Method for forming conductive pattern by direct radiation of electromagnetic wave, and resin structure having conductive pattern thereon

Patent metadata

Field	Value
Publication number	US-10344385-B2
Application number	US-201414910966-A
Country	US
Kind code	B2
Filing date	Aug 7, 2014
Priority date	Aug 9, 2013
Publication date	Jul 9, 2019
Grant date	Jul 9, 2019

Abstract

The method for forming the conductive pattern by direct radiation of the electromagnetic wave includes: forming a first region having a predetermined surface roughness by selectively radiating the electromagnetic wave on a polymer resin substrate containing titanium dioxide (TiO2); forming a conductive seed on the polymer resin substrate; forming a metal layer by plating the polymer resin substrate having the conductive seed formed thereon; and removing the conductive seed and the metal layer from a second region of the polymer resin substrate, wherein the second region has surface roughness smaller than that of the first region.

First claim

The invention claimed is:

1. A method for forming conductive pattern by direct radiation using an electromagnetic wave, the method comprising:
preparing a polycarbonate polymer resin substrate containing titanium dioxide (TiO 2 ) having a rutile crystal structure and in a particle state having a particle diameter of 100 nm to 5 μm, and in an amount of 1 to 7 wt % based on the weight of the polycarbonate resin substrate, wherein the TiO 2 effects heat transfer to a depth direction of the polycarbonate polymer resin substrate when the polycarbonate polymer resin substrate is irradiated by a laser electromagnetic wave;
forming a first region having a predetermined surface roughness by selectively irradiating the polycarbonate polymer resin substrate with a laser electromagnetic wave having a wavelength of 1064 nm and an average power of about 3 to 20 W, the polycarbonate polymer resin having a second region that is not irradiated by the laser electromagnetic wave;
forming a conductive seed on the polymer resin substrate by applying a dispersion liquid comprising ethanol and metal nanoparticles on the polycarbonate polymer resin substrate and precipitating and drying the metal nanoparticles to form the conductive seed in a particle form;
forming a metal layer by plating the polymer resin substrate having the conductive seed formed thereon; and
removing the conductive seed and the metal layer from the second region of the polycarbonate polymer resin substrate by sonication followed by air blowing,
wherein the first region of the polycarbonate polymer resin substrate has surface roughness defined by a center line arithmetic average roughness of the absolute values (Ra) of 1 μm to 5 μm, and the second region has a center line arithmetic average roughness of the absolute values (Ra) smaller than that of the first region.

2. The method of claim 1 , wherein the surface roughness of the first region of the polycarbonate resin substrate as defined by degree of adhesion to the metal layer measured using an ISO 2409 standard method cross-cut test having an interval of 2 mm or less using a tape having adhesion of 4.0 to 6.0 N/10 mm width is a delamination area of 5% or less.

3. The method of claim 1 , wherein the surface roughness of the second region of the polycarbonate resin substrate as defined by degree of adhesion to the metal layer measured using an ISO 2409 standard method cross-cut test having an interval of 2 mm or less using a tape having adhesion of 4.0 to 6.0 N/10 mm width is a delamination area of 65% or more.

4. The method of claim 1 , wherein the conductive seed contains at least one kind metal selected from the group consisting of copper (Cu), platinum (Pt), palladium (Pd), silver (Ag), gold (Au), nickel (Ni), tungsten (W), titanium (Ti), chromium (Cr), aluminum (Al), zinc (Zn), tin (Sn), lead (Pb), magnesium (Mg), manganese (Mn) and iron (Fe), ions or complex ions thereof.

5. The method of claim 1 , further comprising surface-treating the polymer resin substrate with a surfactant having surface tension lower than that of the dispersion liquid or solution, between the radiating of the electromagnetic wave and the forming of the conductive seed.

6. The method of claim 1 , wherein the forming of the metal layer includes electroless-plating a conductive metal on the polymer resin substrate.

Assignees

• Lg Chemical Ltd

Inventors

• Kim Jae Hyun
• Jun Shin Hee
• Kim Jae Jin
• Park Chee-Sung
• Seong Eun Kyu
• Lee Su Jeong
• Park Cheol-Hee
• Jeong Han Nah
• Jung Sang Yun

Classifications

• H05K1/097

  Inks comprising nanoparticles and specially adapted for being sintered at low temperature (H05K1/095 takes precedence) · CPC title

• H01B13/01236

  the wires being disposed by machine · CPC title

• H01B5/16

  comprising conductive material in insulating or poorly conductive material, e.g. conductive rubber (H01B1/14, H01B1/20 take precedence; insulating bodies with conductive admixtures H01B17/64; conductive paints C09D5/24) · CPC title

• H01B1/22

  the conductive material comprising metals or alloys · CPC title

• C25D5/56

  of plastics · CPC title