Dielectric composition and multilayer electronic component

Patent metadata

Field	Value
Publication number	US-10358388-B2
Application number	US-201815889856-A
Country	US
Kind code	B2
Filing date	Feb 6, 2018
Priority date	Nov 6, 2017
Publication date	Jul 23, 2019
Grant date	Jul 23, 2019

Abstract

A multilayer electronic component includes: a body including first and second internal electrodes alternately disposed with respective dielectric layers interposed therebetween; and first and second external electrodes disposed on the body to be connected to the first and second internal electrodes, respectively, wherein each of the dielectric layers includes Ba m TiO 3 and includes a plurality of grains and grain boundaries formed between adjacent grains, and a sum of contents of Si and Dy in the grain boundary is 10 to 15 parts by weight.

First claim

What is claimed is:

1. A dielectric composition comprising:
a base material powder including Ba m TiO 3 (0.995≤m≤1.010), (Ba,Ca)(Ti,Zr)O 3 , Ba(Ti,Zr)O 3 , or (Ba,Ca)(Ti,Sn)O 3 modified from Ba m TiO 3 ;
a first accessory component including a variable-valence acceptor element oxide or carbonate of manganese (Mn), chromium (Cr), iron (Fe), cobalt (Co), copper (Cu), or zinc (Zn) and a fixed valence acceptor element oxide or carbonate of magnesium (Mg) or zirconium (Zr);
a second accessory component including an oxide or a carbonate including silicon (Si) or glass including silicon (Si);
a third accessory component including BaO or BaCO 3 ; and
a fourth accessory component including Dy and V 2 O 5 ,
wherein a sum of contents of Si and Dy in a grain boundary formed between adjacent grains of the dielectric composition is 10 to 15 parts by weight based on 100 parts by weight of an overall amount of oxide in the grain boundary.

2. The dielectric composition of claim 1 , wherein a content of Mg of the first accessory component is 0.5 parts by weight or less based on 100 parts by weight of an overall amount of oxide and carbonate.

3. The dielectric composition of claim 1 , wherein the second accessory component further includes an oxide or a carbonate including aluminum (Al).

4. The dielectric composition of claim 1 , wherein the fourth accessory component further includes a rare earth element of Y, Gd, Sm, Nd, Tb, Eu, Yb, Er, and Lu.

5. The dielectric composition of claim 1 , wherein a ratio of a content of Dy to a content of Si in the grain boundary formed between adjacent grains of the dielectric composition is 1.0 to 1.6.

6. A multilayer electronic component comprising:
a body including first and second internal electrodes alternately disposed with respective dielectric layers interposed therebetween; and
first and second external electrodes disposed on the body to be connected to the first and second internal electrodes, respectively,
wherein the dielectric layers include the dielectric composition of claim 1 .

7. A multilayer electronic component comprising:
a body including first and second internal electrodes alternately disposed with respective dielectric layers interposed therebetween; and
first and second external electrodes disposed on the body to be connected to the first and second internal electrodes, respectively,
wherein each of the dielectric layers includes Ba m TiO 3 (0.995≤m≤1.010) and includes a plurality of grains and grain boundaries formed between adjacent grains, and
a sum of contents of Si and Dy in the grain boundaries is 10 to 15 parts by weight, based on 100 parts by weight of an overall amount of oxide in the grain boundaries.

8. The multilayer electronic component of claim 7 , wherein in the grain boundary of the dielectric layer, a ratio (Dy/Si) of Dy to Si by weight is 1.0 to 1.6.

9. The multilayer electronic component of claim 7 , wherein a thickness of the grain boundary of the dielectric layer is within a range from 0.7 to 1.5 nm.

10. The multilayer electronic component of claim 7 , wherein the grain boundary of the dielectric layer includes a dielectric grain having a core-shell structure, and
a size of the grain is 50 to 500 nm, and a thickness of the dielectric layer is 0.9 μm or less.

11. The multilayer electronic component of claim 7 , wherein a thickness deviation ((thickness standard deviation/thickness average value)×100) of the grain boundary is 10 or less.

12. The multilayer electronic component of claim 7 , wherein the first and second internal electrodes include Ni or Ni alloys.

13. A dielectric composition comprising:
a base material powder including Ba m TiO 3 (0.995≤m≤1.010);
a first accessory component including a variable-valence acceptor element oxide or carbonate of manganese (Mn), chromium (Cr), iron (Fe), cobalt (Co), copper (Cu), or zinc (Zn) and a fixed valence acceptor element oxide or carbonate of magnesium (Mg) or zirconium (Zr);
a second accessory component including an oxide or a carbonate including silicon (Si) or glass including silicon (Si);
a third accessory component including BaO or BaCO 3 ; and
a fourth accessory component including Dy and V 2 O 5 ,
wherein a content of Si in a grain boundary formed between adjacent grains of the dielectric composition is at least 4.2 parts by weight based on 100 parts by weight of an overall amount of oxide in the grain boundary, and
wherein a ratio of a content of Dy to a content of Si in a grain boundary formed between adjacent grains of the dielectric composition is 1.0 to 1.6.

14. The dielectric composition of claim 13 , wherein a sum of contents of Si and Dy in the grain boundary formed between adjacent grains of the dielectric composition is 10 to 15 parts by weight based on 100 parts by weight of an overall amount of oxide in the grain boundary.

15. The dielectric composition of claim 13 , wherein the base material powder further includes (Ba,Ca)(Ti,Zr)O 3 , Ba(Ti,Zr)O 3 , or (Ba,Ca)(Ti,Sn)O 3 modified from Ba m TiO 3 .

16. The dielectric composition of claim 13 , wherein the second accessory component further includes an oxide or a carbonate including aluminum (Al).

17. The dielectric composition of claim 13 , wherein the fourth accessory component further includes a rare earth element of Y, Gd, Sm, Nd, Tb, Eu, Yb, Er, and Lu.

18. A multilayer electronic component comprising:
a body including first and second internal electrodes alternately disposed with respective dielectric layers interposed therebetween; and
first and second external electrodes disposed on the body to be connected to the first and second internal electrodes, respectively,
wherein the dielectric layers include the dielectric composition of claim 13 .

Assignees

• Samsung Electro Mech

Inventors

• Yun Ki Myoung
• Jung Dong Jun
• Park Jae Sung
• Ham Tae Young
• Kwon Hyung Soon
• Kim Jong Han
• Kim Hyoung Uk

Classifications

• H01G4/0085

  Fried electrodes · CPC title

• H01G4/1281

  with grain boundary layer · CPC title

• H01G4/1227

  based on alkaline earth titanates · CPC title

• H01G4/30

  Stacked capacitors (H01G4/33 takes precedence) · CPC title

• C04B2235/6582

  Hydrogen containing atmosphere · CPC title