ABS-based resin composition and method article manufactured therefrom

Patent metadata

Field	Value
Publication number	US-10364346-B2
Application number	US-201615532067-A
Country	US
Kind code	B2
Filing date	Nov 11, 2016
Priority date	Nov 13, 2015
Publication date	Jul 30, 2019
Grant date	Jul 30, 2019

Abstract

Disclosed are an ABS-based resin composition and a molded article manufactured therefrom. More particularly, the ABS-based resin composition according to the present disclosure includes (a) 22.5 to 50% by weight of a vinyl cyan compound-conjugated diene-based rubber-like polymer-aromatic vinyl compound copolymer resin; (b) 47.5 to 75% by weight of an aromatic vinyl compound-vinyl cyan compound copolymer resin; (c) 1 to 6% by weight of a polyether ester amide resin; and (d) 1.5 to 3% by weight of an ethoxylated alkylamine-based antistatic agent, thereby providing a high humidification amount and less deformation. Accordingly, the present disclosure relates to an ABS-based resin composition suitable for application to disks for air washers, humidifiers, and the like, and a molded article manufactured therefrom.

First claim

The invention claimed is:

1. A method of preparing an ABS-based resin composition, the method comprising: a step of feeding (a) 22.5 to 50% by weight of a vinyl cyan compound-conjugated diene-based rubber-like polymer-aromatic vinyl compound copolymer resin, wherein (a) the vinyl cyan compound-conjugated diene-based rubber-like polymer-aromatic vinyl compound copolymer resin is prepared by graft-polymerizing 40 to 70% by weight of a conjugated diene-based rubber-like polymer having an average particle diameter of 2500 to 3500 Å with 8 to 48% by weight of an aromatic vinyl compound and 6 to 24% by weight of a vinyl cyan compound; (b) 47.5 to 75% by weight of an aromatic vinyl compound-vinyl cyan compound copolymer resin; (c) 1 to 6% by weight of a polyether ester amide resin; and (d) 1.5 to 3% by weight of an ethoxylated alkylamine-based antistatic agent into an extruder, followed by mixing and extruding in a 180 to 220° C. barrel.

2. The method according to claim 1 , wherein (c) the polyether ester amide resin is generated by polycondensation of a polyamide having a reactive terminal with a polyether having a reactive terminal.

3. The method according to claim 1 , wherein a humidification amount measured for six hours by means of a humidifier (LAW-A049AS, LG Electronics) that is equipped with 46 disks with a diameter of 215 mm and a thickness of 1.6 mm manufactured from the ABS-based resin composition is 400 cc/hr or more.

4. The method according to claim 1 , wherein, after marking 90°, 180°, 270°, and 360° spots on an air washer disk with a diameter of 215 mm and a thickness of 1.6 mm manufactured from the ABS-based resin composition and then immersing the air washer disk in a water bath for 168 hours, deformation ranges of the marked spots are 1.0 mm or less.

5. A molded article manufactured from the method according to claim 1 .

6. A product comprising a disk or disk assembly manufactured from the method according to claim 1 .

7. The product according to claim 6 , wherein the product is an air washer, a humidifier, an air purifier, a humidifier-combined air washer, a humidifier-combined air purifier, or an air washer air purifier.

8. The method according to claim 1 , wherein (b) the aromatic vinyl compound-vinyl cyan compound copolymer resin comprises 55 to 80% by weight of an aromatic vinyl compound and 20 to 45% by weight of a vinyl cyan compound.

9. The method according to claim 1 , wherein the vinyl cyan compound is one or more selected from the group consisting of acrylonitrile, methacrylonitrile, and ethacrylonitrile.

10. The method according to claim 1 , wherein the conjugated diene-based rubber-like polymer is one or more selected from the group consisting of a butadiene rubbery copolymer, a butadiene-styrene rubbery copolymer, and an isoprene rubbery polymer.

11. The method according to claim 1 , wherein the aromatic vinyl compound is one or more selected from the group consisting of styrene, α-methylstyrene, o-ethylstyrene, p-ethylstyrene, and vinyltoluene.

12. The method according to claim 1 , wherein an alkyl group of (d) the ethoxylated alkylamine-based antistatic agent has a carbon number of 13 to 15.

13. The method according to claim 1 , wherein the ABS-based resin composition further comprises one or more additives selected from the group consisting of a flame retardant, an anti-bacterial agent, an anti-dripping agent, a releasing agent, an antioxidant, a heat stabilizer, a lubricant, a UV stabilizer, an impact modifier, a filler, an inorganic additive, a stabilizer, a pigment, and a dye.

14. An apparatus comprising:
a molded disk assembly comprising a plurality of disks arranged in parallel and formed from an ABS-based resin composition, comprising:
(a) 22.5 to 50% by weight of a vinyl cyan compound-conjugated diene-based rubber-like polymer-aromatic vinyl compound copolymer resin;
(b) 47.5 to 75% by weight of an aromatic vinyl compound-vinyl cyan compound copolymer resin;
(c) 1 to 6% by weight of a polyether ester amide resin; and
(d) 1.5 to 3% by weight of an ethoxylated alkylamine-based antistatic agent.

15. The apparatus of claim 14 wherein the plurality of disks comprise air washer disks.

16. The apparatus of claim 14 wherein the plurality of disks comprise humidifier disks or air purifier disks.

17. The apparatus of claim 14 wherein the plurality of disks are coupled in parallel to a shaft or a supporter.

Assignees

• Lg Chemical Ltd

Inventors

• Ryoo Seung Cheol
• Lee Soo Kyeong
• Kim Seong Lyong

Classifications

• C08L2205/03

  containing three or more polymers in a blend · CPC title

• C08L25/12 Primary

  with unsaturated nitriles · CPC title

• C08L33/20 Primary

  Homopolymers or copolymers of acrylonitrile (C08L55/02 takes precedence) · CPC title

• C08J5/00

  Manufacture of articles or shaped materials containing macromolecular substances (manufacture of semi-permeable membranes B01D67/00 - B01D71/00) · CPC title

• C08L55/02 Primary

  ABS [Acrylonitrile-Butadiene-Styrene] polymers · CPC title