Ligand compound, organic chromium compound, catalyst system for oligomerization of olefins, and method for oligomerization of olefins using the catalyst system (as amended)
US-2017029346-A1 · Feb 2, 2017 · US
Ligand compound, catalyst system for olefin oligomerization, and method for oligomerizing olefins using the same
US10287373B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10287373-B2 |
| Application number | US-201615527898-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 21, 2016 |
| Priority date | Oct 21, 2015 |
| Publication date | May 14, 2019 |
| Grant date | May 14, 2019 |
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- Title
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Abstract
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The present invention relates to a ligand compound, a catalyst system for olefin oligomerization, and a method for oligomerizing olefins using the same. The ligand compound according to the present invention has a structure in which a substituent is substituted in the trans form, and thereby when used for olefin oligomerization, the activity of the catalyst used and the selectivity of 1-hexene and 1-octene can be increased.
First claim
Opening claim text (preview).
The invention claimed is: 1. A compound represented by Chemical Formula 1 or 2 below: in Chemical Formulas 1 and 2, R 1 to R 4 are each independently C 1-10 alkyl; C 3-6 cycloalkyl unsubstituted or substituted by C 1-10 alkyl or C 1-10 alkoxy; C 6-20 aryl unsubstituted or substituted by C 1-10 alkyl or C 1-10 alkoxy; Or C 5-20 heteroaryl unsubstituted or substituted by C 1-10 alkyl or C 1-10 alkoxy, R 5 is C 3-6 cycloalkyl unsubstituted or substituted by C 1-10 alkyl or C 1-10 alkoxy; C 6-20 aryl unsubstituted or substituted by C 1-10 alkyl or C 1-10 alkoxy; or C 5-20 heteroaryl unsubstituted or substituted by C 1-10 alkyl or C 1-10 alkoxy, and X is a bond or C 1-5 alkylene. 2. The compound of claim 1 , wherein R 1 to R 4 are identical to one another. 3. The compound of claim 1 , wherein R 1 to R 4 are phenyl. 4. The compound of claim 1 , wherein R 5 is cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexyl substituted with methyl, or phenyl. 5. The compound of claim 1 , wherein X is a bond or methylene. 6. The compound of claim 1 , wherein R 5 is C 3-6 cycloalkyl, or C 6-20 aryl, and X is methylene. 7. The compound of claim 1 , wherein R 5 is C 3-6 cycloalkyl, and X is a bond. 8. The compound of claim 1 , wherein the compound represented by Chemical Formula 1 or 2 is any one selected from the group consisting of the following compounds: 9. A catalyst system for olefin oligomerization, comprising: the compound of claim 1 , a source of transition metal, and a cocatalyst. 10. A method for oligomerizing olefins, comprising multimerizing olefins in the presence of the catalyst system for olefin oligomerization of claim 9 .
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Classifications
Organo-phosphines · CPC title
Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond · CPC title
Phosphorus compounds (sugar phosphates C07H11/04; nucleotides C07H19/00, C07H21/00; nucleic acids C07H21/00) · CPC title
Antimony compounds · CPC title
of manganese, technetium or rhenium · CPC title
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- What does patent US10287373B2 cover?
- The present invention relates to a ligand compound, a catalyst system for olefin oligomerization, and a method for oligomerizing olefins using the same. The ligand compound according to the present invention has a structure in which a substituent is substituted in the trans form, and thereby when used for olefin oligomerization, the activity of the catalyst used and the selectivity of 1-hexene …
- Who is the assignee on this patent?
- Lg Chemical Ltd
- What technology area does this patent fall under?
- Primary CPC classification C08F210/14. Mapped technology areas include Chemistry & Metallurgy.
- When was this patent published?
- Publication date Tue May 14 2019 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
- What related patents are in patentsdb?
- We list 7 related publications on this page (citations in our corpus or others sharing the same primary CPC).