, agglomerating or aggregating · CPC title

• B01J20/3078

  Thermal treatment, e.g. calcining or pyrolizing · CPC title