Heat treatable coated article with low-E coating having zinc stannate based layer between IR reflecting layers and corresponding method

Patent metadata

Field	Value
Publication number	US-10287209-B2
Application number	US-201715848120-A
Country	US
Kind code	B2
Filing date	Dec 20, 2017
Priority date	Nov 20, 2013
Publication date	May 14, 2019
Grant date	May 14, 2019

Abstract

A coated article is provided which may be heat treated (e.g., thermally tempered) in certain example instances. In certain example embodiments, the coated article includes a low-emissivity (low-E) coating having a zinc stannate based layer provided over a silver-based infrared (IR) reflecting layer, where the zinc stannate based layer is preferably located between first and second silver based IR reflecting layers. The zinc stannate based layer may be provided between and contacting (i) an upper contact layer of or including Ni and/or Cr (or Ti, or TiOx), and (ii) a layer of or including silicon nitride.

First claim

The invention claimed is:

1. A coated article including a coating supported by a glass substrate, comprising:
a first dielectric layer supported by the glass substrate;
a second dielectric layer supported by the glass substrate and located over the first dielectric layer;
a first infrared (IR) reflecting layer comprising silver supported by the glass substrate and located over at least the first and second dielectric layers;
a first upper contact layer comprising an oxide of NiCr from 20-40 Å thick, the first upper contact layer located over and directly contacting the first IR reflecting layer comprising silver;
a layer comprising zinc stannate from 350-600 Å thick located over and directly contacting the first upper contact layer comprising the oxide of Ni and Cr in order to improve color stability upon heat treatment;
a first layer comprising silicon nitride located over and directly contacting the layer comprising zinc stannate;
a layer comprising zinc oxide supported by the glass substrate and located over at least the first layer comprising silicon nitride;
a second IR reflecting layer comprising silver located over at least the first layer comprising silicon nitride and the layer comprising zinc oxide, wherein the coating contains no more than two IR reflecting layers comprising silver;
a second upper contact layer located over and directly contacting the second IR reflecting layer comprising silver;
another dielectric layer located over at least the second IR reflecting layer and the second upper contact layer; and
wherein layers of the coating are of materials and thicknesses configured so that the coated article will have a transmissive ΔE* value of no greater than 5.0 upon heat treatment at about 650 degrees C. for all time periods between 0 and 30 minutes.

2. The coated article of claim 1 , wherein the first dielectric layer comprises silicon nitride.

3. The coated article of claim 1 , further comprising a layer comprising NiCr located between and directly contacting the first layer comprising silicon nitride and a further layer comprising silicon nitride.

4. The coated article of claim 1 , wherein the layer comprising zinc stannate contains more Zn than Sn.

5. The coated article of claim 1 , wherein the coating has a sheet resistance (R s ) of no greater than 3.0 ohms/square.

6. The coated article of claim 1 , wherein the coated article, measured monolithically, has a visible transmission of at least 40%.

7. The coated article of claim 1 , wherein the layer comprising zinc stannate is the thickest layer in the coating.

8. A coated article including a coating supported by a glass substrate, comprising:
a first dielectric layer supported by the glass substrate;
a second dielectric layer supported by the glass substrate and located over the first dielectric layer;
a first infrared (IR) reflecting layer comprising silver supported by the glass substrate and located over at least the first dielectric layer;
an upper contact layer comprising an oxide of NiCr from 10-100 Å thick, the upper contact layer comprising an oxide of NiCr located over and directly contacting the first IR reflecting layer comprising silver;
a layer comprising zinc stannate from 200-800 Å thick located over and directly contacting the upper contact layer comprising an oxide of NiCr;
a first layer comprising silicon nitride from 80-200 Å thick located over and directly contacting the layer comprising zinc stannate;
a layer comprising zinc oxide supported by the glass substrate and located over at least the first layer comprising silicon nitride;
a second IR reflecting layer comprising silver located over at least the first layer comprising silicon nitride and located over and directly contacting the layer comprising zinc oxide, wherein the coating contains no more than two IR reflecting layers comprising silver;
another dielectric layer located over at least the second IR reflecting layer; and
wherein layers of the coating are of materials and thicknesses configured so that the coated article will have a transmissive ΔE* value of no greater than 5.0 upon heat treatment at about 650 degrees C. for all time periods between 0 and 30 minutes.

9. The coated article of claim 8 , wherein the layer comprising zinc oxide is located between and directly contacting the second layer comprising silicon nitride and the second IR reflecting layer.

Assignees

• Guardian Europe S Ar L
• Guardian Europe Sarl

Inventors

• Pallotta Pierre
• Ferreira Jose
• Lage Herbert
• Frank Marcus

Classifications

• C03C17/366 Primary

  Low-emissivity or solar control coatings · CPC title

• C03C17/3652

  the coating stack containing at least one sacrificial layer to protect the metal from oxidation · CPC title

• Y10T428/2495

  Thickness [relative or absolute] · CPC title

• C03C17/3435

  comprising a nitride, oxynitride, boronitride or carbonitride · CPC title

• C03C17/3644

  the metal being silver · CPC title