Alloy material with high strength and toughness and its fabrication method of semi-solid sintering

Patent metadata

Field	Value
Publication number	US-10344356-B2
Application number	US-201515322183-A
Country	US
Kind code	B2
Filing date	Dec 29, 2015
Priority date	Feb 13, 2015
Publication date	Jul 9, 2019
Grant date	Jul 9, 2019

Abstract

The present invention belongs to the technical field of the preparation of alloy materials, and discloses a high strength and toughness alloy material, a method for preparing the alloy material by semi-solid sintering, and application thereof. The preparation method comprises the three steps of mixing powders, preparing alloy powders by high-energy ball milling, and semi-solid sintering of alloy powders, the key point lies in the two-step sintering, wherein the temperature is heated to less than the initial melting temperature of the lowest-temperature melting peak of the alloy powder, under the sintering pressure conditions, and carried out a sintering densification treatment; after pressure release, the temperature is heated to the sintering temperature Ts, and maintained at the same temperature, and a semi-solid processing is carried out, with a sintering temperature Ts: Ts≥the initial melting temperature of the lowest-temperature melting peak of the alloy powder, Ts≤the initial melting temperature of the highest-temperature melting peak of the alloy powder. By using the present method, a variety of high melting point alloy systems comprising such as Ti-based, Ni-based alloy system, and the like are carried out a semi-solid processing, so as to obtain an alloy material with a novel microstructure such as nanocrystalline, ultra-fine crystalline, fine crystalline or bimodal structure, and the like, and having excellent performances, which can be widely used in the fields of aerospace, military, instruments and the like.

First claim

The invention claimed is:

1. A method for preparing a high strength and toughness alloy material by semi-solid sintering, comprising the steps and process conditions as follows:
step 1:
placing elementary substance powders proportionally into a powder mixing machine, and mixed so as to obtain homogeneously mixed powders;

step 2:
placing the homogeneously mixed powders into a ball mill to carry out high-energy ball milling, until forming alloy powders having nanocrystalline or amorphous structure;

step 3:
sintering the alloy powders loaded in a sintering mould consolidated by a powder metallurgy technology, selecting the sintering temperature Ts, and carrying out the sintering in a two-step process,
wherein the temperature is heated to less than the initial melting temperature of the lowest-temperature melting peak of the alloy powder under sintering pressure conditions, and sintering densification of the alloy powders;
following pressure release, the temperature is heated to the sintering temperature Ts, maintaining the same temperature, and a semi-solid processing is carried out, with process conditions as follows:
the sintering temperature Ts:
 Ts≥the initial melting temperature of the lowest-temperature melting peak of the alloy powder,
 Ts≤the initial melting temperature of the highest-temperature melting peak of the alloy powder;
the sintering pressure of 20-500 MPa; and

step 4:
cooling to obtain a high strength and toughness alloy material.

2. The method for preparing a high strength and toughness alloy material by semi-solid sintering according to claim 1 , when the sintering mould used is a graphite mould, the sintering pressure in step 3 is 30-50 MPa; and when the sintering mould used is a tungsten carbide mould, the sintering pressure in step 3 is 50-500 MPa.

3. The method for preparing a high strength and toughness alloy material by semi-solid sintering according to claim 1 , wherein the powder metallurgy technology in step 3 is any one of powder extrusion, powder hot pressing, powder rolling, powder forging and spark plasma sintering.

4. The method for preparing a high strength and toughness alloy material by semi-solid sintering according to claim 1 , wherein the elementary substance powders in step 1 are the powders prepared by atomization process, electrolysis process or hydrogenation-dehydrogenation process.

5. The method for preparing a high strength and toughness alloy material by semi-solid sintering according to claim 1 , wherein the high strength and toughness alloy material prepared in step 3 is carried out a post-heat treatment.

6. The method for preparing a high strength and toughness alloy material by semi-solid sintering according to claim 1 , wherein the high strength and toughness alloy material prepared in step 3 is carried out an annealing treatment.

7. The high strength and toughness alloy material, produced by the method according to any one of claims 1 - 6 .

8. The high strength and toughness alloy material according to claim 7 , wherein the high strength and toughness alloy material is Ti-based, Ni-based, Zr-based, Cu-based, Co-based, Nb-based, Fe-based, Mn-based, Mo-based or Ta-based alloy system.

9. The high strength and toughness alloy material according to claim 7 , wherein the structure of the high strength and toughness alloy material comprises nanocrystalline, ultra-fine crystalline, fine crystalline or dual-scale structure.

Assignees

• Univ South China Tech

Inventors

• Yang Chao
• Yao Yaguang
• Kang Limei
• Liu Lehua
• Qu Shengguan
• Chen Weiping
• Li Yuanyuan

Classifications

• C22C1/0458 Primary

  Alloys based on titanium, zirconium or hafnium · CPC title

• B22F3/18

  by using pressure rollers · CPC title

• B22F3/20

  by extruding · CPC title

• B22F2301/205

  Titanium, zirconium or hafnium · CPC title

• B22F9/04

  starting from solid material, e.g. by crushing, grinding or milling ({C22C1/1084 takes precedence}; crushing, grinding or milling, in general, see the relevant subclasses, e.g. B02C) · CPC title