Method for producing expanded granulate

Patent metadata

Field	Value
Publication number	US-10279516-B2
Application number	US-201414897746-A
Country	US
Kind code	B2
Filing date	Jun 11, 2014
Priority date	Jun 13, 2013
Publication date	May 7, 2019
Grant date	May 7, 2019

Abstract

A process for producing expanded pellets from a thermoplastic elastomer having an elongation at break of more than 100% measured to DIN EN ISO 527-2, comprising:
(a) pressing a polymer melt comprising a blowing agent through a perforated disk ( 18 ) controlled to a temperature between 150° C. and 280° C. and into a pelletizing chamber ( 26 ), (b) using a cutting device ( 20 ) to comminute the polymer melt pressed through the perforated disk ( 18 ) into individual expanding pellets, (c) discharging the pellets from the pelletizing chamber ( 26 ) using a liquid stream ( 36 ),

wherein the blowing agent comprises CO 2 and/or N 2 and the amount of blowing agent in the polymer melt is from 0.5 to 2.5 wt %, the pelletizing chamber ( 26 ) is traversed by a stream of liquid at a temperature between 5° C. and 90° C. and the pressure of 0.1 bar to 20 bar above ambient pressure such that the pellets are expanded in the pressurized liquid by the blowing agent, producing expanded pellets having an uninterrupted skin.

First claim

We claim:

1. A process for production of expanded pellets from a thermoplastic elastomer having an elongation at break of more than 100% measured to DIN EN ISO 527-2, said process comprising:
(a) pressing a polymer melt comprising the thermoplastic elastomer having an elongation at break of more than 100% measured to DIN EN ISO 527-2 and a blowing agent through a perforated disk controlled to a temperature between 150° C. and 280° C.,
(b) using a cutting device to comminute the polymer melt pressed through the perforated disk into expanded pellets, the expended pellets disposed in a pelletizing chamber,
(c) discharging the pellets from the pelletizing chamber using a liquid stream
that traverses the pelletizing chamber, the liquid stream controlled to a temperature between 5° C. and 90° C. and to a pressure from 0.1 bar to 20 bar above ambient pressure,
wherein the pressure and temperature of the liquid stream, and the temperature of the perforated disk being chosen such that the pellets expand in the pressurized liquid stream to produce expanded pellets having an uninterrupted skin, and the blowing agent comprises CO 2 or N 2 , or a combination of CO 2 and N 2 , and the amount of blowing agent in the polymer melt is in a range from 0.5 to 2.5 wt %.

2. The process according to claim 1 wherein the polymer melt comprises a thermoplastic elastomer selected from polyetheramides, polyetheresters, polyesteresters or styrene-butadiene-block copolymers.

3. The process according to claim 1 wherein the thermoplastic elastomer has an elongation at break of more than 200% measured to DIN EN ISO 527-2.

4. The process according to claim 1 wherein the thermoplastic elastomer has a Shore hardness measured to DIN 53505 in the range from A65 to A99.

5. The process according to claim 1 wherein the temperature of the liquid stream in the pelletizing chamber is lowered if the pellets undergo an uncontrolled expansion and do not form an uninterrupted skin, or the temperature of the liquid stream is raised if there is no or insufficient expansion of the pellets.

6. The process according to claim 1 wherein the temperature of the perforated disk is lowered if the pellets undergo an uncontrolled expansion and form an uninterrupted skin, or the temperature of the disk is raised if there is no or insufficient expansion of the pellets.

7. The process according to claim 1 wherein the polymer melt further comprises a nucleating agent.

8. The process according to claim 7 wherein the nucleating agent has a size between 0.01 μm and 100 μm and is selected from talc, calcium fluoride, sodium phenylphosphinate, aluminum oxide, carbon black, graphite, pigments, finely divided polytetrafluoroethylene or a mixture thereof.

9. The process according to claim 1 wherein the blowing agent comprises a co-blowing agent and wherein the co-blowing agent is selected from an alkane, an alcohol, a halogenated hydrocarbon or a mixture thereof.

10. The process according to claim 1 wherein a pressure and a temperature of the pelletizing chamber are chosen such that the bulk density of the expanded pellets is not more than 250 g/l.

11. The process according to claim 1 wherein the temperature of the liquid is between 25° C. and 45° C.

12. The process according to claim 1 wherein the discharged pellets and the liquid stream flow into a dryer, and the pellets are separated from the liquid and collected, and the liquid is filtered and recycled to the pelletizing chamber.

13. The process according to claim 1 wherein the thermoplastic elastomer is a copolyamide, the pressure in the pelletizing chamber is from 5 to 20 bar above ambient pressure, and the blowing agent is present from 1.5 wt % to 2.5 wt %.

14. A process for production of expanded pellets from a thermoplastic elastomer having an elongation at break of more than 200% measured to DIN EN ISO 527-2, and a Shore hardness from A65 to A99 measured to DIN 53505, said process comprising:
(a) pressing a polymer melt comprising the thermoplastic elastomer having an elongation at break of more than 200% measured to DIN EN ISO 527-2 and a blowing agent through a perforated disk controlled to a temperature between 150° C. and 280° C.;
(b) using a cutting device to comminute the polymer melt pressed through the perforated disk into expanded pellets, the expended pellets disposed in a pelletizing chamber;
(c) discharging the pellets from the pelletizing chamber using a liquid stream that traverses the pelletizing chamber, the liquid stream controlled to a temperature between 5° C. and 90° C. and to a pressure of from 0.1 bar to 20 bar above ambient pressure,
wherein the pressure and temperature of the liquid stream, and the temperature of the perforated disk being chosen such that the pellets expand in the pressurized liquid stream to produce expanded pellets having an uninterrupted skin, and the blowing agent comprises CO 2 or N 2 , or a combination of CO 2 and N 2 , and the amount of blowing agent in the polymer melt is in a range from 0.5 to 2.5 wt %.

15. The process according to claim 14 wherein the temperature of the liquid stream in the pelletizing chamber is lowered, or the temperature of the perforated disk is lowered, if the pellets undergo an uncontrolled expansion and do not form an uninterrupted skin.

16. The process according to claim 14 wherein the temperature of the liquid stream is raised temperature, or the temperature of the disk is raised, if there is no or insufficient expansion of the pellets.

Assignees

• Basf Se

Inventors

• Däschlein Christian
• Gutmann Peter
• Prissok Frank
• Keppeler Uwe
• Ahlers Jürgen

Classifications

• C08J2353/02

  of vinyl aromatic monomers and conjugated dienes · CPC title

• C08J2367/00

  Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers · CPC title

• C08J2377/00

  Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers · CPC title

• C08J2371/02

  Polyalkylene oxides · CPC title

• B29B7/88

  Adding charges {, i.e. additives} · CPC title