Self healing materials and cables

Patent metadata

Field	Value
Publication number	US-10354776-B2
Application number	US-201515306377-A
Country	US
Kind code	B2
Filing date	Apr 10, 2015
Priority date	Apr 24, 2014
Publication date	Jul 16, 2019
Grant date	Jul 16, 2019

Abstract

The present invention concerns a cable comprising an elongated conducting element and a self-healing material surrounding said elongated conducting element, characterized in that the self-healing material is a cross-linked material obtained from a polymeric composition comprising: A. a polymer matrix comprising at least one olefin polymer with hydrophilic moiety, and B. at least one amphiphilic compound, as self-healing additive.

First claim

The invention claimed is:

1. Cable comprising an elongated conducting element and a self-healing material surrounding said elongated conducting element, wherein the self-healing material is a cross-linked material obtained from a polymeric composition comprising:
A. a polymer matrix comprising at least one olefin polymer with hydrophilic moiety, and
B. at least one amphiphilic compound, as self-healing additive,
wherein the polymeric composition comprises at least 10 % by weight of amphiphilic compound(s) B over the total weight of the polymeric composition.

2. Cable according to claim 1 , wherein the olefin polymer with hydrophilic moiety is an ethylene vinyl acetate copolymer.

3. Cable according to claim 1 , wherein the polymer matrix A is only composed of one or several olefin polymer(s) with hydrophilic moiety.

4. Cable according to claim 1 , wherein the amphiphilic compound is able to form intermolecular interactions with the olefin polymer with hydrophilic moiety, during the healing process.

5. Cable according to claim 1 , wherein the amphiphilic compound and the olefin polymer with hydrophilic moiety are compatible together.

6. Cable according to claim 1 , wherein the amphiphilic compound comprises:
an aliphatic chain, saturated or unsaturated, comprising at least four carbon atoms, as lipophilic moiety, and
a hydrophilic moiety.

7. Cable according to claim 6 , wherein the hydrophilic moiety is selected among carboxylic acid, precursors of carboxylic acids, ionic form of carboxylic acids, esters, amines, amides, alcohols, any derivative thereof, and any combination thereof.

8. Cable according to claim 1 , wherein the amphiphilic compound is a polymeric compound selected among grafted olefin polymers, polymers with hydrophilic moities, and any derivative thereof.

9. Cable according to claim 1 , wherein the amphiphilic compound is a non-polymeric compound selected among fatty acids and any derivative thereof.

10. Cable according to claim 9 , wherein the fatty acid is selected among oleic acid, ricinoleic acid and any derivative thereof.

11. Cable according to claim 9 , wherein the fatty acid is triglycerides of oleic acid or triglycerides of ricinoleic acid.

12. Cable according to claim 9 , wherein the fatty acid is selected among oil polyols.

13. Cable according to claim 1 , wherein the polymeric composition comprises at least two amphiphilic compounds B.

14. Cable according to claim 1 , wherein the polymeric composition comprises at least 30 % by weight of ethylene vinyl acetate copolymer over the total weight of the polymeric composition.

15. Cable according to claim 1 , wherein the polymeric composition comprises less than 40 % by weight of flame retardant filler over the total weight of the polymeric composition.

16. Cable according to claim 1 , wherein the polymeric composition of the invention comprises:
A. the polymer matrix comprising at least one ethylene vinyl acetate copolymer with a vinyl acetate moiety content of at least 40 % by weight, and
B. at least 30 parts by weight of the amphiphilic compound(s) with respect to 100 parts by weight of polymer matrix A.

17. Cable according to claim 1 , wherein the polymeric composition further comprises an organic peroxide as cross-linking agent.

18. Cable according to claim 1 , wherein the cross-linked material is an extruded material.

19. Cable according to claim 1 , wherein said cross-linked material is a material selected among an insulating layer, a protecting jacket, and a bedding.

20. Process of manufacturing the cable according to claim 1 , wherein the process comprises the following steps:
i. mixing the polymeric composition;
ii. applying the mixed polymeric composition around the elongated conducting element; and
iii. cross-linking the polymeric composition of step ii, to obtain the cross- linked material surrounding the elongated conducting element.

21. The cable as claimed in claim 1 , wherein the amphipilic compound is different from the olefin polymer with hydrophilic moiety.

22. A crosslinked product obtained from nanocomposite of polymer and POSS (Polyhedral Oligomeric Silsesquioxane), comprising:
at least one amphiphilic dispersing agent selected from the group consisting of an amphiphilic carboxylic acid-based dispersing agent, an amphiphilic amine-based dispersing agent, a vegetable oil having a triglyceride structure, a process oil having an ester group, and a mixture thereof.

23. A crosslinked product obtained from nanocomposite of polymer and organonanoclay, comprising :
(b1) an amphiphilic dispersing agent selected from the group consisting of an amphiphilic carboxylic acid-based dispersing agent, an amphiphilic amine-based dispersing agent, and a mixture thereof; and
(b2) an amphiphilic oil selected from the group consisting of a vegetable oil having a triglyceride structure, a process oil having an ester group, and a mixture thereof.

Assignees

• Nexans

Inventors

• Bacquet Gérard Marcel
• Kim Seong-Jin
• Ahn Dae-Up
• Kim Kwon-Soon
• Bae Ji-Hyun
• Kim Young-Gu
• Jeon Jun-Bae
• Baek Mi-Geon

Classifications

• H02G1/16

  for repairing insulation or armouring of cables · CPC title

• H01B7/1895

  Internal space filling-up means · CPC title

• H01B3/448 Primary

  from other vinyl compounds · CPC title

• H01B3/441 Primary

  from alkenes · CPC title

• C08L23/0853

  Ethylene vinyl acetate copolymers · CPC title