Method for producing expanded granules

Patent metadata

Field	Value
Publication number	US-10005218-B2
Application number	US-201314391870-A
Country	US
Kind code	B2
Filing date	Apr 12, 2013
Priority date	Apr 13, 2012
Publication date	Jun 26, 2018
Grant date	Jun 26, 2018

Abstract

The invention relates to a process for production of expanded pellets from a polymer melt comprising a blowing agent, said process comprising the steps of:
a) pressing the polymer melt comprising a blowing agent through a perforated disk controlled to a temperature between 150° C. and 280° C. and into a pelletizing chamber, b) using a cutting device to comminute the polymer melt pressed through the temperature-controlled perforated disk into individual expanding pellets, c) discharging the pellets from the pelletizing chamber using a liquid stream,

wherein the blowing agent comprises CO 2 or N 2 or a combination of CO 2 and N 2 and the pelletizing chamber is traversed by a stream of liquid which is controlled to a temperature between 10° C. and 60° C. and the pressure of which is from 0.7 bar to 20 bar above ambient pressure, the pressure and temperature for the liquid in the pelletizing chamber and also the temperature for the perforated disk being chosen such that the pellets are expanded in the pressurized liquid by the blowing agent they contain so as to produce expanded pellets having an uninterrupted skin.

First claim

We claim:

1. A process for production of expanded pellets from a polymer melt comprising a blowing agent and a thermoplastic polyurethane, said process comprising the steps of:
a) pressing the polymer melt through a perforated disk controlled to a temperature between 150° C. and 280° C. and into a pelletizing chamber,
b) using a cutting device to comminute the polymer melt pressed through the perforated disk into individual expanding pellets,
c) discharging the pellets from the pelletizing chamber using a liquid stream,
wherein the blowing agent comprises CO 2 or N 2 or a combination of CO 2 and N 2 ,
wherein the pelletizing chamber is traversed by a stream of liquid which is controlled to a temperature between 10° C. and 60° C. and the pressure of which is from 0.7 bar to 20 bar above ambient pressure,
wherein the pressure and temperature for the liquid in the pelletizing chamber and also the temperature for the perforated disk are chosen such that the pellets are expanded in the pressurized liquid by the blowing agent they contain so as to produce expanded pellets having an uninterrupted skin, wherein the bulk density of the expanded pellets is between 30 g/l and 250 g/l,
wherein the temperature of the liquid in the pelletizing chamber is lowered when the pellets undergo an uncontrolled expansion which does not produce an uninterrupted skin and is raised when there is no or insufficient expansion of the pellets and wherein the temperature of the perforated disk is lowered when the pellets undergo an uncontrolled expansion which does not produce an uninterrupted skin and is raised when there is no or insufficient expansion of the pellets.

2. The process according to claim 1 , wherein the polymer melt comprises a nucleating agent.

3. The process according to claim 2 , wherein the nucleating agent has a size between 0.01 μm and 100 μm and is selected from the group consisting of talc, calcium fluoride, sodium phenylphosphinate, aluminum oxide, carbon black, graphite, pigments, finely divided polytetrafluoroethylene and a mixture thereof.

4. The process according to claim 1 , wherein the blowing agent comprises a co-blowing agent and wherein the co-blowing agent is selected from the group consisting of an alkane, an alcohol, a halogenated hydrocarbon and a mixture thereof.

5. The process according to claim 1 , wherein the mass of a bead of the pellets is between 2 mg and 40 mg.

6. The process according claim 1 , wherein the bead width, the bead height and the bead length of a bead of the pellets are each between 2 mm and 20 mm.

7. The process according to claim 1 , wherein the beads of the pellets have a cell size below 250 μm.

Assignees

• Basf Se

Inventors

• Rudolph Hans
• Klostermann Rainer
• Kaminsky Torben
• Lohaus Bernd
• Ahlers Jürgen
• Schmied Bernhard
• Gutmann Peter
• Hahn Klaus
• Prissok Frank
• Marten Elke
• Däschlein Christian

Classifications

• B29C44/3461

  Making or treating expandable particles · CPC title

• C08J9/16

  Making expandable particles · CPC title

• C08J2367/00

  Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers · CPC title

• C08J2203/182

  of physical blowing agents, e.g. acetone and butane · CPC title

• B29B9/14

  fibre-reinforced · CPC title