Method of patterning target layer
US-2018113975-A1 · Apr 26, 2018 · US
US10353127B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10353127-B2 |
| Application number | US-201815948770-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 9, 2018 |
| Priority date | Aug 24, 2015 |
| Publication date | Jul 16, 2019 |
| Grant date | Jul 16, 2019 |
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The wire grid polarizer (WGP) comprises an array of parallel, elongated nanostructures located over a surface of a transparent substrate and a plurality of spaces, including a space between adjacent nanostructures. Each of the nanostructures can include (1) a plurality of parallel, elongated wires located on the substrate, including an inner-pair located between an outer-pair; (2) lateral-gaps between each wire of the outer-pair and an adjacent wire of the inner-pair; (3) and a center-gap between the two wires of the inner-pair.
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What is claimed is: 1. A method of making a wire grid polarizer (WGP), the method comprising the following steps: providing an array of parallel, elongated support ribs located over a transparent substrate and spaces between the support ribs, the spaces being solid-material-free; conformal coating the substrate and the support ribs with a first-layer while maintaining solid-material-free at least a portion of the spaces between the support ribs; etching the first-layer to remove horizontal segments and leaving an array of inner-pairs of parallel, elongated wires along sides of the support ribs, each wire of each inner-pair being separate from the other wire of the inner-pair; conformal coating the substrate and the support ribs with a second-layer while maintaining solid-material-free at least a portion of the spaces between the support ribs; etching the second-layer to remove horizontal segments and leaving middle-pairs, the middle-pairs being an array of parallel, elongated wires, each wire of each middle-pair being separated from the other wire of the middle-pair by wires of the inner-pair; conformal coating the substrate and the support ribs with a third-layer while maintaining solid-material-free at least a portion of the spaces between the support ribs; etching the third-layer to remove horizontal segments and leaving outer-pairs, the outer-pairs being an array of parallel, elongated wires along sides of the support ribs, each wire of each outer-pair being: spaced apart with respect to the other wire of the outer-pair; and spaced apart with respect to wires of the inner-pair by wires of a middle-pair, the wires of the middle-pair being formed of material of the second-layer; filling spaces between the support ribs with a solid material; and etching the solid material, the support ribs, and the middle-pair to form: lateral-solid-material-free-regions between at least a portion of each wire of each outer-pair and at least a portion of an adjacent wire of the inner-pair; and center-solid-material-free-regions between at least a portion of the two wires of each inner-pair. 2. The method of claim 1 , wherein the middle-pair and the solid material are both made of the same material. 3. The method of claim 1 , wherein etching the support ribs, the middle-pair, and the solid material include: etching through the support ribs then into the transparent substrate between the two wires of each inner-pair; etching away completely the middle-pair and continuing to etch into the transparent substrate between each wire of each outer-pair an adjacent wire of the inner-pair; and etching the solid material and continuing to etch into the transparent substrate. 4. The method of claim 1 , wherein the center-solid-material-free-regions extend from a distal-end, farther from the transparent substrate, to a proximal-end, closer to the transparent substrate, of an adjacent wire of the inner-pair, and extend beyond the proximal-end into the transparent substrate for a distance of at least 10% of a thickness of the adjacent wire of the inner-pair. 5. The method of claim 1 , wherein the center-solid-material-free-regions extend for 70% to 98% of a distance from a distal-end, farther from the transparent substrate, towards a proximal-end, closer to the transparent substrate, of an adjacent wire of the inner-pair. 6. The method of claim 1 , further comprising etching the transparent substrate between adjacent support ribs, forming base-ribs, each base-rib having one of the inner-pairs and one of the outer-pairs thereon. 7. The method of claim 1 , further comprising etching the transparent substrate between adjacent support ribs, forming base-ribs, each base-rib having one of the inner-pairs and one of the outer-pairs thereon, and forming a solid-material-free space between adjacent base-ribs, each solid-material-free space: extending from a distal-end, farther from the transparent substrate, towards a proximal-end, closer to the transparent substrate, of an adjacent wire of the outer-pair; and extending beyond the proximal-end into the transparent substrate for a distance of at least 15% of a thickness of the adjacent wire of the outer-pair. 8. The method of claim 1 , wherein the lateral-solid-material-free-regions extend for at least 80% of a distance from a distal-end, farther from the transparent substrate, towards a proximal-end, closer to the transparent substrate, of an adjacent wire of the inner-pair. 9. The method of claim 1 , wherein the lateral-solid-material-free-regions extend for 70% to 98% of a distance from a distal-end, farther from the transparent substrate, towards a proximal-end, closer to the transparent substrate, of an adjacent wire of the inner-pair. 10. The method of claim 1 , wherein etching the support ribs includes forming the center-solid-material-free-region from a distal-end of the inner-pair farthest from the transparent substrate to a proximal-end of the inner-pair closest to the transparent substrate. 11. The method of claim 1 , wherein one of the first-layer or the third-layer is reflective and the other of the first-layer or the third-layer is absorptive. 12. The method of claim 11 , wherein the second-layer is transparent. 13. The method of claim 1 , wherein the second-layer is made of a different material than the first-layer and the third-layer is made of a different material than the first-layer or the second-layer. 14. A method of making a wire grid polarizer (WGP), the method comprising the following steps: providing an array of parallel, elongated support ribs located over a transparent substrate and spaces between the support ribs, the spaces being solid-material-free; conformal coating the substrate and the support ribs with a first-layer while maintaining solid-material-free at least a portion of the spaces between the support ribs; etching the first-layer to remove horizontal segments and leaving an array of inner-pairs of parallel, elongated wires along sides of the support ribs, each wire of each inner-pair being separate from the other wire of the inner-pair, and using the inner-pair as a mask and etching into the substrate; conformal coating the substrate and the support ribs with a second-layer while maintaining solid-material-free at least a portion of the spaces between the support ribs; etching the second-layer to remove horizontal segments and leaving middle-pairs, the middle-pairs being an array of parallel, elongated wires, each wire of each middle-pair being separated from the other wire of the middle-pair by wires of the inner-pair; conformal coating the substrate and the support ribs with a third-layer while maintaining solid-material-free at least a portion of the spaces between the support ribs; etching the third-layer to remove horizontal segments and leaving outer-pairs, the outer-pairs being an array of parallel, elongated wires along sides of the support ribs, each wire of each outer-pair being: spaced apart with respect to the other wire of the outer-pair; and spaced apart with respect to wires of the inner-pair by wires of a middle-pair, the wires of the middle-pair being formed of material of the second-layer; and etching the support ribs and the middle-pair to form: lateral-solid-material-free-regions between at least a portion of each wire of each outer-pair and at least a portion of an adjacent wire of the inner-pair; and center-solid-material-free-regions between at least a portion of the two wires of each inner-pair. 15. The method of claim 14 , wherein an order of the steps is: providing the array of parallel, elongated support ribs; conformal coatin
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