Thermoformed container and production method thereof

Patent metadata

Field	Value
Publication number	US-10287416-B2
Application number	US-201415023238-A
Country	US
Kind code	B2
Filing date	Sep 17, 2014
Priority date	Sep 20, 2013
Publication date	May 14, 2019
Grant date	May 14, 2019

Abstract

Provided is a thermoformed container having a superior appearance as a result of inhibition of coloring and generation of defects during the melt molding, having sufficient strength, and further having a self-purge feature in a production process. The thermoformed container includes an EVOH layer (A) containing an ethylene-vinyl alcohol copolymer (I) as a principal component, wherein the EVOH layer (A) contains a carbonyl compound (II), the carbonyl compound (II) is an unsaturated aldehyde (II-1), a saturated aldehyde (II-2), a saturated ketone (II-3) or a combination thereof, and the content of the carbonyl compound (II) in the EVOH layer (A) is 0.01 ppm or greater and 100 ppm or less. The carbonyl compound (II) is preferably an unsaturated aldehyde (II-1), and the unsaturated aldehyde (II-1) is preferably an unsaturated aliphatic aldehyde.

First claim

The invention claimed is:

1. A heat-molded container that comprises an EVOH layer (A) comprising an ethylene-vinyl alcohol copolymer (I) as a principal component,
wherein
the EVOH layer (A) comprises a carbonyl compound (II), wherein
the carbonyl compound (II) is an unsaturated aldehyde (II-1), a saturated aldehyde (II-2), a saturated ketone (II-3) or a combination thereof, and
a content of the carbonyl compound (II) in the EVOH layer (A) is 0.01 ppm to 100 ppm.

2. The heat-molded container according to claim 1 , wherein the carbonyl compound (II) is the unsaturated aldehyde (II-1), and the unsaturated aldehyde (II-1) is an unsaturated aliphatic aldehyde.

3. The heat-molded container according to claim 2 , wherein the unsaturated aliphatic aldehyde is crotonaldehyde, 2,4-hexadienal, 2,4,6-octatrienal or a combination thereof.

4. The heat-molded container according to claim 1 , wherein the carbonyl compound (II) is the saturated aldehyde (II-2), and the saturated aldehyde (II-2) is propanal, butanal, hexanal or a combination thereof.

5. The heat-molded container according to claim 1 , wherein the carbonyl compound (II) is the saturated ketone (II-3), and the saturated ketone (II-3) is acetone, methyl ethyl ketone, 2-hexanone or a combination thereof.

6. The heat-molded container according to claim 1 , wherein the EVOH layer (A) further comprises a conjugated polyene compound (III), and
a content of the conjugated polyene compound (III) in the EVOH layer (A) is 0.01 ppm to 1,000 ppm.

7. The heat-molded container according to claim 6 , wherein the conjugated polyene compound (III) is sorbic acid, a sorbic acid salt or a combination thereof.

8. The heat-molded container according to claim 1 ,
wherein
the carbonyl compound (II) is the unsaturated aldehyde (II-1),
the unsaturated aldehyde (II-1) is an unsaturated aliphatic aldehyde,
the unsaturated aliphatic aldehyde is crotonaldehyde, 2,4-hexadienal, 2,4,6-octatrienal or a combination thereof,
the EVOH layer (A) further comprises a conjugated polyene compound (III), and
a content of the conjugated polyene compound (III) in the EVOH layer (A) is 0.01 ppm to 1,000 ppm.

9. The heat-molded container according to claim 1 ,
wherein
the carbonyl compound (II) is the saturated aldehyde (II-2),
the saturated aldehyde (II-2) is propanal, butanal, hexanal or a combination thereof,
the EVOH layer (A) further comprises a conjugated polyene compound (III), and
a content of the conjugated polyene compound (III) in the EVOH layer (A) is 0.01 ppm to 1,000 ppm.

10. The heat-molded container according to claim 1 , wherein the carbonyl compound (II) is the saturated ketone (II-3),
the saturated ketone (II-3) is acetone, methyl ethyl ketone, 2-hexanone or a combination thereof,
the EVOH layer (A) further comprises a conjugated polyene compound (III), and
a content of the conjugated polyene compound (III) in the EVOH layer (A) is 0.01 ppm to 1,000 ppm.

11. The heat-molded container according to claim 1 , further comprising:
thermoplastic resin layers (B) each laminated on one face side and another face side of the EVOH layer (A); and
a polyolefin layer (C) arranged between the EVOH layer (A) and the thermoplastic resin layer (B) and comprising a carboxylic acid-modified polyolefin as a principal component,
wherein a solubility parameter of the thermoplastic resin constituting the thermoplastic resin layer (B) calculated using a Fedors equation is 11 (cal/cm 3 ) 1/2 or less.

12. The heat-molded container according to claim 1 , which is a cup-shaped container.

13. The heat-molded container according to claim 1 , which is a tray-shaped container.

14. A method for producing the heat-molded container according to claim 1 , the method comprising:
forming an EVOH layer (A) with a resin composition comprising an ethylene-vinyl alcohol copolymer (I) as a principal component and comprising the carbonyl compound (II); and
subjecting a layer comprising the EVOH layer (A) to heat molding,
wherein
the carbonyl compound (II) is an unsaturated aldehyde (II-1), a saturated aldehyde (II-2), a saturated ketone (II-3) or a combination thereof, and
a content of the carbonyl compound (II) in the resin composition is 0.01 ppm to 100 ppm.

Assignees

• Kuraray Co

Inventors

• Kawai Hiroshi
• Nakazawa Shogo

Classifications

• C08K5/07

  Aldehydes; Ketones · CPC title

• C08K5/09

  Carboxylic acids; Metal salts thereof; Anhydrides thereof · CPC title

• C08K5/098 Primary

  Metal salts of carboxylic acids · CPC title

• B65D1/26

  Thin-walled containers, e.g. formed by deep-drawing operations {(B65D1/165 takes precedence)} · CPC title

• B32B2439/60

  Bottles · CPC title