Method of and apparatus for producing saccharified solution by using biomass as raw material, and continuous reactor

Patent metadata

Field	Value
Publication number	US-10344342-B2
Application number	US-201415104356-A
Country	US
Kind code	B2
Filing date	Dec 19, 2014
Priority date	Dec 26, 2013
Publication date	Jul 9, 2019
Grant date	Jul 9, 2019

Abstract

A method of producing a saccharified solution, in which saccharified slurry is obtained by hydrothermally treating cellulosic biomass slurry in a supercritical state or a subcritical state by a continuous reactor. The method reduces the risk of a pressure reducing valve becoming clogged when the high-temperature and high-pressure slurry is flash-evaporated after being hydrothermally treated. Also provides an apparatus for producing a saccharified solution and a continuous reactor. At the time of hydrothermally treating the cellulosic biomass slurry by the continuous reactor continuously, the slurry is intensely stirred in a front part of the continuous reactor, and stirred in a rear part of the continuous reactor by a stirring device with low propelling force, such that the plug flow in the axial direction is kept while the slurry is being uniformly mixed with respect to the cross section perpendicular to the mixing axis.

First claim

The invention claimed is:

1. A method of producing a saccharified solution by using biomass as a raw material, the method comprising:
a hydrolytic saccharification step comprising hydrothermally treating a cellulosic biomass slurry in a supercritical state or a subcritical state in a continuous reactor to obtain a saccharified slurry containing solid materials formed in the continuous reactor, the continuous reactor having a front part configured to mix the cellulosic biomass slurry and steam and a rear part configured to move the slurry mixed with the steam toward an outlet as a plug flow in an axial direction of the continuous reactor;
a crushing step comprising supplying the saccharified slurry to a crushing apparatus, and then crushing the solid materials in the saccharified slurry into pieces with the crushing apparatus;
a flash step comprising supplying the saccharified slurry, containing the crushed solid materials, through a pressure reducing valve to a flash tank, and then flash-evaporating and cooling down the saccharified slurry; and
a solid-liquid separation step of performing solid-liquid separation to separate the cooled down saccharified slurry into a saccharified solution and solid matter.

2. The method of producing a saccharified solution according to claim 1 , wherein
in the crushing step, part of the saccharified solution that is obtained in the solid-liquid separation step is added to the saccharified slurry to dilute the saccharified slurry.

3. The method of producing a saccharified solution according to claim 1 , wherein
the front part includes biaxial screws, biaxial paddles, biaxial oval blades, or biaxial kneaders,
the rear part includes pin vanes or plate vanes, and
the biaxial screws, the biaxial paddles, the biaxial oval blades, or the biaxial kneaders of the front part, and the pin vanes or the plate vanes of the rear part, are provided on a same rotary shaft or same rotary shafts.

4. An apparatus for producing a saccharified solution by using biomass as a raw material, the apparatus comprising:
a continuous reactor configured to hydrothermally treat a cellulosic biomass slurry in a supercritical state or a subcritical state to obtain a saccharified slurry containing solid materials formed in the continuous reactor, the continuous reactor having a front part configured to mix the cellulosic biomass slurry and steam and a rear part configured to move the slurry mixed with the steam toward an outlet as a plug flow in an axial direction of the continuous reactor;
a crushing apparatus configured to crush the solid materials contained in the saccharified slurry into pieces;
a flash tank configured to flash-evaporate and cool down the saccharified slurry containing the crushed solid materials;
a pressure reducing valve disposed at an inlet of the flash tank, and through which the saccharified slurry containing the crushed solid materials is supplied to the flash tank;
a solid-liquid separator configured to perform solid-liquid separation to separate the cooled down saccharified slurry into a saccharified solution and solid matter; and
saccharified slurry supply piping configured to supply the saccharified slurry from the continuous reactor to the crushing apparatus.

5. The apparatus for producing a saccharified solution according to claim 4 , further comprising:
saccharified solution supply piping configured to supply part of the saccharified solution from the solid-liquid separator to the crushing apparatus,
wherein the crushing apparatus is configured to mix the saccharified slurry containing the solid materials with the saccharified solution, and to crush the solid materials contained in the saccharified slurry that has been diluted with the saccharified solution.

6. The apparatus for producing a saccharified solution according to claim 4 , wherein
the front part includes biaxial screws, biaxial paddles, biaxial oval blades, or biaxial kneaders,
the rear part includes pin vanes or plate vanes, and
the biaxial screws, the biaxial paddles, the biaxial oval blades, or the biaxial kneaders of the front part, and the pin vanes or the plate vanes of the rear part, are provided on a same rotary shaft or same rotary shafts.

7. The apparatus for producing a saccharified solution according to claim 5 , wherein
the crushing apparatus includes:
a mixing chamber including a stirring device configured to mix the saccharified slurry and the saccharified solution;
a crushing blade configured to crush the solid materials contained in the saccharified slurry that has been diluted with the saccharified solution; and
a screen configured to separate any of the solid materials that are larger than a predetermined size,

the saccharified slurry supply piping and the saccharified solution supply piping are connected to the mixing chamber, and
the crushing apparatus is configured to supply the saccharified slurry that has passed through the screen and that has been diluted to outside.

8. A continuous reactor for hydrothermally treating cellulosic biomass slurry in a supercritical state or a subcritical state, the continuous reactor comprising:
a front part including biaxial screws, biaxial paddles, biaxial oval blades, or biaxial kneaders, the front part being configured to mix the cellulosic biomass slurry and steam and forming an inlet side of the continuous reactor and constituting ¼ to ½ of the continuous reactor; and
a rear part including pin vanes or plate vanes, the rear part being configured to move the slurry mixed with the steam toward an outlet as a plug flow in an axial direction of the continuous reactor,
wherein the biaxial screws, the biaxial paddles, the biaxial oval blades, or the biaxial kneaders of the front part, and the pin vanes or the plate vanes of the rear part, are provided on a same rotary shaft or same rotary shafts.

9. The continuous reactor according to claim 8 , comprising two rotary shafts that are parallel to each other.

Assignees

• Kawasaki Heavy Ind Ltd

Inventors

• Kusuda Hiromasa
• Izumi Noriaki
• Tajiri Hironori
• Tsujita Shoji
• Tsuzawa Masaki

Classifications

• C12M45/20

  Heating; Cooling (heating or cooling apparatus for laboratory uses B01L7/00) · CPC title

• C12M45/02

  by mechanical forces; Stirring; Trituration; Comminuting (crushing, pulverizing, disintegrating in general B02C) · CPC title

• B01J19/18

  Stationary reactors having moving elements inside (B01J19/08, B01J19/26 take precedence) · CPC title

• C13K1/02 Primary

  obtained by saccharification of cellulosic materials (manufacture of fodder A23K10/32) · CPC title

• C12M45/04

  Phase separators; Separation of non fermentable material; Fractionation · CPC title