Coating process and coating for press-fit contact

Patent metadata

Field	Value
Publication number	US-10348017-B2
Application number	US-201514600584-A
Country	US
Kind code	B2
Filing date	Jan 20, 2015
Priority date	Jul 20, 2012
Publication date	Jul 9, 2019
Grant date	Jul 9, 2019

Abstract

A process is disclosed for coating a substrate. The process includes providing a substrate having at least one free surface; depositing a first layer of a first material on the free surface of the substrate; depositing a second layer of a second material, different from the first material, on the first layer; depositing a third layer of a third material, different from the first and second materials, on the second layer; depositing a protective layer of a fourth material, different from the first, second and third materials, on the third layer; and performing a reflow of at least the second and third layers from the first, second, and third layers, by transfer of heat through the thermal contact on the protective layer, such that the protective layer prevents oxidation of at least the third layer.

First claim

What is claimed is:

1. A process for coating a substrate comprising the steps of:
providing a substrate having at least one free surface;
depositing a first layer of a first material on the free surface of the substrate;
depositing a second layer of a second material, different from the first material, on the first layer;
depositing a third layer of a third material, different from the first and second materials, on the second layer;
depositing a protective layer of a fourth material, different and separate from the first, second and third materials, on the third layer, the protective layer is an outermost layer deposited on the substrate, the fourth material of the protective layer consists of graphite powder and microcrystalline active carbon; and
performing a reflow of at least the second and third layers from the first, second, and third layers, by transfer of heat through the thermal contact on the protective layer, such that the fourth material of the protective layer does not melt or mix with the first, second, and third layers during reflow and the protective layer prevents oxidation of at least the third layer.

2. The process of claim 1 , wherein a temperature of the reflow is 1.5 to 3 times higher than the melting temperature of the third material.

3. The process of claim 1 , wherein the temperature of the reflow is 0.8 to 1.5 times higher than the melting temperature of the second material.

4. The process of claim 1 , wherein the temperature of the reflow is less than or equal to the melting temperature of the first material or the substrate.

5. The process of claim 1 , wherein the fourth material is a mixture of 80% to 95% of graphite and the remainder of microcrystalline active carbon.

6. The process of claim 1 , wherein the fourth material is a mixture of 90% of graphite and of 10% of microcrystalline active carbon.

7. The process of claim 1 , wherein the first, second, and third materials include elementary metals.

8. The process of claim 1 , wherein the third material has a melting point lower than a melting point of the first and second materials.

9. The process of claim 1 , wherein the second material has a melting temperature 1.5 to 3 times greater than a melting temperature of the third material.

10. The process of claim 1 , wherein the substrate and the first material each have a melting temperature at least 2 to 3 times higher than a melting temperature of the second material.

11. The process of claim 1 , wherein the fourth material has a specific heat 2 to 3 times higher than a specific heat of the second and third materials.

12. The process of claim 1 , wherein the first material includes nickel.

13. The process of claim 1 , wherein the second material includes zinc or antimony.

14. The process of claim 1 , wherein the third material includes tin or silver.

15. The process of claim 1 , wherein a temperature of the reflow is at least 350° C.

16. The process of claim 1 , wherein a temperature of the reflow is in a range from 350° C. to 600° C.

17. The process of claim 1 , wherein a temperature of the reflow is in a range from 380° C. to 580° C.

18. The process of claim 1 , wherein a temperature of the reflow is in a range from 400° C. to 550° C.

19. The process of claim 1 , wherein a duration of the reflow is between 1 second and 15 seconds.

20. The process of claim 1 , wherein a duration of the reflow is between 2 seconds and 10 seconds.

21. The process of claim 1 , wherein a duration of the reflow is between 3 seconds and 7 seconds.

22. The process of claim 1 , wherein a thickness of the first layer is 0.05 μm to 5 μm; a thickness of the second layer is 0.05 μm to 5 μm; or a thickness of the third layer is 0.05 μm to 2.5 μm.

23. The process claim 1 , further comprising a removal of the protective layer after the reflow step.

24. A process for coating a press-fit contact pin comprising the steps of:
providing a substrate having at least one free surface;
depositing a first layer of a first material on the free surface of the substrate;
depositing a second layer of a second material, different from the first material, on the first layer;
depositing a third layer of a third material, different from the first and second materials, on the second layer;
depositing a protective layer of a fourth material, different and separate from the first, second and third materials, on the third layer, the protective layer is an outermost layer coated on the substrate, the fourth material of the protective layer consists of graphite powder and microcrystalline active carbon; and
performing a reflow of at least the second and third layers from the first, second, and third layers, by transfer of heat through the thermal contact on the protective layer, such that the fourth material of the protective layer does not melt or mix with the first, second, and third layers during reflow and the protective layer prevents oxidation of at least the third layer.

25. A process for coating an element positioned on a printed circuit board, comprising the steps of:
providing a printed-circuit board substrate having at least one free surface;
depositing a first layer of a first material on the free surface of the substrate;
depositing a second layer of a second material, different from the first material, on the first layer;
depositing a third layer of a third material, different from the first and second materials, on the second layer;
depositing a protective layer of a fourth material, different and separate from the first, second and third materials, on the third layer, the protective layer is an outermost layer coated on the substrate, the fourth material of the protective layer consists of graphite powder and microcrystalline active carbon; and
performing a reflow of at least the second and third layers from the first, second, and third layers, by transfer of heat through the thermal contact on the protective layer, such that the fourth material of the protective layer does not melt or mix with the first, second, and third layers during reflow and the protective layer prevents oxidation of at least the third layer.

Assignees

• Tyco Electronics France Sas

Inventors

• Bednarek Alain

Classifications

• H05K3/46

  Manufacturing multilayer circuits · CPC title

• C23C28/322

  only coatings of metal elements only · CPC title

• C23C28/343

  with at least one DLC or an amorphous carbon based layer, the layer being doped or not · CPC title

• H05K3/0091

  Apparatus for coating printed circuits using liquid non-metallic coating compositions · CPC title

• C22C13/00

  Alloys based on tin · CPC title