Microcellular foamed nanocomposite and preparation method thereof

Patent metadata

Field	Value
Publication number	US-2017190862-A1
Application number	US-201615393469-A
Country	US
Kind code	A1
Filing date	Dec 29, 2016
Priority date	Jan 5, 2016
Publication date	Jul 6, 2017
Grant date	—

Abstract

A microcellular foaming nanocomposite includes an elastomeric polymer; a nanofiller; at least two of amphiphilic dispersing agents; a chemical blowing agent; an activator for chemical blowing agent; and a crosslinking agent. The present arrangement also relates to a preparation method of a microcellular foamed nanocomposite.

First claim

1 . A microcellular foaming nanocomposite comprising:
an elastomeric polymer; a nanofiller; at least two of amphiphilic dispersing agents; a chemical blowing agent; an activator for chemical blowing agent; and a crosslinking agent.

2 . The nanocomposite according to claim 1 , wherein the elastomeric polymer is ethylene-propylene-dien copolymer (EPDM).

3 . The nanocomposite according to claim 1 , wherein the nanofiller is selected from the group consisting of carbon black, nanoclay, nanosilica, polyhedral oligomer silsesquioxane (POSS), layered double hydroxide, nano-CaCO 3 , carbon nanotube, griffin, colloid nanoparticle, and a mixture thereof.

4 . The nanocomposite according to claim 1 , wherein the at least two of amphiphilic dispersing agents are selected from the group consisting of an amphiphilic carboxylic acid based compound, an amphiphilic amine based compound, and an amphiphilic fatty acid ester compound, separately.

5 . The nanocomposite according to claim 1 , wherein the chemical blowing agent is selected from the group consisting of p,p′-oxybis(benzenesulfonylhydrazide), (p-toluenesulfonylhydrizide (TSH), (p-toluenesulfonylsemicarbazide (TSSC), azidodicarbonamide (ADC), and the mixture thereof.

6 . The nanocomposite according to claim 1 , wherein the activator is selected from the group consisting of metallic activator, acidic activator, basic activator, urea-based activator, and a mixture thereof.

7 . The nanocomposite according to claim 1 , wherein the nanocomposite comprises elastomeric polymer in an amount of 100 parts by weight, nanofiller in an amount of 0.1 to 20 parts by weight, amphiphilic dispersing agents in an amount of 1 to 40 parts by weight, chemical blowing agent in an amount of 1 to 20 parts by weight, activator in an amount of 0.1 to 10 parts by weight, and crosslinking agent in amount of 0.1 to 10 parts by weight, the amounts being expressed with respect to 100 parts by weight of elastomeric polymer.

8 . Microcellular foamed nanocomposite obtained from the microcellular foaming nanocomposite according to claim 1 .

9 . The microcellular foamed nanocomposite according to claim 8 , wherein it has an average cell size of 120 μm or below, or a cell density of 10 7 cells/cm 3 or more.

10 . A method for preparing a microcellular foamed nanocomposite according to claim 8 , comprising the steps of:
a) mixing elastomeric polymer, nanofiller, at least two of amphiphilic dispersing agents, chemical blowing agent, activator for chemical blowing agent and crosslinking agent; b) crosslinking the mixture obtained from the step a) under the condition of high pressure; and c) releasing the pressure and foaming.

11 . A cable comprising at least one elongated conductive element surrounded by at least one microcellular foamed nanocomposite according to claim 8 .

12 . A cable comprising at least one elongated conductive element surrounded by at least one microcellular foamed nanocomposite obtained from the method according to claim 10 .

Assignees

• Nexans

Inventors

• Ahn Dae-Up
• Jeon Jun-Bae
• Kim Seong-Jin

Classifications

• C08J2203/04

  N2 releasing, ex azodicarbonamide or nitroso compound · CPC title

• C08J2323/16

  Ethene-propene or ethene-propene-diene copolymers · CPC title

• C08J9/105

  containing sulfur · CPC title

• C08J2207/06

  Electrical wire insulation · CPC title

• C08J2201/026

  Crosslinking before of after foaming · CPC title