Heat treatable coated article with low-E coating having zinc stannate based layer between IR reflecting layers and corresponding method

Patent metadata

Field	Value
Publication number	US-9873633-B2
Application number	US-201314084895-A
Country	US
Kind code	B2
Filing date	Nov 20, 2013
Priority date	Nov 20, 2013
Publication date	Jan 23, 2018
Grant date	Jan 23, 2018

Abstract

A coated article is provided which may be heat treated (e.g., thermally tempered) in certain example instances. In certain example embodiments, the coated article includes a low-emissivity (low-E) coating having a zinc stannate based layer provided over a silver-based infrared (IR) reflecting layer, where the zinc stannate based layer is preferably located between first and second silver based IR reflecting layers. The zinc stannate based layer may be provided between and contacting (i) an upper contact layer of or including Ni and/or Cr (or Ti, or TiOx), and (ii) a layer of or including silicon nitride.

First claim

The invention claimed is:

1. A coated article including a coating supported by a glass substrate, comprising:
a first dielectric layer supported by the glass substrate;
a second dielectric layer supported by the glass substrate and located over the first dielectric layer;
a first infrared (IR) reflecting layer comprising silver supported by the glass substrate and located over at least the first and second dielectric layers;
a first upper contact layer comprising an oxide of NiCr from 20-40 Å thick, the first upper contact layer located over and directly contacting the first IR reflecting layer comprising silver;
a layer comprising zinc stannate from 350-600 Å thick located over and directly contacting the first upper contact layer comprising the oxide of NiCr in order to improve color stability upon heat treatment;
a first layer comprising silicon nitride from 80-200 Å thick located over and directly contacting the layer comprising zinc stannate;
a layer comprising zinc oxide supported by the glass substrate and located over at least the first layer comprising silicon nitride;
a second IR reflecting layer comprising silver located over at least the first layer comprising silicon nitride and the layer comprising zinc oxide, wherein the coating contains no more than two IR reflecting layers comprising silver;
a second upper contact layer located over and directly contacting the second IR reflecting layer comprising silver;
another dielectric layer located over at least the second IR reflecting layer and the second upper contact layer; and
wherein layers of the coating are of materials and thicknesses configured so that the coated article will have a transmissive ΔE* value of no greater than 5.0 upon heat treatment at about 650 degrees C. for all time periods between 0 and 30 minutes.

2. The coated article of claim 1 , wherein the first dielectric layer comprises silicon nitride.

3. The coated article of claim 1 , wherein the another dielectric layer comprises tin oxide.

4. The coated article of claim 1 , further comprising a layer comprising NiCr that is located between and directly contacting the first layer comprising silicon nitride and a further layer comprising silicon nitride.

5. The coated article of claim 1 , wherein the second dielectric layer comprises zinc oxide and is located under and directly contacting the first IR reflecting layer comprising silver.

6. The coated article of claim 1 , wherein the layer comprising zinc stannate contains more Zn than Sn.

7. The coated article of claim 1 , wherein the layer comprising zinc stannate, with respect to metal content, contains from 51-90% Zn and from 10-49% Sn (wt. %).

8. The coated article of claim 1 , wherein the layer comprising zinc stannate is substantially fully oxided.

9. The coated article of claim 1 , wherein the layer comprising zinc stannate consists essentially of zinc stannate.

10. The coated article of claim 1 , wherein the coating has a sheet resistance (R s ) of no greater than 3.0 ohms/square.

11. The coated article of claim 1 , wherein the coated article, measured monolithically, has a visible transmission of at least about 40%.

12. The coated article of claim 1 , wherein the coated article is heat treated.

13. he coated article of claim 1 , wherein the layer comprising zinc stannate is the thickest layer in the coating.

14. The coated article of claim 1 , wherein the layer comprising zinc stannate is at least five times thicker than is the upper contact layer comprising the oxide of NiCr.

15. The coated article of claim 1 , wherein the layer comprising zinc stannate is at least twice as thick as the first layer comprising silicon nitride that is located over and directly contacting the layer comprising zinc stannate.

16. The coated article of claim 1 , wherein the second IR reflecting layer comprising silver is at least 40 angstroms thicker than is the first IR reflecting layer comprising silver.

17. The coated article of claim 1 , wherein layers of the coating are of materials and thicknesses so that the coated article will have a glass side reflective ΔE* value of no greater than 5.0 upon heat treatment at about 650 degrees C. for all time periods between 0 and 30 minutes.

18. The coated article of claim 1 , wherein layers of the coating are of materials and thicknesses so that the coated article will have a glass side reflective ΔE* value of no greater than 4.0 upon heat treatment at about 650 degrees C. for all time periods between 0 and 24 minutes.

19. The coated article of claim 1 , wherein layers of the coating are of materials and thicknesses so that the coated article will have a transmissive ΔE* value of no greater than 4.0 upon heat treatment at about 650 degrees C. for all time periods between 0 and 24 minutes.

20. The coated article of claim 1 , wherein layers of the coating are of materials and thicknesses so that the coated article will have a haze % of no greater than 0.60% upon heat treatment at about 650 degrees C. for all time periods between 0 and 30 minutes.

21. The coated article of claim 1 , wherein the layers of the coating are of materials and thicknesses so that visible transmission of the coated article substantially plateaus and thus does not change by more than 1.0% between heat treating times of from 12-24 minutes at a heat treating temperature of about 650 degrees C.

22. The coated article of claim 1 , further comprising a layer comprising an oxide of NiCr located over and directly contacting the first layer comprising silicon nitride, and a second layer comprising silicon nitride located over and directly contacting the layer comprising the oxide of NiCr.

23. The coated article of claim 1 , further comprising a layer comprising NiCr located over and directly contacting the first layer comprising silicon nitride, and a second layer comprising silicon nitride located over and directly contacting the layer comprising NiCr.

24. The coated article of claim 23 , wherein the layer comprising zinc oxide is located between and directly contacting the second layer comprising silicon nitride and the second IR reflecting layer.

25. The coated article of claim 1 , further comprising an absorber layer located over and directly contacting the first layer comprising silicon nitride, and a second layer comprising silicon nitride located over and directly contacting the absorber layer.

26. The coated article of claim 25 , wherein the layer comprising zinc oxide is located between and directly contacting the second layer comprising silicon nitride and the second IR reflecting layer.

27. A coated article including a coating supported by a glass substrate, comprising:
a first dielectric layer supported by the glass substrate;
a second dielectric layer supported by the glass substrate and located over the first dielectric layer;
a first infrared (IR) reflecting layer comprising silver supported by the glass substrate and located over at least the first dielectric layer;
an upper contact layer comprising an oxide of NiCr from 20-40 Å thick, the upper contact layer comprising an oxide of NiCr located over and directly contacting the first IR reflecting layer comprising silver;
a layer comprising zinc stannate from 350-600 Å thick located over and directly contacting the upper contact layer comprising an oxide of NiCr in order to improve color stability upon heat treatment;
a first lay

Assignees

• Centre Luxembourgeois De Rech Pour Le Verre Et La Ceramique (C R V C ) Sarl
• Guardian Europe Sarl

Inventors

• Pallotta Pierre
• Ferreira Jose
• Lage Herbert
• Frank Marcus

Classifications

• C03C17/3644

  the metal being silver · CPC title

• C03C17/3626 Primary

  one layer at least containing a nitride, oxynitride, boronitride or carbonitride · CPC title

• C03B27/00

  Tempering {or quenching} glass products · CPC title

• C03C17/3639

  Multilayers containing at least two functional metal layers · CPC title

• C03C17/366 Primary

  Low-emissivity or solar control coatings · CPC title