Process for preparing a catalyst

Patent metadata

Field	Value
Publication number	US-10343149-B2
Application number	US-201515121905-A
Country	US
Kind code	B2
Filing date	Feb 26, 2015
Priority date	Feb 28, 2014
Publication date	Jul 9, 2019
Grant date	Jul 9, 2019

Abstract

The present disclosure relates to a process for preparing a catalyst. The process comprises coating zeolite gel over the alumina support to obtain a chloride free zeolite gel coated alumina support, crystallizing the chloride free zeolite gel coated alumina support, washing, drying and calcining the crystallized zeolite coated alumina support to obtain a calcined crystallized chloride free zeolite coated alumina support, treating the calcined crystallized chloride free zeolite coated alumina support with ammonium nitrate to obtain sodium free support, washing, drying, and calcining the support to obtain a calcined chloride free zeolite coated alumina support, immersing the calcined chloride free zeolite coated alumina support in an active metal and a promoter metal solution mixture followed by stirring to obtain a metal coated chloride free zeolite coated alumina support, and drying and calcining the metal coated chloride free zeolite coated alumina support to obtain the catalyst.

First claim

The invention claimed is:

1. A process for preparing a catalyst for naphtha reforming, said process comprising the following steps:
a) providing a chloride free alumina support;
b) coating zeolite gel over the chloride free alumina support to obtain a zeolite gel coated chloride free alumina support, wherein said zeolite has molar ratio of SiO 2 to A1 2 O 3 ranging from 10:1 to 20:1;
wherein said zeolite gel is prepared by

i. dissolving NaAlO 2 in deionized water followed by stirring to form a first mixture;
ii. adding tetraethyl ortho-silicate to said first mixture followed by stirring to form a second mixture; and
iii. adding tetra-propylammonium hydroxide drop-wise to said second mixture followed by stirring to form said zeolite gel,
c) crystallizing the zeolite gel coated chloride free alumina support to obtain a crystallized zeolite coated chloride free alumina support;
d) washing, drying and calcining the crystallized zeolite coated chloride free alumina support to obtain a calcined crystallized zeolite coated chloride free alumina support;
e) treating the calcined crystallized zeolite coated chloride free alumina support with ammonium nitrate to obtain sodium free support;
f) washing, drying, and calcining the support to obtain a calcined zeolite coated chloride free alumina support,
g) immersing the calcined zeolite coated chloride free alumina support in an active metal and a promoter metal solution mixture followed by stirring to obtain a metal coated zeolite coated chloride free alumina support; and
h) drying and calcining the metal coated zeolite coated chloride free alumina support to obtain the catalyst.

2. The process as claimed in claim 1 , wherein said active metal and promoter metal solution mixture is prepared by,
i) preparing an active metal solution by using at least one precursor of an active metal, wherein said active metal is a Group VIII metal;
ii) preparing a promoter metal solution by using at least one precursor of a promoter metal, wherein said promoter metal is a Group IV metal; and
iii) mixing the active metal solution and the promoter metal solution to form said active metal and promoter metal solution mixture.

3. The process as claimed in claim 1 , wherein
i. crystallization step (c) is carried out in a temperature range of 150° C. to 250° C. for a time period ranging from 2 days to 8 days under autogenous pressure;
ii. drying step (d) is carried out in an oven in a temperature range of 100° C. to 200° C.;
iii. calcination step(d) is carried out in a furnace in a temperature range of 500° C. to 600° C. for a time period ranging from 2 hours to 10 hours;
iv. drying step (f) is carried out in an oven in a temperature range of 100° C. to 200° C. for a time period ranging from 10 hours to 20 hours; and
v. calcination step (f) is carried out in a furnace in a temperature range of 500° C. to 650° C. for a time period ranging from 4 hours to 10 hours.

4. The process as claimed in claim 1 , wherein said drying step (h) is carried out in an oven in a temperature range of 100° C. to 200° C. for a time period ranging from 10 hours to 20 hours.

5. The process as claimed in claim 1 , wherein said calcining step (h) is carried out in a furnace in a temperature range of 500° C. to 600° C. for a time period ranging from 5 hours to 20 hours.

6. The process as claimed in claim 1 , wherein said precursor of active metal is at least one selected from a group consisting of Diamine-dinitro platinate II, Hexachloroplatinic acid, Platinum acetylacetonate, Platinum Nitrate, Tetrammineplatinum (II) chloride, and Platinum (IV) chloride.

7. The process as claimed in claim 1 , wherein said precursor of promoter metal is at least one selected from a group consisting of tetra butyl tin, tin (IV) chloride, and tin (II) chloride.

Assignees

• Reliance Industries Ltd

Inventors

• Sharma Nagesh
• Kumar Ajay
• Mettu Anilkumar
• Katravulapalli Veera Venkata Satya Bhaskara Sita Rama Murthy
• Gopalakrishna Kalpana
• Jasra Raksh Vir

Classifications

• B01J29/072

  Iron group metals or copper · CPC title

• B01J29/40

  of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively · CPC title

• B01J37/0246

  Coatings comprising a zeolite · CPC title

• B01J29/7815

  Zeolite Beta · CPC title

• C10G35/09 Primary

  Bimetallic catalysts in which at least one of the metals is a platinum group metal · CPC title