Process and apparatus for producing a mixed feed stream for a steam reforming plant

Patent metadata

Field	Value
Publication number	US-10633250-B2
Application number	US-201716085109-A
Country	US
Kind code	B2
Filing date	Mar 6, 2017
Priority date	Mar 16, 2016
Publication date	Apr 28, 2020
Grant date	Apr 28, 2020

Abstract

This invention relates to a process and an apparatus for producing a mixed feed stream for a steam reforming plant from a first feed stream containing methane and a second feed stream comprising higher hydrocarbons, olefins and diolefins. According to the invention, the required hydrogenation of the mono- and diolefins and the hydrodesulfurization of the organic sulfur compounds contained in the feed stream are carried out step by step under process conditions optimized in each case. Furthermore, the inlet temperature into the respective reaction zone is controlled such that overheating of the feedstocks is avoided, which otherwise leads to undesired coke deposits, cloggings and the accelerated deactivation of the catalysts used.

First claim

The invention claimed is:

1. A process for producing a mixed feed stream for a steam reforming plant containing at least one reforming stage, the mixed feed stream comprising a first feed stream containing methane and a second feed stream comprising higher hydrocarbons, olefins and diolefins, wherein the first and/or the second feed stream also contains sulfur compounds, and wherein the process comprises the following steps:
a) providing the first feed stream and the second feed stream;
b) heating the first feed stream in a first heating device;
c) combining and mixing at least a part of the first feed stream with the second feed stream, introducing this mixture into a first hydrogenation zone, at least partly converting the diolefins in the first hydrogenation zone under diolefin hydrogenation conditions, discharging a diolefin hydrogenation product stream from the first hydrogenation zone;
d) introducing the diolefin hydrogenation product stream into a second hydrogenation zone, at least partly converting the olefins in the second hydrogenation zone under olefin hydrogenation conditions, discharging an olefin hydrogenation product stream from the second hydrogenation zone;
e) introducing the olefin hydrogenation product stream into a third hydrogenation zone, at least partly converting the sulfur compounds in the third hydrogenation zone under conditions of the hydrodesulfurization (HDS) to desulfurized hydrocarbons and hydrogen sulfide, discharging an HDS product stream from the third hydrogenation zone;
f) introducing the HDS product stream into at least one adsorption zone, filled with an adsorbent selective for hydrogen sulfide, at least partly separating the hydrogen sulfide by adsorption on the adsorbent, discharging an adsorber product stream depleted of hydrogen sulfide from the adsorption zone; and
g) introducing the adsorber product stream as mixed feed stream into at least one reforming stage,
wherein:
i. after heating in the first heating device, the first feed stream is split up into a first hydrogenation partial stream and a second hydrogenation partial system,
ii. the first hydrogenation partial stream is introduced into a cooling device,
iii. a cooled first hydrogenation partial stream is discharged from the cooling device,
iv. the cooled first hydrogenation partial system is combined and mixed with the second feed stream,
v. the mixture thus obtained is introduced into the first hydrogenation zone.

2. The process according to claim 1 , wherein combining and mixing of at least a part of the first feed stream with the second feed stream is effected such that on entry into the first hydrogenation zone the mixture has a temperature of less than 300° C.

3. The process according to claim 1 , wherein the diolefin hydrogenation product stream is combined and mixed with the second hydrogenation partial stream and the mixture thus obtained is introduced into the second hydrogenation zone.

4. The process according to claim 1 , wherein an air cooler or a heat exchanger is used as cooling device, wherein in use of a heat exchanger cooling preferably is effected by indirect heat exchange against at least a part of the first feed stream before the first heating device.

5. The process according to claim 1 , wherein the cooling capacity of the cooling device and/or the quantity ratio of the first hydrogenation partial stream to the second hydrogenation partial stream is chosen such that on entry into the first hydrogenation zone the mixture has a temperature of less than 300° C.

6. The process according to claim 1 , wherein prior to combining and mixing with at least a part of the first feed stream the second feed stream is introduced into an adsorption zone which is filled with an adsorbent selective for metals.

7. The process according to claim 1 , wherein the first heating device is designed as heat exchanger, wherein the first feed stream is heated by indirect heat exchange against a hot raw synthesis gas product stream from the steam reforming plant, against a hot flue gas stream from the reformer furnace or against a hot product gas stream from the CO conversion plant (CO shift) downstream of the stream reforming plant.

8. The process according to claim 1 , wherein the steam reforming plant comprises a pre-reforming stage in which higher hydrocarbons are at least partly converted to methane under pre-reforming conditions.

Assignees

• Air Liquide

Inventors

• Ott Jorg
• Lehmann Maik
• Nieding Sebastian
• Szieleit Christian

Classifications

• C10G70/046

  by adsorption, i.e. with the use of solids · CPC title

• C01B3/38 Primary

  using catalysts · CPC title

• C10G45/02

  to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing · CPC title

• C10G67/06

  including a sorption process as the refining step in the absence of hydrogen · CPC title

• C10G25/00

  Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents · CPC title